All Faculty and Research Staff Publications

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2020
Hu HY, Chen SJ, Mandal M, Pratik SM, Buss JA, Krska SW, Cramer CJ, Stahl SS. Copper-catalysed benzylic C-H coupling with alcohols via radical relay enabled by redox buffering. Nature Catalysis. 2020 .
Gerken JB, Stamoulis A, Suh SE, Fischer ND, Kim YJ, Guzei IA, Stahl SS. Efficient electrochemical synthesis of robust, densely functionalized water soluble quinones. Chemical Communications. 2020 ;56:1199-1202.
Wang F, Stahl SS. Electrochemical Oxidation of Organic Molecules at Lower Overpotential: Accessing Broader Functional Group Compatibility with Electron-Proton Transfer Mediators. Accounts of Chemical Research. 2020 ;53:561-574.
Konnick MM, Knapp SMM, Stahl SS. Mechanism of the reaction of an NHC-coordinated palladium(II)-hydride with O-2 in acetonitrile. Polyhedron. 2020 ;182.
Ryan MC, Kim YJ, Gerken JB, Wang F, Aristov MM, Martinelli JR, Stahl SS. Mechanistic insights into copper-catalyzed aerobic oxidative coupling of N-N bonds. Chemical Science. 2020 ;11:1170-1175.
Li YD, Karlen SD, Demir B, Kim H, Luterbacher J, Dumesic JA, Stahl SS, Ralph J. Mechanistic Study of Diaryl Ether Bond Cleavage during Palladium-Catalyzed Lignin Hydrogenolysis. Chemsuschem. 2020 .
Anson CW, Stahl SS. Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O-2 and Oxidation of H-2, Alcohols, Biomass, and Complex Fuels. Chemical Reviews. 2020 ;120:3749-3786.
2019
Kozack CV, Sowin JA, Jaworski JN, Iosub AV, Stahl SS. Aerobic Acyloxylation of Allylic C-H Bonds Initiated by a Pd-0 Precatalyst with 4,5-Diazafluoren-9-one as an Ancillary Ligand. Chemsuschem. 2019 ;12:3003-3007.
Wang YH, Schneider PE, Goldsmith ZK, Mondal B, Hammes-Schiffer S, Stahl SS. Bronsted Acid Scaling Relationships Enable Control Over Product Selectivity from O-2 Reduction with a Mononuclear Cobalt Porphyrin Catalyst. ACS Central Science. 2019 ;5:1024-1034.
Ryan MC, Whitmire LD, McCann SD, Stahl SS. Copper/TEMPO Redox Redux: Analysis of PCET Oxidation of TEMPOH by Copper(II) and the Reaction of TEMPO with Copper(I). Inorganic Chemistry. 2019 ;58:10194-10200.
Rafiee M, Alherech M, Karlen SD, Stahl SS. Electrochemical Aminoxyl-Mediated Oxidation of Primary Alcohols in Lignin to Carboxylic Acids: Polymer Modification and Depolymerization. Journal of the American Chemical Society. 2019 ;141:15266-15276.
Das A, Nutting JE, Stahl SS. Electrochemical C-H oxygenation and alcohol dehydrogenation involving Fe-oxo species using water as the oxygen source. Chemical Science. 2019 ;10:7542-7548.
Perez JM, Kontur WS, Alherech M, Coplien J, Karlen SD, Stahl SS, Donohue TJ, Noguera DR. Funneling aromatic products of chemically depolymerized lignin into 2-pyrone-4-6-dicarboxylic acid with Novosphingobium aromaticivorans. Green Chemistry. 2019 ;21:1340-1350.
Singh SK, Savoy AW, Yuan ZY, Luo H, Stahl SS, Hegg EL, Hodge DB. Integrated Two-Stage Alkaline-Oxidative Pretreatment of Hybrid Poplar. Part 1: Impact of Alkaline Pre-Extraction Conditions on Process Performance and Lignin Properties. Industrial & Engineering Chemistry Research. 2019 ;58:15989-15999.
Wang F, Stahl SS. Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp(3))-H Bonds. Angewandte Chemie-International Edition. 2019 ;58:6385-6390.
Jaworski JN, Kozack CV, Tereniak SJ, Knapp SMM, Landis CR, Miller JT, Stahl SS. Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)(2)/4,5-Diazafluoren-9-one. Journal of the American Chemical Society. 2019 ;141:10462-10474.
Piszel PE, Vasilopoulos A, Stahl SS. Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper/Nitroxyl Catalysis. Angewandte Chemie-International Edition. 2019 .
Beller M, Shi F, Stahl SS. Preface to Special Issue of ChemSusChem: Sustainable Organic Synthesis. Chemsuschem. 2019 ;12:2834-2834.
Anson CW, Stahl SS. Processes for Electrochemical Production of Electrolyte-free Hydrogen Peroxide. Joule. 2019 ;3:2889-2891.
Li B, Wendlandt AE, Stahl SS. Replacement of Stoichiometric DDQ with a Low Potential o-Quinone Catalyst Enabling Aerobic Dehydrogenation of Tertiary Indolines in Pharmaceutical Intermediates. Organic Letters. 2019 ;21:1176-1181.
2018
Tereniak SJ, Landis CR, Stahl SS. Are Phosphines Viable Ligands for Pd-Catalyzed Aerobic Oxidation Reactions? Contrasting Insights from a Survey of Six Reactions. Acs Catalysis. 2018 ;8:3708-3714.
Ryan MC, Martinelli JR, Stahl SS. Cu-Catalyzed Aerobic Oxidative N-N Coupling of Carbazoles and Diarylamines Including Selective Cross-Coupling. Journal of the American Chemical Society. 2018 ;140:9074-9077.
Lennox AJJ, Goes SL, Webster MP, Koolman HF, Djuric SW, Stahl SS. Electrochemical Aminoxyl-Mediated alpha-Cyanation of Secondary Piperidines for Pharmaceutical Building Block Diversification. Journal of the American Chemical Society. 2018 ;140:11227-11231.
Wang F, Rafiee M, Stahl SS. Electrochemical Functional-Group-Tolerant Shono-type Oxidation of Cyclic Carbamates Enabled by Aminoxyl Mediators. Angewandte Chemie-International Edition. 2018 ;57:6686-6690.
Rafiee M, Konz ZM, Graaf MD, Koolman HF, Stahl SS. Electrochemical Oxidation of Alcohols and Aldehydes to Carboxylic Acids Catalyzed by 4-Acetamido-TEMPO: An Alternative to "Anelli" and "Pinnick" Oxidations. Acs Catalysis. 2018 ;8:6738-6744.
Wang YH, Goldsmith ZK, Schneider PE, Anson CW, Gerken JB, Ghosh S, Hammes-Schiffer S, Stahl SS. Kinetic and Mechanistic Characterization of Low-Overpotential, H2O2-Selective Reduction of O-2 Catalyzed by N2O2-Ligated Cobalt Complexes. Journal of the American Chemical Society. 2018 ;140:10890-10899.
Wang D, Weinstein AB, White PB, Stahl SS. Ligand-Promoted Palladium-Catalyzed Aerobic Oxidation Reactions. Chemical Reviews. 2018 ;118:2636-2679.
Das A, Rahimi A, Ulbrich A, Alherech M, Motagamwala AH, Bhalla A, Sousa LD, Balan V, Dumesic JA, Hegg EL, et al. Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources. Acs Sustainable Chemistry & Engineering. 2018 ;6:3367-3374.
Mannel DS, King J, Preger Y, Ahmed MS, Root TW, Stahl SS. Mechanistic Insights into Aerobic Oxidative Methyl Esterification of Primary Alcohols with Heterogeneous PdBiTe Catalystsy. Acs Catalysis. 2018 ;8:1038-1047.
Rafiee M, Wang F, Hruszkewycz DP, Stahl SS. N-Hydroxyphthalimide-Mediated Electrochemical Iodination of Methylarenes and Comparison to Electron-Transfer-Initiated C-H Functionalization. Journal of the American Chemical Society. 2018 ;140:22-25.
Preger Y, Root TW, Stahl SS. Platinum-Based Heterogeneous Catalysts for Nitrile Synthesis via Aerobic Oxidative Coupling of Alcohols and Ammonia. Acs Omega. 2018 ;3:6091-6096.
Lennox AJJ, Nutting JE, Stahl SS. Selective electrochemical generation of benzylic radicals enabled by ferrocene-based electron-transfer mediators. Chemical Science. 2018 ;9:356-361.
Gerken JB, Pang YTQ, Lauber MB, Stahl SS. Structural Effects on the pH-Dependent Redox Properties of Organic Nitroxyls: Pourbaix Diagrams for TEMPO, ABNO, and Three TEMPO Analogs. Journal of Organic Chemistry. 2018 ;83:7323-7330.
Nutting JE, Rafiee M, Stahl SS. Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions. Chemical Reviews. 2018 ;118:4834-4885.
2017
Ahmed MS, Mannel DS, Root TW, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd-Bi-Te/C (PBT/C) Catalyst. Org. Process Res. Dev. 2017 ;21:1388-1393.
Goldsmith ZK, Harshan AK, Gerken JB, Voros M, Galli G, Stahl SS, Hammes-Schiffer S. Characterization of NiFe oxyhydroxide electrocatalysts by integrated electronic structure calculations and spectroelectrochemistry. Proceedings of the National Academy of Sciences of the United States of America. 2017 ;114:3050-3055.
Stahl SS, Rovis T. Cluster Preface: Catalytic Aerobic Oxidations. Synlett. 2017 ;28:1546-1547.
Hruszkewycz DP, Miles KC, Thiel OR, Stahl SS. Co/NHPI-mediated aerobic oxygenation of benzylic C-H bonds in pharmaceutically relevant molecules. Chemical Science. 2017 ;8:1282-1287.
Anson CW, Stahl SS. Cooperative Electrocatalytic O-2 Reduction Involving Co(salophen) with p-Hydroquinone as an Electron-Proton Transfer Mediator. Journal of the American Chemical Society. 2017 ;139:18472-18475.
Jaworski JN, McCann SD, Guzei IA, Stahl SS. Detection of Palladium(I) in Aerobic Oxidation Catalysis. Angewandte Chemie-International Edition. 2017 ;56:3605-3610.
Mannel DS, Ahmed MS, Root TW, Stahl SS. Discovery of Multicomponent Heterogeneous Catalysts via Admixture Screening: PdBiTe Catalysts for Aerobic Oxidative Esterification of Primary Alcohols. Journal of the American Chemical Society. 2017 ;139:1690-1698.
Walroth RC, Miles KC, Lukens JT, MacMillan SN, Stahl SS, Lancaster KM. Electronic Structural Analysis of Copper(II)-TEMPO/ABNO Complexes Provides Evidence for Copper(I)-Oxoammonium Character. Journal of the American Chemical Society. 2017 ;139:13507-13517.
Vasilopoulos A, Zultanski SL, Stahl SS. Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes. Journal of the American Chemical Society. 2017 ;139:7705-7708.
Tereniak SJ, Stahl SS. Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C-H Imidoylation of Heterocycle-Containing Molecules. Journal of the American Chemical Society. 2017 ;139:14533-14541.
Wang YH, Pegis ML, Mayer JM, Stahl SS. Molecular Cobalt Catalysts for O-2 Reduction: Low-Overpotential Production of H2O2 and Comparison with Iron-Based Catalysts. Journal of the American Chemical Society. 2017 ;139:16458-16461.
Das A, Stahl SS. Noncovalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene-TEMPO Conjugate. Angewandte Chemie-International Edition. 2017 ;56:8892-8897.
Wang DA, Stahl SS. Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)(2) and Discovery of Fe(OTf)(3) as a Highly Effective Cocatalyst. Journal of the American Chemical Society. 2017 ;139:5704-5707.
McCann SD, Lumb JP, Arndtsen BA, Stahl SS. Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diannine Precursor into a Highly Active Aerobic Oxidation Catalyst. Acs Central Science. 2017 ;3:314-321.

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