Air oxidation of primary alcohols catalyzed by copper(I)/TEMPO. Preparation of 2-amino-5-bromobenzaldehyde

TitleAir oxidation of primary alcohols catalyzed by copper(I)/TEMPO. Preparation of 2-amino-5-bromobenzaldehyde
Publication TypeJournal Article
Year of Publication2013
AuthorsHoover, JM, Stahl, SS
JournalOrganic Syntheses
Volume90
Pagination240-250
ISBN Number0078-6209
Accession Number2014:1020019
Keywordsalc selective air oxidn copper TEMPO catalyst, Alcohols Role: RCT (Reactant), RACT (Reactant or reagent) (selective prepn. of aldehydes via copper(I)/TEMPO-catalyzed air oxidn. of aldehydes), aldehyde prepn, Aldehydes Role: SPN (Synthetic preparation), PREP (Preparation) (selective prepn. of aldehydes via copper(I)/TEMPO-catalyzed air oxidn. of aldehydes), Oxidation (selective prepn. of aldehydes via copper(I)/TEMPO-catalyzed air oxidn. of aldehydes)
Abstract

The prepn. of 2-amino-5-bromobenzaldehyde via copper(I)/TEMPO-catalyzed air oxidn. of the corresponding benzylic alc was reported. The methodol. was shown to be applicable to the prepn. of a variety of aldehydes. [on SciFinder(R)]

DOI10.1002/0471264229.os090.23