Experimental Techniques

    The experiments that are most frequently run for our recent research endeavors are TRIVE-FWM experiments.  We use a regenerative amplifier to pump two optical parametric amplifiers, which can be tuned independently to pulse wavelengths throughout the mid-IR (giving the first two variables).  The output from one OPA is split further, and each pulse train is passed into a retroreflector on a movable stage.  Actuators controlling the positions of these stages allow us to adjust the time interval between each of the pulses from the split OPA (shown as ω2 and ω2' below) and the pulses from the other OPA (ω1).  These delay times give experiments two more dimensions.  These three pulses are then spacially and temporally overlapped in the sample.  The TRIVE signal (shown in red) is then emitted in the direction determined by phase-matching and passed through a monochrometer (another variable) to an MCT detector.  Spectra collected are slices in the 5D space of these variables.  We recommend looking into some of the recent publications if you are interested in some of the explorations we have made.