Please follow the links on the left to see full list of refereed and invited publications

 

 Preprints:

 

Molecular mobility in supported thin films of polystyrene, poly(methyl methacrylate), and

poly(2-vinyl pyridine) probed by dye reorientation

K. Paeng, R. Richert, and M.D. Ediger

Soft Matter (submitted) pdf file

 

Segmental dynamics of dilute poly(ethylene oxide) in low molecular weight glassformers

J. Zhao and M.D. Ediger

Macromolecules  (submitted) pdf file

 

Highly stable vapor-deposited glasses of four tris-naphthylbenzene isomers

K. Dawson, L. Zhu, L.A. Kopff, R.J. McMahon, L. Yu, and M.D. Ediger

J. Phys. Chem. Lett. (submitted) pdf file

 

Last updated: 9/19/2011

 


   
Recent Publications

 

Self-diffusion of the amorphous pharmaceutical indomethacin near Tg

S.F. Swallen and M.D. Ediger

Soft Matter  (2011) DOI: 10.1039/c1sm06283b pdf file

 

Molecular motion in freestanding thin films of poly(methyl methacrylate),

poly(4-tert-butyl styrene) poly(α-methyle styrene) and poly(2-vinyl pyridine)

K. Paeng and M.D. Ediger

Macromolecules 44, 7034-42 (2011) pdf file

 

Surface diffusion of an organic glass

L. Zhu, C. Brian, S.F. Swallen, P. Straus, M.D. Ediger, and L. Yu

Phys. Rev. Lett. 106, 256103 (2011) pdf file

 

Direct measurement of molecular motion in freestanding polystyrene thin films

K. Paeng, S.F. Swallen, and M.D. Ediger

J. Am. Chem. Soc. 133, 8444-7 (2011) pdf file

 

Evolution of glassy gratings with variable aspect ratios under surface diffusion

R. Malshe, M.D. Ediger, L. Yu, and J.J. de Pablo

J. Chem. Phys. 134, 194704 (2011) pdf file

 

Glasses crystallize rapidly at free surfaces by growing crystals upward

Y. Sun, L. Zhu, K. Kearns, M.D. Ediger, and L. Yu

Proc. Nat'l Acad. Sci. USA 108, 5990-5995 (2011) pdf file

 

Structural variations of an organic glassformer vapor-deposited onto a temperature-gradient

stage.

Z. Fakhraai, T. Still, G. Fytas, and M.D. Ediger

J. Phys. Chem. Lett. 2, 423-7 (2011) pdf file

 

Anisotropic structure and transformation kinetics of vapor-deposited indomethacin glasses

K. Dawson, L. Zhu, L. Yu, and M.D. Ediger

J. Phys. Chem. B. 115, 455-463 (2011) pdf file

 

Temperature-ramping measurement of dye reorientation to probe molecular motion in polymer glasses

K. Paeng, H.-N. Lee, S.F. Swallen, and M.D. Ediger

J. Chem. Phys. 134, 024901 (2011) pdf file

 

Mechanical rejuvenation in poly(methyl methacrylate) glasses?  Molecular mobility after deformation

H.-N. Lee and M.D. Ediger

Macromolecules. 43, 5863 (2010). pdf file

 

Observations of low heat capacities for vapor-deposited glasses of indomethacin as

determined by AC nanocalorimetry

K.L. Kearns, K.R. Whitaker, M.D. Ediger, H. Huth, and C. Schick

J. Chem. Phys.  133, 014702 (2010).  pdf file

 

Interaction between physical aging, deformation, and segmental mobility in poly(methyl methacrylate) glasses

H.-N. Lee and M.D. Ediger

J. Chem. Phys. 133, 0149901 (2010).   pdf file

 

The transformation of stable glasses into supercooled liquids: growth fronts and anomalously

fast liquid diffusion

S.F. Swallen, K. Windsor, R. J. McMahon, M.D. Ediger, and T. E. Mates

Journal of Physical Chemistry B.  114, 2635-2643 (2010)  pdf file

 

Does Brillouin light scattering probe the primary glass transition process at temperatures well above glass transition?

P. Voudouris, N. Gomopoulus, A. Le Grand, N. Hadjichristidis, G. Floudas, M.D. Ediger, and G. Fytas

J. Chem. Phys. 132, 074906 (2010) pdf file

 

Heterogeneous dynamics during deformation of a polymer glass

R.A. Riggleman, H.-N. Lee, M.D. Ediger, and  J.J. de Pablo

Soft Matter. 6, 287-291 (2010)  pdf file

 

One micron length scale controls kinetic stability of low energy glasses

K.L. Kearns, H. Huth, C. Schick, and M.D. Ediger

Journal of Physical Chemistry Letters. 1, 388-392 (2010) pdf file

 

High modulus organic glasses prepared by physical vapor deposition

K.L. Kearns, T. Still, G. Fytas, and M.D. Ediger

Adv. Mater. 22, 39-42 (2010)  pdf file

 

Physical vapor deposition as a route to hidden amorphous states

K.J. Dawson, K.L. Kearns, L. Yu, W. Steffen, and M.D. Ediger

Proc. Nat’l. Acad. Sci. USA 106 (36), 15165-15170 (2009)  pdf file

 

Two DSC glass transitions in miscible blends of polyisoprene/poly(4-tert-butyl styrene)

J. Zhao, Y. Sun, L. Yu, and M.D. Ediger

Macromolecules 42, 6777-6783 (2009)   pdf file

 

Diffusion-Controlled and “Diffusionless” Crystal Growth Near the Glass Transition: Relation Between Liquid Dynamics and Growth Kinetics of Seven ROY Polymorphs

Y. Sun, H. Xi, M.D. Ediger, R. Richert, and L. Yu

J. Chem. Phys.  131, 074506, (2009) pdf file

 

Molecular Mobility of PMMA Glass During Uniaxial Tensile Creep Deformation

H-N. Lee, K. Paeng, S.F. Swallen, M.D. Ediger, R.A. Stamm, G.A. Medvedev, J.M. Caruthers

J. Polym. Sci, Part B: Polym. Phys. Ed.  47 (17), 1713-1727 (2009) pdf file

 

Deformation-induced mobility in polymer glasses during multistep creep experiments and simulations
H.-N. Lee, R.A. Riggleman, J.J. de Pablo, and M.D. Ediger
Macromolecules 42 (12), 4328-4336 (2009)  pdf file

 

Self-diffusion of supercooled tris-naphthylbenzene

S. F. Swallen, K. Traynor, R. J. McMahon, M.D. Ediger, T. E. Mates

J. Phys. Chem. B 113, 4600-4608 (2009) pdf file

 

Stable glass transformation to supercooled liquid via surface-initiated growth front

S. F. Swallen, K. Traynor, R. J. McMahon, M.D. Ediger, T. E. Mates

Phys. Rev. Lett. 102, 065503 (2009) pdf file
 

Highly stable indomethacin glasses resist uptake of water vapor

K. J. Dawson, K. L. Kearns, M. Sacchetti, G. Zografi, and M. D. Ediger

J. Phys. Chem. B 113, 2422-2427 (2009) pdf file

 

Calorimetric Evidence for Two Distinct Molecular Packing Arrangements in Stable Glasses of Indomethacin

K. L. Kearns, S. F. Swallen, M. D. Ediger, Y. Sun, and L. Yu

J. Phys. Chem. B 113, 1579-1586 (2009) pdf file

 

Direct measurement of molecular mobility in actively deformed polymer glasses

H-N. Lee, K. Paeng, S.F. Swallen, and M.D. Ediger

Science 323, 231 (2009) pdf file  supplemental

 

Poly (ethylene oxide) Dynamics in Blends with Poly(vinyl acetate): Comparison of Segmental and Terminal Dynamics

J. Zhao, L. Zhang, and M.D. Ediger

Macromolecules 41 (21), 8030-8037 (2008) pdf file

 

Crystallization near Glass Transition:  Transition from Diffusion-Controlled to Diffusionless Crystal Growth Studied with Seven Polymorphs

Y. Sun, H. Xi, S. Chen, M.D. Ediger, and L.Yu

J. Phys. Chem. B 112, 5594-5601, (2008) pdf file

 

Molecular View of the Isothermal Transformation of a Stable Glass to a Liquid

S.F. Swallen, K.L. Kearns, S. Satija, K. Traynor, R.J. McMahon, and M.D. Ediger

J. Chem. Phys. 128, 214514, (2008) pdf file

 

Dye Reorientation as a Probe of Stress-induced Mobility in Polymer Glasses

H.-N. Lee, K. Paeng, S.F. Swallen, and M.D. Ediger

J. Chem. Phys. 128, 134902, (2008) pdf file

 

Hiking Down the Energy Landscape: Progress Towards the Kauzmann Temperature via Vapor Deposition

K.L. Kearns, S.F. Swallen, M.D. Ediger, T. Wu, Y. Sun, and L. Yu

J. Phys. Chem. B 112, 4934-42, (2008) pdf file

 

Perspective on Materials Science: Glass Surfaces Not So Glassy

M.D. Ediger and J.R. Dutcher

Science 319, 577-8 (2008) pdf file

 

Diffusionless Crystal Growth from Glass Has Precursor in Equilibrium Liquid

Y. Sun, H. Xi, M.D. Ediger, and L.Yu

J. Phys. Chem. B 112, 661-4 (2008) pdf file

 

Crystal growth kinetics exhibit a fragility-dependent decoupling from viscosity

M.D. Ediger, P.R. Harrowell, and L. Yu

J. Chem. Phys. 128, 034709 (2008) pdf file

 

Organic Glass-Forming Materials: 1,3,5-Tris(naphthyl)benzene Derivatives

P.A. Bonvallet, C.J. Breitkreuz, Y.S. Kim, E.M. Todd, K. Traynor, C.G. Fry, M.D. Ediger, and R.J. McMahon

J. Org. Chem. 72, 10051-57 (2007) pdf file

 

Free Volume and Finite Size Effects in a Polymer Glass Under Stress

R.A. Riggleman, H-N. Lee, M.D. Ediger, and J. J. de Pablo

Phys. Rev. Lett. 99, 215501 (2007) pdf file

 

Influence of Substrate Temperature on the Stability of Glasses Prepared by Vapor Deposition

K. L. Kearns, S. F. Swallen, M. D. Ediger, T. Wu, and L. Yu.

J. Chem. Phys. 127 (15), 154702 (2007) pdf file 

 

Molecular weight dependence of polystyrene segmental dynamics in dilute blends with poly(vinyl methyl ether)

L. Zhang, T.R. Lutz,  J. Zhao, and M.D. Ediger

J. Polym. Sci, Polym. Phys. Ed. 45, 2252 (2007) pdf file

 

Organic glasses with exceptional thermodynamic and kinetic stability

S. F. Swallen, K. L. Kearns, M. K. Mapes, Y. S. Kim, R. J. McMahon, M. D. Ediger, T. Wu, L. Yu, S. Satija

Science 315, 353 (2007) pdf file  supplemental file