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Smaller
than the eye can see: How your computer is made.
Program Module #2: Polymers
(Day 1 of 4)
Materials Needed:
1.) Black tetrahedron models
2.) “Silly Putty” lab
solutions, polyvinyl acetate solution and sodium borate solutions (Enough
for 8-10 pairs of students).
3.) Graduated Cylinders
(8-10)
4.) Beakers, 100mL (8-10)
5.) Plastic Petri dishes
(8-10)
6.) Lab Notebooks (Always
needed)
7.) Quiz (15-20 copies)
8.) Scissors (Always needed)
9.) Tape, Scotch (Always
needed)
Pre-Class Preparations:
1.)
Divide students into 5 groups of
3-4 students. It is recommended that these groups be a different
arrangement from the previously arranged groups.
2.)
Divide students into pairs for
the second activity for the day.
3.)
Be sure that the tetrahedron
models are as evenly divided for work among the five groups of students who
will be using them.
4.)
Be sure that handouts found in
Polymers/intropolymer05.pdf
and Polymers/InterviewDevin.pdf
are copied and ready for distribution.
Lesson Plan:
Objectives:
1.)
Provide students with a solid
understanding of the terms atom, molecule, and polymer.
2.)
Provide students with a limited
understanding of chemical bonding as it relates to the sharing of electrons
in a covalent bond.
3.)
Students will understand that
polymers are repeating units.
4.)
Apply knowledge of polymers as
repeating units in elementary math calculations.
5.)
Use models of molecules to
understand the concept of cross-linking.
6.)
Apply knowledge of cross-linking
from models to an experiment involving the actual cross-linking of a polymer
and formulate a hypothesis based on this knowledge.
Agenda:
1.)
Administer Quiz (See Powers
of Ten/powersoftenday1.pdf)
(8 Minutes)
2.)
Review/Discuss/Introduce the
terms Atom, Molecule, and Polymer (20 Minutes)
3.)
Perform Cross-Linking exercise
with tetrahedron Models in groups (25 Minutes)
4.)
Class Discussion of
Cross-Linking exercise (10 Minutes)
5.)
Make Silly Putty in pairs (25
Minutes)
6.)
Class Discussion of Silly Putty
experiment (10 Minutes)
7.)
Make a thin, smooth polymer
surface on a Petri plate and discuss findings (15 Minutes)
8.)
Read Dr. Devin Flowers article
and discuss (7 Minutes).
Additional Information
about Agenda Items:
2.)
Start this discussion with the
following chemical species represented on the board: H, H2, CO2,
and CH4. Ask students to classify each as an atom or a
molecule. Student responses will vary; honor each response. Lead the class
to a discussion of chemical bonding as it relates to sharing electrons in
molecules—single, double and triple covalent bonds should be represented.
Discuss the term polymer by introducing monomers, like ethylene. Show
students that linking molecules (as monomers) together forms a polymer.
Show the shorthand notation of polymers (use ‘n’ as the number of repeating
units present)
3.)
See instructions in Polymers/intropolymer05.pdf.
Students will be placed into the pre-determined groups of five (3-4 students
in each group). It is important that students are allowed to “play” with
the polymer models first. However, specific tasks must be accomplished
after an initial “play” period. First, the students must be given
information on the length and mass of a carbon atom and a water molecule.
Once this information is obtained, the students will use this information to
apply it to the polymer chain they’ve just built using the tetrahedron
models they’ve been supplied with. Groups should experiment with at least
TWO different lengths of polymer chains. Next, students will be directed
to make their polymer chain more rigid—gentle prodding is required here to
get the students to discover the concept of cross-linking. Each group
should perform at least two cross-links within their model.
4.)
Discuss, as a class, methods
that were used to make the polymer chains, calculate the length/mass of the
chain, and add stability to the chain by cross-linking. An appreciation of
how many polymer units must be used in order to create a macroscopic object
should be gained from this discussion.
5.)
See Polymers/intropolymer05.pdf
for the student handout and lab notebook template. Students will follow
the instructions in the handout, record all data in their notebook (on
template), and perform all three trials in pre-determined pairs. It is
recommended that students be allowed to use large amounts of polymer and
cross-linker, if possible. Garbage bags torn in half can be used at each
station to allow for easy clean-up.
6.)
Discuss, as a class, the
conclusions that each pair of students concluded about the amount of
cross-linker that was used in each of the three experiments and how it
affected the cross-linked polymer that was created.
7.)
Students will use the knowledge
gained from their experiment and class discussion to create a recipe for
silly putty that will create a smooth, thin cross-linked polymer that will
cover the surface of a Petri plate. Discuss what works!
8.)
See Polymers/InterviewDevin.pdf
for article.
Smaller
than the eye can see: How your computer is made.
Program
Module #2: Polymers (Day 2 of 4)
Materials Needed:
1.)
Lab Notebooks, Scissors, and
Tape (Always needed)
2.)
See Polymers/Bounce.pdf
(Look for “Notes for instructor”) for a detailed list of All materials
needed for demos and activity. Be sure that the materials gathered are able
to accommodate up to 10 pairs of students!
3.)
Graph Paper (20-30 copies)
Pre-Class Preparations:
1.)
Be sure all materials for demos
and activity are ordered well ahead of time (See Polymers/Bounce.pdf).
2.)
Make copies (15-20) of quizzes
and graph paper for the day and the template for the day (See
Polymers/Bounce.pdf.)
3.)
Divide students into NEW pairs
for the activity.
Lesson Plan:
Objectives:
1.)
Students will gain an
appreciation of the properties of polymers.
2.)
Students will observe and
collect data and conclude for themselves how temperature can affect the
properties of polymers.
3.)
Provide the formula for the
coefficient of restitution and have students calculate this value for a
variety of situations.
4.)
Students will use a laboratory
notebook to collect data from an experiment.
5.)
Students will analyze data from
an experiment graphically and draw conclusions from their analysis.
Agenda:
1.)
Administer Quiz (8 Minutes)
2.)
Show Demos: (15 Minutes)
A.)
Racquetball in liquid Nitrogen
B.)
Happy/Sad Ball bouncing
C.)
Steel Ball bearings (Crystalline
vs. supercooled liquid surfaces)
D.)
Banana and Rubber Hose in liquid
Nitrogen. (Pound Rubber Hose into a wood block using a banana!)
3.)
Perform Experiment (65 minutes)
4.)
Place data from each pair on the
board and have EVERY student graph THEIR OWN data. (22 Minutes)
5.)
Create an average graph on the
board and discuss the significance of the data collected. (10 minutes)
Additional Information
about the Agenda Items:
1.)
See Polymers/Questions
of the Day05.pdf.
See the first quiz in the file.
2.)
See Polymers/Bounce.pdf
for a detailed account of how to perform each demo. See “Notes for
instructor” portion of the document. Be sure to provide some “theatrics”
when performing the demos and allow the students to ask questions, encourage
questions, and let the students examine, with safety, the product of each
demo.
3.)
Perform experiment found in
Polymers/Bounce.pdf.
Students will be working in pre-determined pairs for this experiment.
Each station must be set up well ahead of time and must be monitored closely
by an adult. The students are required to place their polymer balls in the
desired temperature at each station for a specific amount of time. Be sure
consistent time is give to each station and be sure that students use
consistent measuring technique when collecting data for the coefficient of
restitution.
4.)
Place a chart on the board with
the student pairs clearly labeled along with a data chart to place all the
data that the students collected. Students will be instructed to graph
their own data using graph paper. Adults must patrol the room very
carefully to be sure that students place height on the y-axis and
temperature on the x-axis. (dependent vs. independent variable). Adults
must also monitor the students to be sure that spacing is even throughout
the graph.
5.)
Once all data is collected and
analyzed, have students draw conclusions and place those conclusions in
their notebook. Discuss specific student findings as a class discussion.
Smaller
than the eye can see: How your computer is made.
Program
Module #2: Polymers (Day 3 of 4)
Materials Needed:
1.)
Notebooks, Scissors, and Tape
2.)
Density Materials (Samples of
Density objects). See Polymers/Public_Density_Key.pdf
3.)
Beakers (20-30)
4.)
Four liquids with different
densities
5.)
Density samples: Brass and
Aluminum, oil and water, isopropyl alcohol
6.)
Galilean Thermometer
7.)
Digital Calipers and electronic
scales (5-7)
8.)
Materials for Polyurethane foam
(See Polymers/crosslinked
polymers05.pdf)
9.)
Dixie cups (15-25)
10.)Plastic syringes
(15-25) for delivering Polyurethane foam reagents.
11.)1000mL graduated
cylinder
12.)Heat guns (3-5)
13.)Samples of HDPE—milk
jugs and other polymers (8-10 samples)
Pre-Class Preparations:
1.)
Prepare copies of handouts and
quiz for the day.
2.)
Divide students into groups of 3
for the activities
Lesson Plan:
Objectives:
1.)
Provide students with a review
of density and density calculations
2.)
Provide demos that illustrate
the concept of density as it relates to both liquids and solids.
3.)
Have students apply density
calculations to the identification of unknown objects whose density is
known.
4.)
Students will learn how to
collect data related to the mass and volume of objects.
5.)
Students will apply knowledge of
cross-linking to a new polymer.
6.)
Students will apply knowledge of
density to describe how a Galileo Thermometer works.
7.)
Students will observe the affect
of temperature on polymers.
Agenda:
1.)
Administer Quiz (8 Minutes)
2.)
Teacher-Led discussion of
Density (10 Minutes)
3.)
Demos Relative to density (15
Minutes)
4.)
Perform Density Identification
Experiment (40 Minutes)
5.)
Discuss Results and Galileo
Thermometer (12 Minutes)
6.)
Perform Polyurethane foam
Experiment (20 Minutes)
7.)
Use Heat guns to melt milk
jugs/soda bottles (15 minutes)
Additional Information
about the Agenda Items:
1.)
See Polymers/Bounce.pdf.
See the quiz listed at the end of the file.
2.)
Start with a discussion of
density. Have a student come to the board to describe the “density” change
between brass and aluminum samples that will be provided to the students.
After discussion, have the class agree on a definition of density and
provide the formula for calculating density. Give examples of density
(quantitative values) and provide the units that it is measured in.
3.)
Allow each student to hold the
brass and aluminum samples noting the differences between the two samples;
discuss. Using a large graduated cylinder, pour water into the cylinder.
Ask the students what will happen if vegetable oil is poured into the
water. Have students conclude which liquid is more dense from their
observations and how they know which liquid is more dense. Now, pour
isopropyl alcohol into the graduated cylinder; observe as it is placed in
the cylinder and then mixed. Have students draw conclusions about the
density of isopropyl alcohol based on its behavior with oil and water.
4.)
Students will be divided into
groups of three. Each group will have 5 different samples of polymer. Each
group will use volume calculations to measure the volume of each sample
(using calipers). Each group will measure the mass of each sample. Place
all measurements in the student notebook. The density of each polymer will
then be revealed and the students can match their density calculations to
the key provided (See Polymers/public_density_key.pdf).
Students will also use four beakers containing different density liquids to
observe the behavior of their polymers and verify their results.
5.)
Discuss student findings using
Polymers/secret_density_key.pdf.
Ask students how they arrived at their conclusions and ask the students to
write down their conclusions in their notebooks. A brief discussion of how
a Galileo thermometer would be appropriate here. Warm the thermometer in
hot water and then allow it to cool—have students make conclusions based on
density.
6.)
Perform Polyurethane foam
experiment (See Polymers/crosslinked
Polymers 05.pdf.) Students will be working in the same groups.
7.)
Melt different polymer samples
and observe the changing properties!
Smaller
than the eye can see: How your computer is made.
Program
Module #2: Polymers (Day 4 of 4)
Materials List:
1.)
Notebooks, Scissors, Tape
2.)
PDMS
balls materials (See Polymers/crosslinked
Polymers 05.pdf)
3.)
Slime Materials (Unavailable as
of 7-20-06)
4.)
Silly Putty Materials (See
Polymers/intropolymer05.pdf)
5.)
Molds for PDMS balls (5-7)
6.)
Glitter jars (2-3)
7.)
Beakers (15-20)
8.)
Petri Plates
9.)
Meter Sticks ( 5-10)
10.)Rulers (5-10)
11.)HCl (Low Conc.)
Pre-Class Preparations:
1.)
Make copies of quizzes, handouts
2.)
Place students in new PAIRS!
Lesson Plan:
Objectives:
1.)
Students will gain additional
appreciation of how cross-linking affects the properties of polymers.
2.)
Students will gain an increased
knowledge of monomers and how they interact to form polymers
3.)
Students will apply knowledge of
the coefficient of restitution to polymers they have created using different
amounts of cross-linking.
4.)
Students will gain an
appreciation of the difficulty of etching tiny imprints into polymers and
relate this difficulty to the number of items contained on a computer chip.
Agenda:
1.)
Administer Quiz (8 Minutes)
2.)
Perform Slime and PDMS Balls
experiments simultaneously (57 Minutes)
3.)
Make thin, smooth silly putty
polymer and place on a Petri plate. (15 minutes)
4.)
Etch patterns in silly putty
using rulers and HCl (15 Minutes)
5.)
Discuss findings related to
etching process (10 Minutes)
6.)
Measure coefficient of
restitution for PDMS ball samples (15 minutes)
Additional Information
about the Agenda Items:
1.)
See Polymers/Questions
of the Day05.pdf. See the second quiz.
2.)
The class will be put into
pairs. Half of the pairs will work on making their PDMS ball samples. The
other half of the pairs will make slime. Both halves of the room will be
working simultaneously for about 25 minutes before switching. Be sure all
data is collected in the student notebook. See Polymers/crosslinked
polymers05.pdf for details. Once both groups have completed their
tasks, be sure that the PDMS molds are place in the oven for baking (At
least 30 minutes)
3.)
Students have had exposure to
this process before, have them replicate the data they obtained in their
notebook. See Polymers/intropolymer05.pdf
for details on the materials needed for making the silly putty.
4.)
Once a thin layer of the silly
putty is placed on the Petri dish, ask the students to etch a pattern into
the silly putty. This can be done by dipping a ruler into HCl and then
pressing the ruler into the polymer. Be sure that the students etch
patterns that have features that are far apart and close together, noting
the resolution of each type of pattern.
5.)
Discuss and findings of the
etching process by having students show specific examples of the resolution
they obtained from their different designs.
6.)
Follow the same procedure from
Day 2 of this module.
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