(C) ACD $$.RPT.( V 2.0 )as ??9s,OArial,Arial,Arial,Arial,Arial, Arial,Times,Times,Times,Times,Times,Times,Times, ^ CCDEuC@DECCCDECCCDECAFT 'Sample F01 (F:A-01), Fall 2002 Unknownsq 8EuCEEC>EC8EuCEEuC8EuCEEuCAFT 1 May 2003s 8ECEEC>EC8ECEEC8ECEECAFT D. R. Mowreyp &CCDCUCC&CCDC&CCDCAFTq Name Coder VDCV,DCVDCVDCV,DCVDCV,DCAFT F01 (F:A-1)l dSDCDCDCdSDCDCdSDCDCAFTqClassp DCԦDCtDCDCԦDCԦDCDCAFT Fall 2002i (DC HDC 8DC (DC HDC (DC HDCAFTqFWo a=DCa]DCaDCa=DCa]DCa=DCa]DCAFT274.6987n ( EC8!ECEC( EC8!EC( EC8!ECAFTqFormula ]3 EC]*EC]k%EC]3 EC]*EC]3 EC]*ECAFTC15H11ClO3q &CCDCUCC&CCDC&CCDCAFTq Solvent(s)l VDCVDCV5DCVDCVDCVDCVDCAFTcCDCl3z dSDCDCDCdSDCDCdSDCDCAFTqMass of Sample Usedn DCDCDCDCDCDCDCAFTw49.9 mgq (DC HDC 8DC (DC HDC (DC HDCAFTq Mass Spec.~ `=DC ECECa=DC ECa=DC ECAFTo297.0 [+23 Na]_____ESIv &CCDCUCC&CCDC&CCDCAFTqMass Spec Log #k VDCVUDCV DCVDCVUDCVDCVUDCAFTJ3613r `SDCDCDCaSDCDCaSDCDCAFTq Operator(s)w DCDCDCDCDCDCDCAFT Emily Dykhuizenk (DC HDC 8DC (DC HDC (DC HDCAFTqm.p.r b=DCECbDCb=DCECb=DCECAFT 118.5-120 Cu ( EC8!ECEC( EC8!EC( EC8!ECAFTqSynthesized byt ]3 EC],EC]k&EC]3 EC],EC]3 EC],ECAFT T. L. Johnsonp &CCDDUCC&CCDC&CCDCAFTq Key Wordsi VDCVU DDVDCVDCVU DCVDCVU DCAFT&??l dSDCDDDCdSDCDCdSDCDCAFTqNotes DCEDDCDCECDCECAFTXTwo multiplets at 7.53 and 8.20 ppm are 2nd order and have no defined coupling constants4CCODCODCCC 4ODCDCDCODC 4DC EC ECDC 4 ECDECDEC EC 4CCODCODCCC 4ODCDCDCODC 4DCDECDECDC 4CCODCODCCC 4ODCDCDCODC 4DC EC ECDC 4 ECDECDEC EC 4CCODCODDCD 4ODCDECDEDODD } &C@ D*DDVշCD&C@ D*D@ D&C@ D*D@ DAFTAcquisition Time (sec)m V D@ DVU#DDVDDV D@ DVU#D@ DV D@ DVU#D@ DAFTe1.5729n D+Ds^D&Ds~D@ Ds>D@ Ds~D@ Ds>D@ DAFT>13C{ D@ DsE+DD&DD@ DsE@ DD@ DsE@ DAFTNumber of Transientsj E@ Dy E+D E&DE@ Dy E@ DE@ Dy E@ DAFT8192| &C+D*D@7DVշC1D&C+D*D+D&C+D*D+DAFTOriginal Points Countl V D+DV!D@7DVD1DV D+DV!D+DV D+DV!D+DAFT\32768s D1Ds~D+DsD+Ds~D+DsD+DAFT\32768w D+DsE@7DD1DD+DsE+DD+DsE+DAFTSweep Width (Hz)o E+DE@7DA E1DE+DE+DE+DE+DAFT20833.33} &C@7D*DBDVշC=D&C@7D*D@7D&C@7D*D@7DAFTTemperature (degree C)m V D@7DVU#DBDVD=DV D@7DVU#D@7DV D@7DVU#D@7DAFTe24.0004C@ DgpD@ DgpDDCD 4gpD@ DD@ DDDgpDD 4D@ DDE@ DDEDDD 4CDDEDDE@ DC@ D 4C@ DgpD@ DgpD+DC+D 4gpD@ DD@ DD+DgpD+D 4D@ DDE@ DDE+DD+D 4C+DgpD+DgpD@7DC@7D 4gpD+DD+DD@7DgpD@7D 4D+DDE+DDE@7DD@7D 4C@7DgpD@7DgpDBDCBD C%?17yEcD1%?12EzD1%?16" EcD1%?13zEˈD1%?15EzD1%?14# EˈD1$?8ӗEzD1$?9jErӈD1$?7iE7cD1$?1~%E6cD1$?6(ELD1$?2(EzD1$?5cc/E LD1$?3Mc/EzD1$?42EcD1%?10L9EcD1%?11;  ?' 1I ? n ??? ??1? 1 ?  ? L  ?  @d z?  e ?  ; ;?   ?  { @?   ? 8 ?  ? J z?" 4 4J CDDED}JW CDDEDBB5B^B,+Bz$BuBB5BYBYB ˳BxB2BDBu0B\B~DBB&B4kBfsBTBB$4BӶBgB7KBBݳBB˶BѿBB|ʿB]BfB`B~BBB8BWBBNB}BCBrBBӺBB#B1BBVB_BBBXBB$}B* B0wBxBg\BôBDB%B/B9EB BB)B"BAB݌BϽBBBB락BB{B$#BrB7BcBmB;BϷB[(BBB BBhB|ټBqBмBжBBBBBXBuBBZBǶBMBB;=BNBBB7BBJBBӻB]BϵBBjBBBBuBGRBiBgBSBB)B"BB2VBBZBxBBĺB,BVBYxBBB(BzB_B"BUBVB;B B%B@BB5BLBBǹBweBNBwBTBBBBBBlBvB`:BBr1BuBBrBVB0BBzB4ҸBxB⻸B/BBRBBPҴBstBBVBhBAB(B^@BٷB-BB BƷBBr@BַBBBzBB# B܄BHBBzBֱB/B#B BBB`BTBB~̳BVgBBifB2B HB$BZB B BXBRBqڤBBŤBmB[BgBB$:B|B 5B|WBŶBJBB'B˶BB@BBGBףBQBȣBSBGB%BBg˶ByBFBgB\BdBB?B9B^,B´BB0BBZBBNBӳBf2BB'BnBJBBcB08BBZ״B賠B)4B B3kB=BlKBtoB-TB4PB#BEB*rBj5BٴB0BB BEkBBBԟBۻB༟BͶBċBڷBBBZB:BQBBBDMB^Bu5BrB(B^BwBBBcԶBΞBilB'BBB05B|uBBfBB6YBJB2BiB&B:صBBBoBB;ٝB(B_ǝB B+BBbBByBzBWBdBQB3Bw>B~B$(BcBBw8BBBcʜB/BB?BBBєBryBwBbB`BM޷B5BB/(B;Be B׃B BKB7BζBΛBaҴBB,B'BB^BVgBzBB]B B5BCB2B4жBBCBBC]B/B϶BΚBO[B,BBnB:iB"wB3-BiBʴBIBMBFBQB>B.B B.BEBEBXߙBBʙB/TBBz6BB@BB B2tB)BMBfoB):BѷBS%BB BBCBʜBn٘BB@BTqB睘B}(BB/B6wBBiBqݴBg_BBK.B5BBBB(WBݗB!BӗB۶BDzBBbBBBwB`Bg-BPBB1@Be>B5BB B%B'B6BB6[BvߖBYvBB|%BBB B BcBBPBB/BBٔBeBൔBB5BBʁB̴B{B~BXBnB(B77B"BzB(B8BFB@BB+׶B֓BδBBBB4BB<~BQByBYBq߶BZ@BeBBBD BBBBْBBB݄B}BpBB/bBswB{XBrBB!aB-ȴB;B߶B2BBB3ɴBBx2BB:BʑBBBBBB聑B6BvBBPOBmBt=B䘴B B)BBYBBB*B2BBBBkB턐Bz޷BkBiBVB\qB~=B;B 6BBh B IBB9BAޏB&B_ϏBE{B}Bd>BIB\BBͳBbBfBXUBB=BB%B>dBBrBB=׵B?BQ1Bo̎B EBB&ĶBBVB BBvBjBbUB7EB=BδB+BBB~[BB=BߍBB'BGBԟBBB:BqB϶BSBQB@BB=BBJ'BB BKBBBwҌBBBζB뙌BtBBuBYBJɴBSB;B*ΆBiBBOBFB2iBɉBDBqvBB+ZByBUEBBBq\B BcB#BBH΅BĶBTȅBBBmB]BBlB2BfBBIBfB /BNBCBBB[BBCBτBHBB%BŕBzBBY׳By|BwfBoBmB:BZB!BNUBBeBBVصBσB0BB1.BB`BÛBnBpBɴB=`BԶBXBVB5BB!/BB BVBB?BBBnQBςBB,BBڕBB#rB]SBpBaBLB1B'BA)BB:BBB(BLB B8 BB^B0BBBBmBBUB/BRBᕴB;ByBB?#BB뱴BJB2BŀB BĀBbBܞBBBBmBVBRB!BEB гBvB(BB;BBEBBB;BuѶBRBB'B@ִBFB=B~BrLB~BӴBQ~BٔB1~BNB~Bm̴B}BщB}B]yB%}B҆BR}BVB&}B8Bl|BZB|BhPB/|BBY|B-BL|B8B{B"B{BKB{B2Bu|{ByBp{BXB>{B5ǶBzBB+zB:BnzB;B^zB BHzBByBByBmBBgyB*B[yBo*BFyB‹ByBJҶBxBFBKxBBsxBQBOxBv˶B2/xB/BwBRBwBdBCwBBmwBBOwB"ߴBvBȶB#vBNJBZvB:B^vBnB(>vB.VBvBkѳBuBDBXuBXBpuBB GuB92BuBS_BtBtBfBtBB#sBóB~sB8B|sBNڶB_sBB(MsBBrBpBvrBLBrB23BmrB۳B{)rBtBrBBqBBqBBЂqBtfB$YqBV$BpBRдB5pBζBpBoBpB8B#_pBBpBBoB BoB\BoB{BQMoBjB]GoBB#oBg-BnB^fBʔnBGHBnBﾶB2nBJB nBqB`mBBfmB8BmB/B(kmBpBeMmB2B:lBĈBlB: BlBôBlBS?BDlB ŶBkBCBBhkBcCBkBBkBYӶB8kB{/BkB!B*jBrBjBBjB[FB;qjB'B#jBBkiB BiBB̬iBvB!iB,EB/iBw.B iBBhB9aBܩhB?Bt_hB ³BAhBwBhBmBBUB{̳BUB BCUBBlUB6B9UBX>BUBBGTBBSTBBTBB(lTBBTB۶BTB2ѶBSB&ABSBʴBЛSB׶BESBvѴB!SB^B$RBKB§RBzBRBeBT`RB+BRBdƶB4QBvB١QBBQBTBd]QB@B0QB"B QB~BKPBuaBPB)RB8xPBlABQPBbB!PBѶBCOBQ\BխOBVϴB0OB@BKOBB9OBB-OB\BNB-@BNBaB^oNB_B0NB]BMBBMBvB˼MBBJ~MBpB]MB"B7 MB?BLBRBLBӴBpBABBABBlAB*BD@AB."BAB"B@BPBl@B9B^@B*B[@B/Bs.@BBZ?BB?BtʴBӁ?BҾBj?B˿B?BB?BBo>B5_B>B ߴBg>BA޴Bu7>BB>BjBJ=B#B=B5B϶B4BôB4BBas4BUBzg4BrOBU4BB*4B0B3BˉB3B&uBG3B&B@3BKBL3BNBw2BTB-2B߶B32BB{p2BB&2BoB1BHB1BPB71B+Bd1B̶B##1BB0BDB0BB0BBa0B;BX0BW2B=0B}B/B^kB /BsGBj/BƓB>/B B //BPB.BneB.BmB.BBg.B2AI .BB-B׳B-BDBN-BTBy-BB:,-B̓B-BNB,BGB9,B BX,BBD,B\a@&;,B@+BdB+BWBb+BRBS+BɶBC2+BMBt+BB+B;WBf*BAB|*B_B`)*B.B *BU$B)BB)BBw)BB)BУBE;)BEBu#)BB(BB(BB \(B9Ba2(BB (BͶB'B|B'BjBj'B|Bg'BZAB'BZ~fB'BhB^&B|B˅&B'B&Y&BB&BB%B0B%B5ٶB%Bs$B܂%BPBVG%BB$BiPBB$BB$BAB$B-0BYJ$B3vBkA$BB #B;B.#BB#B ȶB#BvB]M#BB#B6B]"B߶B"BăBt"BoBI\"B4B "BFBO!BB!B|B!BBlP!BfB!B8۳B!B?Be BB-t B>BdY B B, BB BsBDBB֣BiYBBݛBJBB8BBBO BάBVBBBGqBAB/BciBBrBMB϶BBCCB.BBJBB9Bj+BbBBBMǶB BEB>Bw|B#B+BsBzBڵBdB/BkaBN}B5aB8BQBBvBBBBTB.B BMB(BBQBBpB*BBuBIB.'Bb}BiB-BdBbB˴B$B_BZBUB;BcB*BsB5BOBBOB^B!BhBABbB϶Bc BRڴBuB̳BB5B2BBPBBCBUBB%BBJBfBBwBvBVB}BBrIBBBRB>BtBIζB30B^BdB}ѴBBB9BKB>B}BYBBJ*B$|BBIWB BB0BNBqBTBB3BCBH0BkBBdBBrB}BfYB'EBROBB$B BʠB,BxBB=BeBBI9BfBBVBBBOB7B}B7uB ]B=Bs*B7B B2B)B_0BBBX<B@Bi3B:YB BB BֶB BgBc BBDK B7B B/=B BB B=`Bz B.ܷB`B B qB$ BKʹB BBk B4sB͏ BXB(c BٴB?W BxB B B B~B BjB܌ BB6 BIzB BB BrB B,Bž BBB` BB' BKĴB BBBBǡBB?BD*B$BB BOBQBBBBB( BEB2BBBnBBBf BB.|BBoB`BBBNBBBB,"BBBwZBB9BBBVBnBxBB0BB]BsfB B-B BTBôBBBڶBUBkoBK&B3BB?B:BuB(BV~B#BuoBnBfB5B(B BBBۿB٦BzrB B`B䳶BHBBSBɶBAB\A\BABPA)˳Bh8AOB@A̷ByA%0B@PAB@A5B'bA^nBABA7B8A1BAbǴBڑAnB8A,BA")B>AtBAxBA״BDA(BA}BA[B3AwBpA/BKnAnB,AB?A8B,AOBTAwBA>BEABfBAyB,ABAEBQA˛BfAƷBAd!BrtA8BAA B|A|BABA{BcA,B%'AqBABtAbBl AYBA;/BhABABPA1B?AԳBARBhAMBKAKBABqABABAB QA$BAdBAB WAB-A BWABAMmBABtAQBA$BBKAj'BA€BA=*BABAMTBALBĒA텵Bn?AX{BzASBAABAʸBْABjKAܶB!ABgQA#BAƘBZAO*B!A{}BAYBAB3A:jBAo$B-AB`ABmAɶBlcA;B;A䨶BxABWAe"B, AݟBAB7 AhBAB7A|B"AvB޼AB(ABAB .AѶBJABAtBlAU4BAtBArBATB!AEB\A0B4ABABtAHBYA;sBABL(A=UBAĴBcA|SB&@A׶BA0PBA,BAB{ABuABj(AB{A0B9FA빴BAسB^A/BAcBpAQB{AbBWA|BA/ضB>RAvBTABAzfBA BABGXAlB A$BABANBvAwBAdAcB(AQBҟAJB4pA?B(A/ B>pAB:AyBAwBAL8BSAcBAȖBRA6̴BAB-A>BAMAĶB AܴBABTʱABA;`BAqBkAXݶBAB5A-BA,B\ЯA~B+kA|BrʮA0BAABApFBAyBꔭA-ʶB5AdB$}AB1wAaBb_ASB栫AB)AEBЪA&BAAB;A B\AثB[qABШA9BԸAB}eABʧABAB*AB2ANpBeA}B0A\B;AOKBHAnBĤA@BjAgBܣABiAEBsABeA/sBABs ABA B|AdBcA}aBA´B ABA\JBSAضBAB A(ɴBeAKB.BAZBAnBNA~BAGгB}A8 Bf0A BABA&BABA!Bn6AִBA+BAJB0A.BAȶBA~B_HA BABдBlAyB*ABxAnB$ABAݵB@A B*A}BAB3rAiB*AYBaݓABa`AB#A9B٧A\̶B A媶BőA BAϴBBA6BֳADBNxA|ABŏAB뭏A\+BTABюA5BprA_ B> AlBA1BZA$B%AɴBGABNȀB׋A۶B,Ac˴BZA*BA0BfAbBZA̴B(AVBZA'BMA@@BJA EBAҶB ƇANtB IA&B݆AY0B:A4BA B.AB\ASBxAB҄A9B*IA,fB~AsBA= BxA;oBY7ABA϶BAॴBUABIIA^zBkAB͊AdrBڄA8`BA{QBtAB{3~AjB}AeB|A4B{AB!{A_BtKzA#ٶB~yANB%{xA+JB'xAYBwA[ǷB=uwA$BWvA׷B-uAUBuA]BԶtAWB9sAGB3rAzB(rAtBpAABoA,BQoAg?BnAaBmAB:mAXB(lA\]BclAĺB kAB;jA:ݶBb(jAŴB+LhAƷBgA4_BefAƶBV@fAA)BfAT`B=ReADBdAhBcAGB:cABBbA&BgRaAB|`AQB@`A3hB_ABͫ^AKiB]A B9\A&жB@\AdzB߷ZAZBdZAվBKZApB޽YAʹBWA WBjWA˴BVA)BdVA~B5UAKB\UAB%;SAMBRA۹BRAABQAB^QA|1BT5PAHBOABNA|öBYNAneB{)NA_ӷBpLAB KA BȔJAxBJAɪBIABIA=BHAiҷB GABFAjB EAE9B EAB0DAz2BuCA+B/CAs״BBANڶBSAAYB@ABL?AB_?AdBs}>AhBAbBA(kBSDA}fB!bABAGB@dB@B@΢BRe@zB@/̸Bd@ Bڲ@)B@=Bk@ĵB5@ zB@˴B_@tȴBs@pB@4BT@ gBw@^h@qXBb@>B%a@BضB9]@ƳBJ)[@BX@BW@cBR@/BQ@B}L@B_H@BfC@B>B@XBNA@,BN6=@B&Z;@$B}9@}kB4@B1@teBG.@aBE-@$ֵB~'@3+B%@Bm"@nųB@yB@NB@sBva@GB"_ ­+C/ҽ>q?# #ABABӵBر-A 189.91(10)#8A,B8A,BӵBP;@ 164.43(8)# B,B B,BӵB6A 155.29(1)#'BZ~fB'BZ~fBӵBh)B 134.00(15)#^)*B.B^)*B.BӵBH*EA 131.76(4)#%;,B@%;,B@ӵBтB130.26(17, 13)#D,B\a@D,B\a@ӵBB 130.23(3, 5)#g.B2Ag.B2AӵB'B128.68(14, 16)#:7B׭A:7B׭AӵB]B 122.28(6, 2)#VB\qBVB\qBӵBvA 45.80(18)VuBVuBXB Chloroform-dCDDEDCDDED Chemical Shift (ppm) Intensity   C@ND`D Do"No.(ppm)(Hz)Height 145.803453.60.34372122.289220.30.78143128.689702.90.78524128.819713.00.12535130.239819.91.00006130.269821.80.95737131.769934.90.13928134.0010104.10.37609155.2911709.50.129010164.4312398.70.089711189.9114320.10.1226uBEJEEKFNo.AtomExp. Shift (ppm)Calc. Shift (ppm)Difference (ppm)11845.8045.4700.33126122.28124.080-1.80032122.28124.080-1.800414128.68129.900-1.220516128.68129.900-1.220612128.81129.630-0.81573130.23131.430-1.19985130.23131.430-1.199917130.26130.1600.0971013130.26130.1600.097114131.76130.3201.4381215134.00134.600-0.599131155.29157.620-2.328148164.43165.200-0.7681510189.91189.4600.454j s~D@ DsDDsDDs~D@ DsD@ Ds~D@ DsD@ DAFT:F01*u ??u,NArial,Arial,Arial,Arial,Arial,Arial,Symbol,Times New Roman,Times New Roman, Arial,Times,Times,Times,Times,Times,Times,Times, ^CCDEuC@DECCCDECCCDECAFT 'Sample F01 (F:A-01), Fall 2002 Unknownsq8EuCEEC>EC8EuCEEuC8EuCEEuCAFT 1 May 2003s8ECEEC>EC8ECEEC8ECEECAFT D. R. Mowreyp &CCDCUCC&CCDC&CCDCAFTq Name CoderVDCV,DCVDCVDCV,DCVDCV,DCAFT F01 (F:A-1)l dSDCDCDCdSDCDCdSDCDCAFTqClasspDCԦDCtDCDCԦDCԦDCDCAFT Fall 2002i  (DC HDC 8DC (DC HDC (DC HDCAFTqFWoa=DCa]DCaDCa=DCa]DCa=DCa]DCAFT274.6987n ( EC8!ECEC( EC8!EC( EC8!ECAFTqFormula ]3 EC]*EC]k%EC]3 EC]*EC]3 EC]*ECAFTC15H11ClO3q &CCDCUCC&CCDC&CCDCAFTq Solvent(s)lVDCVDCV5DCVDCVDCVDCVDCAFTcCDCl3z dSDCDCDCdSDCDCdSDCDCAFTqMass of Sample UsednDCDCDCDCDCDCDCAFTw49.9 mgq  (DC HDC 8DC (DC HDC (DC HDCAFTq Mass Spec.~`=DC ECECa=DC ECa=DC ECAFTo297.0 [+23 Na]_____ESIv &CCDCUCC&CCDC&CCDCAFTqMass Spec Log #kVDCVUDCV DCVDCVUDCVDCVUDCAFTJ3613r `SDCDCDCaSDCDCaSDCDCAFTq Operator(s)wDCDCDCDCDCDCDCAFT Emily Dykhuizenk  (DC HDC 8DC (DC HDC (DC HDCAFTqm.p.rb=DCECbDCb=DCECb=DCECAFT 118.5-120 Cu ( EC8!ECEC( EC8!EC( EC8!ECAFTqSynthesized byt]3 EC],EC]k&EC]3 EC],EC]3 EC],ECAFT T. L. Johnsonp &CCDDUCC&CCDC&CCDCAFTq Key WordsiVDCVU DDVDCVDCVU DCVDCVU DCAFT&??l dSDCDDDCdSDCDCdSDCDCAFTqNotesDCEDDCDCECDCECAFTXTwo multiplets at 7.53 and 8.20 ppm are 2nd order and have no defined coupling constants4CCODCODCCC 4ODCDCDCODC 4DC EC ECDC 4 ECDECDEC EC 4CCODCODCCC 4ODCDCDCODC 4DCDECDECDC 4CCODCODCCC 4ODCDCDCODC 4DC EC ECDC 4 ECDECDEC EC 4CCODCODDCD 4ODCDECDEDODD } &C@ D*DDVշCD&C@ D*D@ D&C@ D*D@ DAFTAcquisition Time (sec)mV D@ DVU#DDVDDV D@ DVU#D@ DV D@ DVU#D@ DAFTe2.7197n sD@ Dr DDrDDsD@ Dr D@ DsD@ Dr D@ DAFTCommentjD@ D@DDǠDDD@ D@D@ DD@ D@D@ DAFT:F01k D@ DǀEDDDD@ DǀE@ DD@ DǀE@ DAFTDate{q{E@ DqEDqEDq{E@ DqE@ Dq{E@ DqE@ DAFT425/09/2002 17:16:21p &CD*D@ DVշCD&CD*DD&CD*DDAFT File Named DDW@E@ D:DD^ DDW@EDW@EDf DDAFT \\babylon5\nmrdata\UWChem Unknowns\2002-fall Chem636 unknowns - chemsketch+chemdraw+automation data - from cgfry local nmrdata\F03 - Emily Dykhuizen\SB250F.102v &C@ D*D+DVշC&D&C@ D*D@ D&C@ D*D@ DAFTFrequency (MHz)mV D@ DVU#D+DVD&DV D@ DVU#D@ DV D@ DVU#D@ DAFTe299.87n sD@ Dr D+DrD&DsD@ Dr D@ DsD@ Dr D@ DAFTNucleusiD@ DǀD+DD&DD@ DǀD@ DD@ DǀD@ DAFT,1H{ D@ DǀE+DD&DD@ DǀE@ DD@ DǀE@ DAFTNumber of Transientsiq{E@ Dq E+DqE&Dq{E@ Dq E@ Dq{E@ Dq E@ DAFT&32| &C+D*D@7DVշC1D&C+D*D+D&C+D*D+DAFTOriginal Points CountlV D+DV!D@7DVD1DV D+DV!D+DV D+DV!D+DAFT\16384s sD+Dr D@7DrD1DsD+Dr D+DsD+Dr D+DAFT Points CountlD+DǀD@7DD1DD+DǀD+DD+DǀD+DAFT\32768w D+DǀE@7DD1DD+DǀE+DD+DǀE+DAFTSweep Width (Hz)nq{E+DqE@7Dq3 E1Dq{E+DqE+Dq{E+DqE+DAFTw6024.10} &C@7D*DBDVշC=D&C@7D*D@7D&C@7D*D@7DAFTTemperature (degree C)mV D@7DVU#DBDVD=DV D@7DVU#D@7DV D@7DVU#D@7DAFTe24.0004C@ D8loD@ D8loDDCD 48loD@ D8D@ D8DD8loDD 48D@ DDE@ DDED8DD 4CDDEDDE@ DC@ D 4C@ D8loD@ D8loD+DC+D 48loD@ D8D@ D8D+D8loD+D 48D@ DDE@ DDE+D8D+D 4C+D8loD+D8loD@7DC@7D 48loD+D8D+D8D@7D8loD@7D 48D+DDE+DDE@7D8D@7D 4C@7D8loD@7D8loDBDCBD \  CIDEEgDD@XD CIDEEID CIDEEIDAFT   1H NMR (300 MHz, Solvent) d ppm 4.7 (s, 2 H) 7.4 (d, J#=9.0 Hz, 2 H) 7.5 (m, 2 H) 7.7 (m, J%=7.9, 6.8, 1.5, 1.5 Hz, 1 H) 8.1 (d, J=8.8 Hz, 2 H) 8.2 (m, 2 H)C%?17yE~D1%?12ED1%?16" ED1%?13zED1%?15ED1%?14# ED1$?8ӗED1$?9jErD1$?7iED1$?1~%ED1$?6(E{jD1$?2(ED1$?5cc/E |jD1$?3Mc/ED1$?42EKD1%?10L9E]D1%?11; P ?' I m? an a?O? ?m?  m?  L? L  ?  d ?  Ie ?   ?  a a?   ?   I? 8 ? K ?  ?"  N CDDEENW C DDE0 EBCBB BBKBBBmBBz|BBqBBTB)BIBSBtBB BQB5BBBBBBOB2BBBUBBdB B_B[B.BBBsBBuBBUBB9JB?BE"BBBBBB}B6BB4BյBzBBB wBB~nBoBcBBk5BBq!BWB B BBBBdBLBBBBXBB\B7B QBuBEB6B3B#BYBwBBB޻BBͻBiB襻B-BBBlBBrMB B-?B"BB&BB'B!BB'޺BBϺBBYBBBBqBEBMfBqBFBB0B BBB'BMBѹB9BùBBЬBBBBBB.kBqBNBB:BB#BBBBSBJBZ߸BBfBFBBxBZjBBaBB;YBBJBB( BBB_B޷BBAзB%BķB$B(BBB8B;oBBUBB(6BBTBBZ BBAB{BgB)B̶BBNBBBB;BB"`BB ;BBz2BBBsBgBBNԵBdBtѵBWBB֭BBЭBBE­BHBB\BQBB^rBBPBBAB/B2BBBBB-B?BB&ǬB%BRBB9BB?wBBnBBIBB,>BBBXBBnBBBwëB-B~B[BϕB-BkvBBkBPBqbB'B?BBBXBBBBB֪BkB_B>B՗BBBBBxdBIBJB%BGBBFBBkBBxBBBBBB֭BBⅩBBxzBB_UBB>BpB*BB- B-BB5BɨBBB!B*BrBB㛨BJB|B!BqBB!IBBlCBWBBBBUBfBBܧBBMBJBBBʌB)BG\B0BPBB.B@B(BBBfBBB B ŦB+B.¦BSB4B~BfB5B(aBB>BfB0BƅB-BIBGBBBxBTեBkBɥBBgBBBBsqBB/cBBa8B>B2BkBBBߤBbBѤBBgBBئBBB BTvB6B[bB BHBB7B}B.BBzBBB% BͣB BHBkB뀣B: BrBBJB?BDBBBBB B6BDBBBCB5 BBBnݡBB0B` B\B BCBBh|B BQB B5B B=BsBB BBB٠BB\B>BBBىBSBo~BB _BBPB Bc1BBiBBBLB B9BǟBSBBBCB3B+BB][B?"BUBBABGBJ"B:{BBOBBUBDBBiBBBB捞BBc]BBDLBzBp5BfB*BBBBBBBB%ƝBTB BB폝BBDbBBYBB4BT B BpB B@BBdB͜B!B BB^BW BBBjuBUBwMB B BB?B0BBBcBBq B՛BBϛBBBQBԖB B&}BHB,iBBDBB8Bk Bd*BBB9BBi BԚBBB BEBBR|B B_B B9WBk Be@BBB[ B B B^ߙBfBٙBBBB⚙BBX~BBpBPB?YBB?B4BRBnBBBBBeB!BⰘBiBBB:B!B}BBMB B'JBjB~Bn'BBB!BSBڗBBBBõBB@B>YBfBwbBTB5BQBB_!BBB&BBBMBBΖBBfBB!BBBB.bBm B4NB BA&B|Bf#BBB#B4ٕBBЕBBBBץBBBeBZaBBSBTBABLB(BBBBBBBBBBBB B$BnBB]BBG>B~B$BB BBBBBB)B B/BBBBayBCBHTBBt=BBBB BBaBBْBBŒB>B/BBBBuBBHjB&BMBB"BBBBBB)BBU͑BBǑBBBBBn}BDBrBB{UBDBABB"B BOBBUB#BBBBBhBBB7B tBtB=IB BbFB1B)B+BBZBB|B׏BBBBIBBVBB\pBB=_BBBBB+BBBoBB8BǎBBBBVBBƑBBzBBi^BBRB`B +B,BBBBBiBB+ǍBB渍BBBOB$fB9BZBUBCB~B1>BB!BeBBYBPڌBB1ɌBB8BBBBB%|BkB+hB@B8@BB:B_B>,BBBB|ًBB8ˋB BŋBBDB BBoBWgBB^B7B3BOB1B=BBbBBB؊BBEB/BBBᙊB BoBBfBcBEDBB*BPBQBBB6BBBEωBBBB盉B BsBBeBzBkWBB:BBBBeBBB߈BB&ԈBB BlBȠBNBBBbBBPBgB :BBBuBB<BB#BۇBB3‡BBBpBBBxBBRBABABXB99BVB B!BBB_B6BBBeBBLBBkBB~]BcBFBBl$BBBBBSB݅BBֺBY!BB@ BBBsBvB\BBKBBG=B.B4BBB`BB_BքBBBB4BK BʃB B~B3BEB1BM?BB"BB4B B؃B1BMʃBBBBB%BwB!BcBBsRB0B.DByB`BBBBB^B(BEBƂBB5BBm|B'BvB*BIBB@BBa/BBBB)B}BBBBBB@BBfB/pBBPBTB?BBnBYBN BYB BB5BiB<ӀBBnBVBޟBxBNBPBcBBUBBO"BB/BBBbBBBBaBFBB>BB!BB~B5BF~BBp~BB7~B BM~BB}B B }BB4{}BCB1}BBy}BB|BB|BB|BB;|BBy*|BB{BXB5{BBs{BBmh{BBNW{BMBHzBBzBBszB|BKzB]B#zB<BtyBSByBByBBOyB)B-yB BxB{BصxBB0xBBkxBBCxBRBxB=BwB{B0wBHBHwBB ,wBBvBBOvBB0vBBvBBV]BVB']BBʯ\BBև\BUBN\B@B:2\BSB[BB[BCB![BBd[BBS[B;B[BBZB BlZBBZBBMZBB4YBB`YB BYB4BĐYBBGLYBB YBBXBB"XBBGbXBKBEXBB#XBBXBB/WB8BWBNBlWBB3WBBOVBBVBBVBBDVB1BnVBTBUBB[UBBU|UBBbTUBwB!UBBTB~BTBBޮTBBTBB+TBBSBB*SB0 BSBBcSBfB*SB B]SBBVRBqBcRB<BcRBBQRBB>$RBBQBBQBcByQBBEQBBQBBPBBpPBB|rPBBUPBgB3PBBOB2BOBB}OBmBZOBB!OBBNBBNB!B}NBB,CNBBNBB NBBMBBՆMBBwSMBBXBMBFBLB BLBBLLBB9GLBB6LBBqLB BRKBBLKB^BhKB]B)KBB~JBB@JBB JBiBVJBB':JBWBJBBIBBIBhB[IBVBDIBvBAIBB"HBBZHBBfHBzBkHBB HBByGBB;GBB(|GBBA,GBBNGBBѿFBBFBBݗFBBT{FBB6FBaBEB BEB\BݭEB#B;EBBEB BDBB)DBaBDB BbDB=B$DBBCBx BCBhB̠CB BbCB5B\4CBBCBg Bh CBmBbBBg BxBBB BBB AB!BABBABBOABBI'AB%BAB%B@Bn,Bں@BB_@BBY@BwBv&@B4@?BWBǗ?BVB?BsB 1?BTBW+?BzB>BBQ>BBKi>BQBc>B}B$>B#B=BT+B=BZB+n=B*$B8F=BB:=BBBg5B"BZ5BBg4B"B4BB4BBml4B@$B94B #B;"4BB˵3Be#Bw3BBe3B'#B[I3BBt2B"B2BB\_2B"BH2BBB2BB 2B!B1B|#Bƀ1B_B01B]B1B B61BBo0BL#B0B~"Bn0BB 00B"B0B-B{/BB/B!Bm/B!B F/BB /BB{.B!B.B"B=.B BJ.B1"B4.B'B}-BB-B#B r-Bu"B8[-B:Bp-BB-B,!B|,B"Bk,BB%8,B!B} ,BB+Bd!BK+BB8+BhBS+B B1+B"B?*B'BΑ*BBd*B"BX*B "B0*BBj)BB,)B!BΧ)B!Bs(B#B#(B B(B"B'BBr'B~Bx'B4&BJ'BB:&Br!B&B!Br&BBw&BE"B8&BB%B+Br%B B%BB!q%B#B`%B BY2%BB $B="B$B)B{$BBj$B!B#B B5#B<B#B!Bz#B=BR#B B#B&B"BWB#"B B"B!BW"BB"BB!B;#B!B"Bz!BBgb!BrB4!B"BB B"Bz B1B[ BBr B BJ BB B;"BB B\BB*lBBb-BR BBBB}BӯBB_BE!BIBB1BO"BB BB BSB!B+BrB| BA"BBTBBBzBBP6BB]BV!BJBW%B+BBBBFBWB BBBBBZBqsBBhB$B.B BBoBBBEB?B۔B"B .B BBBB8BqBC B^fB BOBBBBBBBM B~BVB,2BBB BBBBBdBB.HBL BBg B'BB`BBuB"B;B BBBBE!B֡BBB B:LBBBBBf BlBjBMB B:bB?BSB B`BBB BĔBBDB B"B B#B]BzBBBB)UB B DBBnBKB[BBBB6CB[B BBBBҮB0BކBB pBBnBBBBB_BBqBtBB0BB B B< BpBU BaB B BQ B$B BkB BB BB BB BB B Bv BiB BY B} B BD BBJ BB BB BB BBC BjB8 BB BzBc BB BLB]e B'Bv B. BBBBB2B_ BXB/BBB&B BBuB oBBRBBBeBeB;B?BIBkBB-]BBXFBOBBBBB?BBLBBBBB.!BB BBBxBM BDBB`BBBBBBfBRBTB B(>BBlBLBBBYBfBT=BaB BBBLBZB|BfBB`+BBABBBBBBBBszBB$BBABAHB AaBkABuABeABcA{BA5BۊAB`FA "B:A$BAHB.A#BABrAB(AJBAmBUABABABTABAB[SABsAFBOABCABA~B:AuBAUBAfBA<B PAB79ABA{BV`A^BIAB0ABvAB7AdBABGABA5 B8AB|*A(BDAB#A@BABeABABA#B3rAXBw ABAdBABABYABAB%AbBABABxcABlABsANBZhA)BrAGBzABABZABfAByA BgABABABBA'BOABGAdBAAB)AB}qAtBѳA.TBݺA#BjAbB9AlmBMAGB6A BAKBNiA BAz*B@A=B6ABbίA?B(#ABޮA?BA8BJJA BAHBA B(AB|ABABrAB ABA"B6AWBZA?BDۣAB0ABUɢA BkyABY@ANBAB9A+BޠABUAhBAmByAB;qAB.A6BZAW BA$BAB+ABA B]AkB ABԛABAxB2A/!B Ai B ABAIB>A B'AZB#qABeABABA:BAB7֖AB+A-BoAB RA B/A%BABjbAK B“A=B4ABABRޒABwABpAxBqA9BNA>BA/B-AMB#֏AEB峏APBAA'BAyBAZB_$A}BAz*B)yABA"B ~A3B{AᲿBҋAB'AB0A)B"ZABNAJBAhBDA BACB̳A_B>6AlBBAB]]A Bw ABABmA<BAB_ApBAB%ބABABAWBK|ABABBA%B,AԽBʁA")BzAB*ABAEB/AB2$AB$~A BP~A B5@}ABa)}AB!{AB`{A8B8zAz$ByAq&BByABvwAT BwABKvAB6uA.B>guABsA"BsAA"B;HrAaBg1rABzqABLpAB8)oA&BdnA BmA'BImAu'BelABkAw!BjAu(BEojA'BjA B4hA"BgA(Bm9gA'BkfA~#BbdA7'B HdA?!BbdA"BFcA0'BzbA%B3aAB_`AWB_A>B2_ABϩ^A B7j]A!B\AB[AB,ZABXZAB4YA#&BEXA &B!WA^"BpWA"B^VA (BUA&BcUA BJTA BZmSA'B6RA(B¤QA"BPA&B7PA!BOA&BXNA"BCANA#BwMA&B7KAB&BOKA!BJA=&BIA'#BYIAt!B^HA%BGA&BGA7"ByEA8%BEA!BDA'BCA#BAICA~'BAAA#BAA%Bn@A%!B?A%BN?AZ"B=AQ(B=A"B @ BJ @"B/^@# B@c$BA.?$BS?aB2?5#B?iB}?z!B&6?4B?B?#B?B? #BΈ?BO?c#B׵?B?j$BSG?#BTݡ?B4L? "BW?B?B9?#B[y?B ?[#Bn?Bih?$B@\?$"BBK?TBA?$B3?B#?B?X"BP?BR?"$B'>B3o>b#BV> B9Ǚ>#Bzz>#BL>BI0>0B-=D$Bj=#BT ˻}B@B" Abּ33?##ABABB@?8.20#ҋABҋABBC@8.08# ~A3B ~A3BB A8.07#A"BA"BB^A8.06#`$A}B`$A}BB`/ A8.05#AZBAZBBA8.04#AA'BAA'BB7^@8.03#ABABB}@7.70#bABbABBiA7.67#>A[`B>A[`BB@qT@7.66#\۪AœB\۪AœBB@7.65#6AMB6AMBB0f@7.65#$ApcB$ApcBB4@7.56#AKBAKBBUA7.56#jAbBjAbBBA7.53#GƳA)ָBGƳA)ָBBۢ@7.53#>AB>ABB A7.51#lABlABBp4@7.51#νAn BνAn BBA7.39#WAݱBWAݱBB2 A7.38#A5tBA5tBB>A7.36#ABABB@?@7.35#u&@B4@u&@B4@B>BB4.72sѵBsѵBWBTMSJS?BAB4@M05(18)_ AAB M00(13, 17)[AuAZB M01(3, 5)7(A˘An B M04(6, 2)A6=ABM02(15)yA.AbB M03(16, 14)C DDE0 ECDDEEcD#E}D| E:BA!JB-BשB(B:@~B>p@G?B!ABiUDz$E[D E9B&jAqB*&ABs/B.jDB%jB,BWB @FBe>?3AAJDEPD EpWB0OA BB1A@BeBAB~1OBA~BqA.eBU*%AeKBW>t?bAeAZADpEGD EBaAPBA;AB2B4SBnB4Bf”B桸@킲B??AGHAZDDE"Do E6BL΋AgBK BlBpQBNBK΋BBB?gG?;A҄A Chemical Shift (ppm) Intensity  & ??W&, MArial,Arial,Arial, Arial,Times,Times,Times,Times,Times,Times,Times, ^ CCDEuC@DECCCDECCCDECAFT 'Sample F01 (F:A-01), Fall 2002 Unknownsq8EuCEEC>EC8EuCEEuC8EuCEEuCAFT 1 May 2003s8ECEEC>EC8ECEEC8ECEECAFT D. R. Mowreyp&CCDCUCC&CCDC&CCDCAFTq Name CoderVDCV,DCVDCVDCV,DCVDCV,DCAFT F01 (F:A-1)ldSDCDCDCdSDCDCdSDCDCAFTqClasspDCԦDCtDCDCԦDCԦDCDCAFT Fall 2002i (DC HDC 8DC (DC HDC (DC HDCAFTqFWoa=DCa]DCaDCa=DCa]DCa=DCa]DCAFT274.6987n( EC8!ECEC( EC8!EC( EC8!ECAFTqFormula]3 EC]*EC]k%EC]3 EC]*EC]3 EC]*ECAFTC15H11ClO3q&CCDCUCC&CCDC&CCDCAFTq Solvent(s)lVDCVDCV5DCVDCVDCVDCVDCAFTcCDCl3zdSDCDCDCdSDCDCdSDCDCAFTqMass of Sample UsednDCDCDCDCDCDCDCAFTw49.9 mgq (DC HDC 8DC (DC HDC (DC HDCAFTq Mass Spec.~`=DC ECECa=DC ECa=DC ECAFTo297.0 [+23 Na]_____ESIv&CCDCUCC&CCDC&CCDCAFTqMass Spec Log #kVDCVUDCV DCVDCVUDCVDCVUDCAFTJ3613r`SDCDCDCaSDCDCaSDCDCAFTq Operator(s)wDCDCDCDCDCDCDCAFT Emily Dykhuizenk (DC HDC 8DC (DC HDC (DC HDCAFTqm.p.rb=DCECbDCb=DCECb=DCECAFT 118.5-120 Cu( EC8!ECEC( EC8!EC( EC8!ECAFTqSynthesized byt]3 EC],EC]k&EC]3 EC],EC]3 EC],ECAFT T. L. Johnsonp&CCDDUCC&CCDC&CCDCAFTq Key WordsiVDCVU DDVDCVDCVU DCVDCVU DCAFT&??ldSDCDDDCdSDCDCdSDCDCAFTqNotesDCEDDCDCECDCECAFTXTwo multiplets at 7.53 and 8.20 ppm are 2nd order and have no defined coupling constants4CCODCODCCC 4ODCDCDCODC 4DC EC ECDC 4 ECDECDEC EC 4CCODCODCCC 4ODCDCDCODC 4DCDECDECDC 4CCODCODCCC 4ODCDCDCODC 4DC EC ECDC 4 ECDECDEC EC 4CCODCODDCD 4ODCDECDEDODD }&C@ D*DDVշCD&C@ D*D@ D&C@ D*D@ DAFTAcquisition Time (sec)mV D@ DVU#DDVDDV D@ DVU#D@ DV D@ DVU#D@ DAFTe2.7197nsD@ Dr DDrDDsD@ Dr D@ DsD@ Dr D@ DAFTCommentjD@ D@DDǠDDD@ D@D@ DD@ D@D@ DAFT:F01kD@ DǀEDDDD@ DǀE@ DD@ DǀE@ DAFTDate{q{E@ DqEDqEDq{E@ DqE@ Dq{E@ DqE@ DAFT425/09/2002 17:16:21p&CD*D@ DVշCD&CD*DD&CD*DDAFT File Named DDW@E@ D:DD^ DDW@EDW@EDf DDAFT \\babylon5\nmrdata\UWChem Unknowns\2002-fall Chem636 unknowns - chemsketch+chemdraw+automation data - from cgfry local nmrdata\F03 - Emily Dykhuizen\SB250F.102v&C@ D*D+DVշC&D&C@ D*D@ D&C@ D*D@ DAFTFrequency (MHz)mV D@ DVU#D+DVD&DV D@ DVU#D@ DV D@ DVU#D@ DAFTe299.87nsD@ Dr D+DrD&DsD@ Dr D@ DsD@ Dr D@ DAFTNucleusiD@ DǀD+DD&DD@ DǀD@ DD@ DǀD@ DAFT,1H{D@ DǀE+DD&DD@ DǀE@ DD@ DǀE@ DAFTNumber of Transientsiq{E@ Dq E+DqE&Dq{E@ Dq E@ Dq{E@ Dq E@ DAFT&32|&C+D*D@7DVշC1D&C+D*D+D&C+D*D+DAFTOriginal Points CountlV D+DV!D@7DVD1DV D+DV!D+DV D+DV!D+DAFT\16384ssD+Dr D@7DrD1DsD+Dr D+DsD+Dr D+DAFT Points CountlD+DǀD@7DD1DD+DǀD+DD+DǀD+DAFT\32768wD+DǀE@7DD1DD+DǀE+DD+DǀE+DAFTSweep Width (Hz)nq{E+DqE@7Dq3 E1Dq{E+DqE+Dq{E+DqE+DAFTw6024.10}&C@7D*DBDVշC=D&C@7D*D@7D&C@7D*D@7DAFTTemperature (degree C)mV D@7DVU#DBDVD=DV D@7DVU#D@7DV D@7DVU#D@7DAFTe24.0004C@ D8loD@ D8loDDCD 48loD@ D8D@ D8DD8loDD 48D@ DDE@ DDED8DD 4CDDEDDE@ DC@ D 4C@ D8loD@ D8loD+DC+D 48loD@ D8D@ D8D+D8loD+D 48D@ DDE@ DDE+D8D+D 4C+D8loD+D8loD@7DC@7D 48loD+D8D+D8D@7D8loD@7D 48D+DDE+DDE@7D8D@7D 4C@7D8loD@7D8loDBDCBD C%? 17ܝD~D1%? 12JuD^D1%? 16DDD1%? 13ܝD˦D1%? 15D^D1%? 14FD˦D1$? 8D^D1$? 9LDrӦD1$? 7LDD1$? 1}DD1$? 6D}D1$? 2DVD1$? 5FD~D1$? 3FDVD1$? 4DJD1%? 10XD^D1%? 11vD_D1%? 18DuD1%? 19yxEuD1? ? ? !? B? c? //? y!X? !? ?  ? Z08j? [9? +n+? n?  k0?  ? ] ? p? :uj? $$7}DDEE MNo.Atom1 Multiplet1 Shift1 (ppm) (ppm)J (Hz)TypeH's  118M054.72[4.69 .. 4.74]-s226, 2M047.38[7.34 .. 7.41]9.01d2316, 14M037.53[7.50 .. 7.57]-m2415M027.67[7.63 .. 7.71]7.91m1515M027.67[7.63 .. 7.71]6.80m1615M027.67[7.63 .. 7.71]1.47m1715M027.67[7.63 .. 7.71]1.47m183, 5M018.05[8.01 .. 8.09]8.82d2913, 17M008.20[8.17 .. 8.24]-m2 ??,Arial, Arial,CCDEuC@DECCCDECCCDECAFT 'Sample F01 (F:A-01), Fall 2002 Unknownsq8EuCEEC>EC8EuCEEuC8EuCEEuCAFT 1 May 2003s8ECEEC>EC8ECEEC8ECEECAFT D. R. Mowrey@JDC DE No.(ppm)(Hz)Height "14.721414.11.000027.352204.50.031537.362207.10.276347.372209.30.086357.382213.90.090167.392216.10.309977.402218.70.036887.512250.60.059597.512251.40.0911107.512253.00.0380117.532257.50.0535127.532258.90.2030137.542260.00.1126147.552265.20.0593157.562266.60.1404167.562268.30.0296177.642291.50.0429187.652292.70.0826197.652294.20.0496207.662298.30.0349217.672299.70.0599227.672300.30.1014237.672300.80.0664247.682302.30.0296257.692306.40.0239267.702307.60.0417277.702309.10.0208288.032408.00.0365298.042410.60.3083308.052412.60.0921318.062417.40.0889328.072419.40.2799338.082422.20.0321348.202460.40.0116(@DDEPE*No.AtomExp. Shift (ppm) Multiplet 1184.72M05267.38M04327.38M044167.53M035147.53M036157.67M02738.05M01858.05M019138.20M0010178.20M00bD DE D8No. Annotation (ppm) 1TMS0.00ODC E@>D%.No. (ppm)ValueAbsolute Value1[4.69 .. 4.74]2.007 1.40769e+82[7.34 .. 7.41]1.960 1.37470e+83[7.49 .. 7.57]1.988 1.39442e+84[7.63 .. 7.71]0.952 6.67483e+75[8.02 .. 8.09]2.000 1.40287e+86[8.17 .. 8.24]1.932 1.35508e+8