List of Graduate Students and Thesis Titles:
I. Stereochemistry of the Norrish Type II Cleavage of Ketones. II. Preparation and Reactions of Metal Carbene Complexes.
Graduated December 1972.
Now at Polaroid, Cambridge, Massachusetts.
I. Metal Carbonyl Catalyzed Olefin Isomerization. II. Reactions of Metal Carbonyl Anions with Methyl and Phenyl Metal Carbonyl Compounds.
Graduated May 1973.
Now at E. I. duPont, Photo Products, Pennsylvania.
The Reaction of Organocopper(I) Reagents with Enol Esters Derived from 1,3- Dicarbonyl Compounds.
Graduated August 1974.
Now Professor at Westmont College, Santa Barbara, California.
I. The Decarbonylation of Acylpentacarbonylmanganese(I) Compounds. II. Nucleophilic Attack of Organolithium Reagents on Acylpentacarbonylmanganese(I) Compounds.
Graduated August 1974.
Now at Eli Lilly, Lafayette, Indiana.
I. Generation, Structure, Basicity and Alkylation of Conjugate Bases of Transition Metal Carbene Complexes. II. Thermolysis of Transition Metal Carbene Complexes.
Graduated December 1974.
Now at BP, Napierville, Illinois.
I. Reaction of Phosphorus Ylide with Transition Metal Carbene Complexes. II. Preparation and Reactions of Diphenylcarbenepentacarbonyltungsten(O).
Graduated December 1974.
Now at Exxon, Baytown, Texas.
Reactions of Anions of Group VI Transition Metal- Carbene Complexes.
Graduated June 1976.
Now at IBM, Poughkeepsie, New York.
Preparations and Reactions of Alkyl- and Arylpentacarbonyltungsten Anions.
Graduated December 1977.
Now at Eastman Chemicals, Kingsport, Tennessee.
I. Reactions of (Di-p-tolycarbene)pentacarbonyltungsten(O) with Alkenes - A Model for the Olefin Metathesis Reaction. II. Stereochemistry of Terminal Alkene Nonproductive Metathesis.
Graduated January 1978.
Now at Dow Chemical, Midland, Michigan.
Electrochemical Reduction of Arylmethoxycarbene Complexes.
Graduated June 1978.
Now at 3M, St. Paul, Minnesota.
Models for the Metal Catalyzed Reduction of Carbon Monoxide by Hydrogen.
Graduated August 1978.
Now at Eastman Kodak, Rochester, New York.
I. Mechanism of Decomposition of Bisacyl Rhenium and Manganese Compounds. II. Mechanism of Rearrangement of Platinacyclobutanes.
Graduated August 1979.
Now at Dow Chemical, North Carolina.
I. Stereochemistry and Mechanism of the Reaction of LiCu(CH3)2 with g-Cyclopropyl a,b-Unsaturated Ketones. II. Stereochemistry and Mechanism of 13CO Exchange with Group VIB Metal Carbene Complexes.
Graduated December 1979.
Now at British Petroleum, Illinois.
Chelated Tungsten Alkene- Carbene Complexes.
Graduated January 1981.
Now Professor at Reed College, Portland, Oregon.
I. Cyclopentadienyl Rearrangements in Phosphine Substitution Reactions of Group VIB Cyclopenta-dienyldicarbonylnitrosyl Complexes. II. Synthesis and Reaction of Alkenylpentacarbonyltungstate(0) Anions. III. Metathesis Reactions of an Asymmetric Titanium Methylene Complex.
Graduated August 1982.
Now at UW Medical School, Madison, Wisconsin.
Tungsten(0) Chelated Aminocarbene- Alkene Complexes.
Graduated December 1982.
Now at Virent Energy Systems, Madison, Wisconsin.
Heterobimetallic Compounds Linked by a Heterodifunctional Ligand.
Graduated January 1984.
Now at Brookhaven National Laboratory.
I. Synthesis and Reactions of Iron Carbene Complexes. II. Synthesis and Reactions of Bridging Methylene Complexes.
Graduated June 1984.
Now Associate Professor at Lafayette College, Easton, Pennsylvania.
Trimethylphosphine Induced Cyclopentadienyl Ligand Transformations.
Graduated August 1984.
Now Associate Professor at the University of California- San Diego.
I. The Relative Rates of the Degenerate Metathesis of Terminal Olefins and the Degenerate Metathesis of Ethylene Catalyzed by Tungsten Hexachloride-Tetramethyl Tin. II. The Metathesls and Polymerization of Terminal Olefins Catalyzed by Molybdenum Nitrosyl Chloride Aluminum Alkyl Complexes. III. The Stereoselective Metathesis of Cis- 2- Pentene to Cis- 2- Butene Catalyzed by Molybdenum Complexes of Phosphines of Different Symmetry and Aluminum Alkyl Cocatalysts.
Graduated December 1984.
Now at Dow Chemical, Midland, Michigan.
Synthesis and Reactivity of Diiron Complexes with Bridging Carbon Ligands.
Graduated August 1985.
Now Professor at Georgia Institute of Technology, Atlanta, Georgia.
I. Structural Comparisons of Iron Formyl and Iron Acetyl Complexes. II. Reactions and Mechanisms Involving a Diiron m- Methylidyne Complex and Alkenes.
Graduated October 1985.
Now at Flinn Scientific, Batavia, Illinois.
I. Intramolecular Cyclopropanation and Olefin Metathesis Reactions of (CO)5W=C(OCH2CH2CH=CHOCH3)C6H4-p-CH3. II. Alkylation at Nitrogen in Tungsten(0) Aminocarbene Complexes. III. Regioselective Deprotonation and Alkylation a to Nitrogen in (CO)5W=C[N(CH3)2]C6H4-p-CH3.
Graduated January 1987.
Now at E.I. duPont, Wilmington, Delaware.
The Synthesis and Reactivity of Diiron Complexes Containing Bridging Alkenylidene, Alkenyl, and Allene Ligands.
Graduated October 1987.
Now at Aldrich Chemical, Milwaukee, Wisconsin.
Synthesis, Structure, and Bonding of Diiron m- Vinylcarbyne Complexes.
Graduated October 1987.
Now at 3M, St. Paul, Minnesota.
Synthesis, Characterization and Reactivity of Rhenium- Platinum Dihydrides.
Graduated May 1989.
Now at Intel
Synthesis, Structure and Hydroformylation Selectivity of Metal Complexes of Diphosphines with Large Natural Bite Angles.
September 1989. Now at Dow Chemical, Midland, MI
I. Formation of Cyclic Hydrocarbons from C5H5(CO)2Fe(CH2)nX Complexes. II. Synthesis of threo- C5H5(CO)2FeCHDCHDCH2SC6H5 and its Conversion to Cyclopropane - A Determination of the Stereochemistry of Cyclopropane Formation. III. Photoreactions of C5H5(CO)2Fe(CH2)nX.
Graduated November 1989.
Now at Dow Chemical, Midland, Michigan.
I. Reactions of Nucleophiles with Cationic Diiron Complexes. II. Reactions of Nucleophiles and Electrophiles with Amphiphilic Rhenium Alkylidene Complexes.
Graduated November 1989.
Now at Dow Chemical, Midland, Michigan.
I. Synthesis and Reactions of Cationic Rhenium Allyl Complexes. II. Acid Catalyzed Isomerization and Deuterium Exchange of Rhenium Alkene Complexes. III. Synthesis and Reactions of Cationic Rhenium Allenyl Complexes.
Graduated November 1991.
Now Associate Professor at Marquette University.
I. Fenske-Hall Molecular Orbital Studies of [CpM(CO)n]2 Complexes: The Interplay of Metal-Metal Bonding and Bridging and Semibridging Ligands. II. The Photolytic Dehydrogenation of the Diiron Alkylidene Complex, [CpFe(CO)]2(m-CO)(m-CHCH2CH2CH2CH3).
Graduated February 1992.
Now Senior Researcher, Laboratoire ICAR, CNRS, Lyon, France.
Rearrangements of Organorhenium Compounds
Graduated December 1992.
Now at Procter and Gamble, Cincinnati, OH.
Synthesis, Reactions and Mechanistic Studies of Rhenium-Platinum Complexes
Graduated January 1993.
Now Vice-President of Business Development and Research at Scientific Protein Laboratories, LLC, Wisconsin.
Selectivity in Rhodium-Catalyzed Hydroformylation is Kinetically Controlled and Determined by Diphosphine Chelation Mode
Graduated October 1993.
Reactions of Small Molecules with Paramagnetic Tricobalt Hydride Clusters
Graduated October 1994.
Now an associate professor at Duke University, Durham, North Carolina.
Reactions of Cp*(CO)2Re=Re(CO)2Cp* with Alkynes and Other Organic Ligands.
Graduated January 1996.
Now at Clorox, Oakland, California.
I. Yttrium(III) d0 Transtion Metal-Alkyl-Alkene Complexes. II. The Reaction of Aceytlene with Cp*3Co3(m2-H)3(m-H).
Graduated in May 1996.
Now at Dupont, Wilmington, Delaware
Effect of ring strain in a hydroxycarbene complex-metal acyl hydride equilibrium : II. Stereochemistry of hydrogen chloride addition to an amphiphilic carbene complex.
Graduated in 1996.
Now an assistant professor at University of Wisconsin-LaCrosse, LaCrosse, Wisconsin
Synthesis and reactions of rhenium pi-propargyl complexes.
Graduated in 1997.
Now at Lifetouch, Minneapolis, MN.
Kinetic and mechanistic investigations of rhenium alkyne complexes.
Graduated in 1998.
Now at 3M in St. Paul, Minnesota.
Electron withdrawing substituents on equatorial and apical phosphines have opposite effects on the regioselectivity of rhodium catalyzed hydroformylation.
Graduated in 1998.
Now at Air Products, Allentown, PA.
Studies of ETA-3 propargyl complexes of rhenium and platinum.
Graduated in 1998.
Now at Augustana College, Rock Island, Illinois.
Kinetics and thermodynamics of d¡-yttrocene-alkyl-alkene complexes : I. : Reaction rates of alkenes with Cp*2YH(THF).
Graduated in 1999.
Now at Duke University, Durham, North Carolina.
I. Kinetics and thermodynamics of alkene complexation in d0 yttrium-alkyl-alkene complexes
II. Mechanism of the reversal of enantioselectrivity in the platinum-catalyzed
Graduated in 1999.
Now an assistant professor at Smith College, MA.
[1,3] metal shifts and dimerizations of rhenium alkynyl carbene complexes
Graduated in 2001.
Now an assistant professor at Kansas State University.
Models of key intermediates in metallocene catalyzed alkene polymerizations: Zirconium- alkyl-alkene chelates.
Graduated in 2001.
Now at Delphi Automotive, Oklahoma City, OK.
Formation and reactions of a hydroxycyclopentadienyl ruthenium hydride: An organometallic complex containing electronically coupled acidic and hydridic hydrogens
Graduated in 2001.
Now a postdoc at University of California-Berkeley.
Regioselectivity of nucleophilic addition to eta-3 propargyl complexes and electronic effects novel equilibrium between eta-3 propargyl and eta-2 allenyl complexs of rhenium
Graduated in 2002.
Now a Exxon-Mobil, Houston, TX.
Formation and reactions of aminocyclopentadienyl ruthenium complexes: an exploration into new organometallic hydrogenation catalysts
Graduated in 2002.
Now at Invista, Orange, TX.
Understanding the Origin of Selectivity in Hydroformylation
Graduated in 2004.
Now at UOP, Des Plaines, IL.
Analysis of a Hydroxycyclopentadienyl Ruthenium Hydride Ligand-Metal Bifunctional Catalyst: Reactivity, Mechanistic Studies and the Development of More Active Catalysts
Graduated in 2004.
Now a postdoc at Colorado State University.
Hydroxycyclopentadienyl Ruthenium Hydride Hydrogenation Catalysts: Mechanism of Imine Reduction and Development of a More Active Catalyst
Graduated in 2005.
Now a postdoc at University of Wisconsin-Madison.
I.Stereochemistry of Cyclopropane Formation Involving Group (IV) Organometallic Complexes
II. Slower Stoichiometric and Faster Catalytic Reduction of Aldehydes by the PPh3 Substituted Hydroxycyclopentadienyl Ruthenium Hydride [2,5-Ph2-3,4-Tol2(eta-5-C44COH)]Ru(CO)(PPh3)H: A Highly Chemoselective Catalyst for Hydrogenation of Aldehydes over Ketones.
Graduated in 2005.
Now a postdoc at Massachusetts Institute of Technology.
In Situ Observations of Hydrogenations with Hydroxycyclopentadienyl Ruthenium Hydride Catalysts
Graduated in 20057.
Now a Research Scientist at SABIC Americas.
Last updated August 20th, 2007