Shvo's Hydroxycyclopentadienyl Ruthenium System | 
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| We have studied the reduction of polar unsaturated species by the ruthenium hydride monomer, which contains both an acidic and a hydridic hydrogen. These reductions occur through a concerted mechanism in which both hydrogens are simultaneously transferred to the substrate outside of the coordination sphere. | 
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Links to
literature references
about this chemistry.
| MAIN PAGES: |
{
Pi-Propargyl Complexes}
{
d0-Olefin Complexes}
{
Hydroformylation}
{ Shvo Ruthenium Chemistry} { Rhenium carbenes} { Rhenium dimer} | ||
| INTERACTIVE MOLECULES: |
{
Pi-Propargyl Complex}
{
d0-Olefin Complex}
{
Hydroformylation}
{ Tricobalt bis-Ethylidine Complex} { Locked Rhenium Carbene} {Rhenium Dimer} | ||
Updated by Sharon Beetner -- sbeetner at chem.wisc.edu