 B.S. With Honors 2005, University of Washington
Ph.D. 2011, Massachusetts Institute of Technology
Room:
Phone:
Email: tandrew@chem.wisc.edu
Position: Assistant Professor
- 6,6-Dicyanofulvenes as Efficient Fullerene Substitutes in Bulk Heterojunction Solar Cells. Andrew, T. L.; Bulović, V. ACS Nano, accepted for publication.
- Improving the Performance of P3HT-Fullerene Bulk Heterojunction Solar Cells with Side-Chain Functionalized Polythiophene Additives: A New Paradigm for Polymer Design. Andrew, T. L.; Lobez, J. M.; Swager, T. M.; Bulović, V. ACS Nano, in press.
- Cascaded Energy Transfer for Efficient Broad-Band Pumping of High-Quality Micro-Lasers. Rotschild, C.; Tomes, M.; Mendoza, H.; Andrew, T. L.; Swager, T. M.; Carmon, T.; Baldo, M. A. Adv. Mater. 2011, 23, 3057-3060.
- Selective Detection of High Explosives Via Photolytic Cleavage of Nitroesters and Nitramines. Andrew, T. L.; Swager, T. M. J. Org. Chem. 2011, 76, 2976-2993. [editor’s selection for feature article]
- Thermally-polymerized rylene nanoparticles. Andrew, T. L.; Swager, T. M. Macromolecules, 2011, 44, 2276-2281.
- Structure Property Relationships for Exciton Transfer in Conjugated Polymers. Andrew, T. L.; Swager, T. M. J. Polym. Sci. B, 2011, 49, 476-498.
- The Synthesis of Azaperylene-9,10-dicarboximides. Andrew, T. L.; VanVeller, B.; Swager, T. M. Synlett, 2010, 3045-3048.
- Synthesis, Reactivity, and Electronic Properties of 6,6-Dicyanofulvenes. Andrew, T. L.; Cox, J. R.; Swager, T. M. Org. Lett. 2010, 12, 5302-5305.
- Confining Light to Deep Subwavelength Dimensions to Enable Optical Nanopatterning. Andrew, T. L.; Tsai, H.-Y.; Menon, R. Science, 2009, 324, 917-921.
- Anionic Oxidative Polymerization: The Synthesis of Poly(phenylenedicyanovinylene) (PPCN2V). Moslin, R. M.; Andrew, T. L.; Kooi, S. E.; Swager, T. M. J. Am. Chem. Soc. 2009, 131, 20-21.
| Research Description
*Joining July 2012* Our research program focuses equally on synthesizing optically- and electronically-interesting materials, and fabricating optoelectronic or spintronic devices using these materials. We are interested in understanding the role of electron spin on organic light-emitting diodes (OLEDs) and photovoltaic cells (OPVs). Additionally, we aim to demonstrate the utility of organic radical-containing materials in magnetic spin valves and magneto-optic devices. Understanding the Effect of Electron Spin in Optoelectronic Devices The electronic and morphological factors that affect charge separation events in organic optoelectronic devices have been (and continue to be) widely studied. However, using spin dynamics to control charge transport within individual molecules and thin films has received comparatively less attention. We aim to fabricate simple OLEDs and OPVs containing a redox-active organic radical interlayer and characterize the resulting effects on device metrics. This project involves synthesizing analogs of prevalent small-molecule and polymeric donor materials containing stable radical moieties and studying the effects of electron spin within specific layers of a nanostructured OLED and OPV.
Organic Nanostructured Magnetic and Magneto-Optic Devices We are interested in studying spin-dependent charge transport in organic thin films. This project involves both the design of interesting, magnetically-active organic materials and the fabrication of appropriate device architectures that take advantage of our unique material systems. Examples of materials include: conjugated polymers containing either pendant or directly-conjugated organic radicals; and small-molecule organic radicals that can either be thermally-evaporated or possess anchoring groups, which will allow adsorption onto SiO2, metal oxides or carbon nanotubes. We aim to fabricate transistor-like spin valves using these materials to characterize their magnetic properties.
L'Oréal USA Fellowship for Women in Science, 2011 Wyeth Scholar, 2009 Chesonis Foundation Solar Revolution Project Fellow, 2008 Coming Foundation Graduate Fellow, 2007 Merck Index Award, 2005 Mary Gates Research Scholar, 2003 Zahlia Jencks Rowe Scholar in Chemistry, 2003
Hyp Dauben Award for Excellence in Organic Chemistry, 2003
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