 Professor
B.S., 1993, Seoul National University
B.S. 1995, Seoul National University
Ph.D., 2000, Michigan State University
Postdoctoral Research Associate, 2000-2002, University of California, Santa Barbara.
Room: 3233
Phone:
Email: kschoi@chem.wisc.edu
Position: Professor
Seabold, J.A.; Choi, K.-S. "Efficient and Stable Photo-Oxidation of Water by a Bismuth Vanadate Photoanode Coupled with an Iron Oxyhydroxide Ocygen Evolution Catalyst". J. Am. Chem. Soc., 2012, 134, 2186-2192. - Synthesis and Photoelectrochemical Properties of Fe2O3/ZnFe2O4 Composite Photoanodes for Use in Solar Water Oxidation Chem. Mater. 2011, 23, 4863-4869.
- Choi, K.-S. “Photodeposition of Co-Based Oxygen Evolution Catalysts on -Fe2O3 Photoanodes” Chem. Mater. 2011, 23, 1686–1693.
- Choi, K.-S. “Enhancing Photoresponse of Nanoparticulate a-Fe2O3 Electrodes by Surface Composition Tuning” J. Phys. Chem C. 2011, 115, 3497-3506.
- Choi, K.-S. “Effect of a Cobalt-Based Oxygen Evolution Catalyst on the Stability and the Selectivity of Photo-Oxidation Reactions of a WO3 Photoanode” Chem. Mater. 2011, 23, 1105–1112.
- McShane. C. M.; Siripala, W. P.; Choi, K.-S. “Effect of Junction Morphology on the Performance of Polycrystalline Cu2O Homojunction Solar Cells” J. Phys. Chem. Lett. 2010, 1, 2666–2670.
- Choi, K.-S. “Shape Effect and Shape Control of Polycrystalline Semiconductor Electrodes for Use in Photoelectrochemical cells” J. Phys. Chem. Lett. 2010, 1, 2244–2250.
- Jung, Y.; Sign, N.; Choi, K.-S. “Cathodic Assembly of Conducting Polymer and Metal-Conducting Polymer Hybrid Films” Angew. Chem. Int. Ed. 2009, 48, 8331-8334.
- Steinmiller, E. M. P.; Choi, K.-S. “Photochemical Deposition of Cobalt-Based Oxygen Evolving Catalyst on a Semiconductor Photoanode for Solar Oxygen Production” Proc. Natl. Acad. Sci. USA 2009, 106, 20633-20636.
- Read, C. G.; Steinmiller, E. M. P.; Choi, K.-S. “Atomic Plane-Selective Deposition of Novel Metal Particles on Metal Oxide Crystals” J. Am. Chem. Soc. 2009,131, 12040-12041.
| Research Description
Our research focuses on design, synthesis, and characterization of semiconducting and metallic crystals and thin film-type electrodes with controlled micro- and nano-structures for use in electrochemical and photoelectrochemical devices (e.g. photoelectrochemical cells, fuel cells, and rechargeable batteries, and sensors). This research combines disciplines of inorganic chemistry, solid state chemistry, electrochemistry, materials chemistry, and nano-scale science. When electrochemical and photoelectrochemical devices contain polycrystalline electrodes or catalysts, variances of particle shapes, sizes, orientations, and interconnections significantly affect the chemical and physical factors that define the energetics and kinetics of these electrodes or catalysts. Therefore, controlling and understanding the effects of micro- and nano-structural features at the interface on functional properties are the keys to producing highly efficient, cost effective, and lightweight devices. In order to accomplish these tasks our group develops new electrochemical synthetic strategies that can make a significant advancement in constructing polycrystalline electrode materials. We achieve this by combining compositionally versatile electrodeposition methods with various new synthetic concepts/techniques that can allow for precise morphological control at various length scales (e.g. electrochemical interfacial supramolecular templating, controlled electrocrystallization). Since electrodeposition is based on a low-temperature solution-based method with many synthetic variables that can be precisely and freely controlled, our approach allows for the assembly of a broad range of inorganic electrodes with systematically varying micro- and nano-structural features (e.g. mesoporous films, nano- and micro-scale crystal engineering).
The functional properties we currently investigate in conjunction with morphological variation include optical, electrochemical, photoelectrochemical, and photo-/electro-catalytic properties. By pursuing an in-depth atomic level understanding of structure-property relationships as well as efficiency enhancement by interfacial engineering, we attempt to bridge the gap between chemistry and materials engineering. Vice Chair-Elect, Gordon Research Conference-Electrodeposition, 2012 - 2011 Chair, ACS-Division of Inorganic Chemistry, Solid State Subdivision, 2010
Volume Organizer of Materials Research Society Bulleting, 2011 University Faculty Scholar - Purdue University, 2011 Iota Sigma Pi Agnes Fay Morgan Research Award, 2010 Purdue College of Science Outstanding Undergraduate Teaching Award by an Assistant Professor, 2008 ACS-ExxonMobil Solid State Chemistry Faculty Fellowship, 2007 ACS PROGRESS/Dreyfus Lectureship Award, 2006 ACS PROGRESS/Dreyfus Lectureship Award by American Chemical Society, 2006 Alfred P. Sloan Research Fellow by Alfred P. Sloan Foundation, 2006 Graduated Magna Cum Laude from Seoul National University, 1993
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