All Faculty and Research Staff Publications

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2011
Ye X, Liu G, Popp BV, Stahl SS. Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)(2)/Pyridine. Journal of Organic Chemistry. 2011 ;76:1031-1044.
Benson MC, Ruther RE, Gerken JB, Rigsby ML, Bishop LM, Tan Y, Stahl SS, Hamers RJ. Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces. ACS Applied Materials & Interfaces. 2011 ;3:3110-3119.
Konnick MM, Decharin N, Popp BV, Stahl SS. O-2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways. Chemical Science. 2011 ;2:326-330.
Huffman LM, Casitas A, Font M, Canta M, Costas M, Ribas X, Stahl SS. Observation and Mechanistic Study of Facile C-O Bond Formation between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles. Chem. - Eur. J. 2011 ;17:10643-10650, S10643/1-S10643/48.
Izawa Y, Pun D, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols. Science. 2011 ;333:209-213.
McDonald RI, Liu G, Stahl SS. Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications. Chemical Reviews. 2011 ;111:2981-3019.
Decharin N, Popp BV, Stahl SS. Reaction of O(2) with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L](+) "Reductive Elimination" Pathway. Journal of the American Chemical Society. 2011 ;133:13268-13271.
Campbell AN, Meyer EB, Stahl SS. Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chemical Communications. 2011 ;47:10257-10259.
White PB, Stahl SS. Reversible Alkene Insertion into the Pd-N Bond of Pd(II)-Sulfonamidates and Implications for Catalytic Amidation Reactions. Journal of the American Chemical Society. 2011 ;133:18594-18597.
Diao T, Stahl SS. Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones. Journal of the American Chemical Society. 2011 ;133:14566-14569.
2010
Izawa Y, Stahl SS. Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization. Advanced Synthesis & Catalysis. 2010 ;352:3223-3229.
Campbell AN, White PB, Guzei IA, Stahl SS. Allylic C-H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover. Journal of the American Chemical Society. 2010 ;132:15116-15119.
Dohm MT, Mowery BP, Czyzewski AM, Stahl SS, Gellman SH, Barron AE. Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers. Journal of the American Chemical Society. 2010 ;132:7957-7967.
King AE, Huffman LM, Casitas A, Costas M, Ribas X, Stahl SS. Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C-H Bond: Evidence for an Aryl-Copper(III) Intermediate. Journal of the American Chemical Society. 2010 ;132:12068-12073.
Ye X, Johnson MD, Diao T, Yates MH, Stahl SS. Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions. Green Chemistry. 2010 ;12:1180-1186.
Casitas A, King AE, Parella T, Costas M, Stahl SS, Ribas X. Direct observation of Cu-I/Cu-III redox steps relevant to Ullmann-type coupling reactions. Chemical Science. 2010 ;1:326-330.
Popp BV, Morales CM, Landis CR, Stahl SS. Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0). Inorganic Chemistry. 2010 ;49:8200-8207.
McDonald RI, Wong GW, Neupane RP, Stahl SS, Landis CR. Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands. Journal of the American Chemical Society. 2010 ;132:14027-14029.
Gerken JB, Landis EC, Hamers RJ, Stahl SS. Fluoride-Modulated Cobalt Catalysts for Electrochemical Oxidation of Water under Non-Alkaline Conditions. Chemsuschem. 2010 ;3:1176-1179.
Zhang J, Gellman SH, Stahl SS. Kinetics of Anionic Ring-Opening Polymerization of Variously Substituted beta-Lactams: Homopolymerization and Copolymerization. Macromolecules. 2010 ;43:5618-5626.
McDonald RI, Stahl SS. Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides. Angewandte Chemie-International Edition. 2010 ;49:5529-5532.
Casitas A, Poater A, Sola M, Stahl SS, Costas M, Ribas X. Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu-III-halide species. Dalton Transactions. 2010 ;39:10458-10463.
Stahl SS. Organotransition Metal Chemistry: From Bonding to Catalysis by John Hartwig.; 2010 pp. 8524-8525.
2009
Zhang JH, Kissounko DA, Lee SE, Gellman SH, Stahl SS. Access to Poly-beta-Peptides with Functionalized Side Chains and End Groups via Controlled Ring-Opening Polymerization of beta-Lactams. Journal of the American Chemical Society. 2009 ;131:1589-1597.
Stephenson NA, Zhu J, Gellman SH, Stahl SS. Catalytic Transamidation Reactions Compatible with Tertiary Amide Metathesis under Ambient Conditions. Journal of the American Chemical Society. 2009 ;131:10003-10008.
Popp BV, Stahl SS. Mechanism of Pd(OAc)(2)/Pyridine Catalyst Reoxidation by O-2: Influence of Labile Monodentate Ligands and Identification of a Biomimetic Mechanism for O-2 Activation. Chemistry-A European Journal. 2009 ;15:2915-2922.
King AE, Brunold TC, Stahl SS. Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction. Journal of the American Chemical Society. 2009 ;131:5044-+.
Lee M-R, Stahl SS, Gellman SH, Masters KS. Nylon-3 Copolymers that Generate Cell-Adhesive Surfaces Identified by Library Screening. Journal of the American Chemical Society. 2009 ;131:16779-16789.
Yang LJ, Lu Z, Stahl SS. Regioselective copper-catalyzed chlorination and bromination of arenes with O-2 as the oxidant. Chemical Communications. 2009 :6460-6462.
Scarborough CC, McDonald RI, Hartmann C, Sazama GT, Bergant A, Stahl SS. Steric Modulation of Chiral Biaryl Diamines via Pd-Catalyzed Directed C-H Arylation. Journal of Organic Chemistry. 2009 ;74:2613-2615.
Mowery BP, Lindner AH, Weisblum B, Stahl SS, Gellman SH. Structure-activity Relationships among Random Nylon-3 Copolymers That Mimic Antibacterial Host-Defense Peptides. Journal of the American Chemical Society. 2009 ;131:9735-9745.
Scarborough CC, Bergant A, Sazama GT, Guzei IA, Spencer LC, Stahl SS. Synthesis of Pd-II complexes bearing an enantiomerically resolved seven-membered N-heterocyclic carbene ligand and initial studies of their use in asymmetric Wacker-type oxidative cyclization reactions. Tetrahedron. 2009 ;65:5084-5092.
2008
Huffman LM, Stahl SS. Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes. Journal of the American Chemical Society. 2008 ;130:9196-+.
Hamada T, Ye X, Stahl SS. Copper-catalyzed aerobic oxidative amidation of terminal alkynes: Efficient synthesis of ynamides. Journal of the American Chemical Society. 2008 ;130:833-+.
Hoerter JM, Otte KM, Gellman SH, Cui Q, Stahl SS. Discovery and mechanistic study of Al-III-catalyzed transamidation of tertiary amides. Journal of the American Chemical Society. 2008 ;130:647-654.
Epand RF, Mowery BP, Lee SE, Stahl SS, Lehrer RI, Gellman SH, Epand RM. Dual mechanism of bacterial lethality for a cationic sequence-random copolymer that mimics host-defense antimicrobial peptides. Journal of Molecular Biology. 2008 ;379:38-50.
Hewgley BJ, Stahl SS, Kozlowski MC. Mechanistic study of asymmetric oxidative biaryl coupling: Evidence for self-processing of the copper catalyst to achieve control of oxidase vs oxygenase activity. Journal of the American Chemical Society. 2008 ;130:12232-+.
Konnick MM, Stahl SS. Reaction of molecular oxygen with a Pd-II-hydride to produce a Pd-II-hydroperoxide: Experimental evidence for an HX-reductive-elimination pathway. Journal of the American Chemical Society. 2008 ;130:5753-5762.
Lee MR, Stahl SS, Gellman SH. Synthesis of beta-Lactams Bearing Functionalized Side Chains from a Readily Available Precursor. Organic Letters. 2008 ;10:5317-5319.
2007
Bell CM, Kissounko DA, Gellman SH, Stahl SS. Catalytic metathesis of simple secondary amides. Angewandte Chemie-International Edition. 2007 ;46:761-763.
Popp BV, Stahl SS. Insertion of Molecular Oxygen into a Palladium-Hydride Bond: Computational Evidence for Two Nearly Isoenergetic Pathways. Journal of the American Chemical Society. 2007 ;129:4410-4422.
Mowery BP, Lee SE, Kissounko DA, Epand RF, Epand RM, Weisblum B, Stahl SS, Gellman SH. Mimicry of antimicrobial host-defense peptides by random copolymers. Journal of the American Chemical Society. 2007 ;129:15474-15476.
Kotov V, Scarborough CC, Stahl SS. Palladium-catalyzed aerobic oxidative amination of alkenes: Development of intra- and intermolecular Aza-Wacker reactions. Inorganic Chemistry. 2007 ;46:1910-1923.
Rogers MM, Kotov V, Chatwichien J, Stahl SS. Palladium-Catalyzed Oxidative Amination of Alkenes: Improved Catalyst Reoxidation Enables the Use of Alkene as the Limiting Reagent. Organic Letters. 2007 ;9:4331-4334.
Popp BV, Wendlandt JE, Landis CR, Stahl SS. Reaction of molecular oxygen with an NHC-coordinated Pd-0 complex: Computational insights and experimental implications. Angewandte Chemie-International Edition. 2007 ;46:601-604.
Kissounko DA, Hoerter JM, Guzei IA, Cui Q, Gellman SH, Stahl SS. Ti-IV-mediated reactions between primary amines and secondary carboxamides: Amidine formation versus transamidation. Journal of the American Chemical Society. 2007 ;129:1776-1783.
Liu G, Stahl SS. Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic pd-catalyzed intramolecular Aza-Wacker reactions. Journal of the American Chemical Society. 2007 ;129:6328-6335.

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