All Faculty and Research Staff Publications

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2012
Zhang J, Markiewicz MJ, Mowery BP, Weisblurn B, Stahl SS, Gellman SH. C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities. Biomacromolecules. 2012 ;13:323-331.
Gerken JB, Chen JYC, Masse RC, Powell AB, Stahl SS. Development of an O-2-Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation. Angewandte Chemie-International Edition. 2012 ;51:6676-6680.
Diao T, Wadzinski TJ, Stahl SS. Direct aerobic alpha,beta-dehydrogenation of aldehydes and ketones with a Pd (TFA)(2)/4,5-diazafluorenone catalyst. Chemical Science. 2012 ;3:887-891.
Zhang JH, Markiewicz MJ, Weisblum B, Stahl SS, Gellman SH. Functionally Diverse Nylon-3 Copolymers from Readily Accessible beta-Lactams. Acs Macro Letters. 2012 ;1:714-717.
Lu Z, Stahl SS. Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles. Organic Letters. 2012 ;14:1234-1237.
King AE, Ryland BL, Brunold TC, Stahl SS. Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics. 2012 ;31:7948-7957.
Campbell AN, Stahl SS. Overcoming the "Oxidant Problem": Strategies to Use O-2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu). Accounts of Chemical Research. 2012 ;45:851-863.
Weinstein AB, Stahl SS. Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations. Angew. Chem., Int. Ed. 2012 ;51:11505-11509.
Redford JE, McDonald RI, Rigsby ML, Wiensch JD, Stahl SS. Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles. Organic Letters. 2012 ;14:1242-1245.
2013
Hill NJ, Hoover JM, Stahl SS. Aerobic Alcohol Oxidation Using a Copper(I)/TEMPO Catalyst System: A Green, Catalytic Oxidation Reaction for the Undergraduate Organic Chemistry Laboratory. Journal of Chemical Education. 2013 ;90:102-105.
Diao TN, Pun D, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity. Journal of the American Chemical Society. 2013 ;135:8205-8212.
Pun D, Diao TN, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)(2)/2-Dimethylaminopyridine: Evidence for the Role of Pd Nanoparticles. Journal of the American Chemical Society. 2013 ;135:8213-8221.
Powell AB, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst. Organic Letters. 2013 ;15:5072-5075.
Izawa Y, Zheng CW, Stahl SS. Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols. Angewandte Chemie-International Edition. 2013 ;52:3672-3675.
Hoover JM, Stahl SS. Air oxidation of primary alcohols catalyzed by copper(I)/TEMPO. Preparation of 2-amino-5-bromobenzaldehyde. Organic Syntheses. 2013 ;90:240-250.
Rahimi A, Azarpira A, Kim H, Ralph J, Stahl SS. Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin. Journal of the American Chemical Society. 2013 ;135:6415-6418.
Greene JF, Hoover JM, Mannel DS, Root TW, Stahl SS. Continuous-Flow Aerobic Oxidation of Primary Alcohols with a Copper(I)/TEMPO Catalyst. Org. Process Res. Dev. 2013 ;17:1247-1251.
Steves JE, Stahl SS. Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems. Journal of the American Chemical Society. 2013 ;135:15742-15745.
Hoover JM, Ryland BL, Stahl SS, I JOf The Che. Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems. Acs Catalysis. 2013 ;3:2599-2605.
Kim J, Stahl SS. Cu/Nitroxyl-Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. Acs Catalysis. 2013 ;3:1652-1656.
Suess AM, Ertem MZ, Cramer CJ, Stahl SS. Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C-H Oxidation. Journal of the American Chemical Society. 2013 ;135:9797-9804.
Lauber MB, Stahl SS. Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System. Acs Catalysis. 2013 ;3:2612-2616.
Hoover JM, Ryland BL, Stahl SS. Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation. Journal of the American Chemical Society. 2013 ;135:2357-2367.
Ye X, White PB, Stahl SS. Mechanistic Studies of Wacker-Type Amidocyclization of Alkenes Catalyzed by (IMes)Pd(TFA)(2)(H2O): Kinetic and Stereochemical Implications of Proton Transfer. Journal of Organic Chemistry. 2013 ;78:2083-2090.
Gerken JB, Rigsby ML, Ruther RE, Perez-Rodriguez RJ, Guzei IA, Hamers RJ, Stahl SS. Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling. Inorganic Chemistry. 2013 ;52:2796-2798.
Martinez C, Wu YC, Weinstein AB, Stahl SS, Liu GS, Muniz K. Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of Phl(OAc)(2) on Aminopalladation Stereoselectivity. Journal of Organic Chemistry. 2013 ;78:6309-6315.
Hong WP, Iosub AV, Stahl SS. Pd-Catalyzed Semmler-Wolff Reactions for the Conversion of Substituted Cyclohexenone Oximes to Primary Anilines. Journal of the American Chemical Society. 2013 ;135:13664-13667.
Weinstein AB, Schuman DP, Tan ZX, Stahl SS. Synthesis of Vicinal Aminoalcohols by Stereoselective Aza-Wacker Cyclizations: Access to (-)-Acosamine by Redox Relay. Angewandte Chemie-International Edition. 2013 ;52:11867-11870.
2014
Stephenson NA, Gellman SH, Stahl SS. Ammonolysis of anilides promoted by ethylene glycol and phosphoric acid. Rsc Advances. 2014 ;4:46840-46843.
Wendlandt AE, Stahl SS. Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst. Journal of the American Chemical Society. 2014 ;136:506-512.
Rahimi A, Ulbrich A, Coon JJ, Stahl SS. Formic-acid-induced depolymerization of oxidized lignin to aromatics. Nature. 2014 ;515:249-52.
Chen JYC, Miller JT, Gerken JB, Stahl SS. Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion. Energy & Environmental Science. 2014 ;7:1382-1386.
Ryland BL, McCann SD, Brunold TC, Stahl SS. Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals. Journal of the American Chemical Society. 2014 ;136:12166-12173.
Wendlandt AE, Stahl SS. Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions. Journal of the American Chemical Society. 2014 ;136:11910-11913.
Diao TN, Stahl SS. O-2-promoted allylic acetoxylation of alkenes: Assessment of "push" versus "pull" mechanisms and comparison between O-2 and benzoquinone. Polyhedron. 2014 ;84:96-102.
Gladysz JA, Bedford RB, Fujita M, Gabbai FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, et al. Organometallics Roundtable 2013-2014. Organometallics. 2014 ;33:1505-1527.
Weinstein AB, Stahl SS. Palladium catalyzed aryl C-H amination with O-2 via in situ formation of peroxide-based oxidant(s) from dioxane. Catalysis Science & Technology. 2014 ;4:4301-4307.
Wang D, Izawa Y, Stahl SS. Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates. Journal of the American Chemical Society. 2014 ;136:9914-9917.
Ryland BL, Stahl SS. Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems. Angewandte Chemie-International Edition. 2014 ;53:8824-8838.
Tsybizova A, Ryland BL, Tsierkezos N, Stahl SS, Roithova J, Schroder D. Speciation Behavior of Copper( II) Acetate in Simple Organic Solvents - Revealing the Effect of Trace Water. European Journal of Inorganic Chemistry. 2014 ;2014:1407-1412.
Gerken JB, Shaner SE, Masse RC, Porubsky NJ, Stahl SS. A survey of diverse earth abundant oxygen evolution electrocatalysts showing enhanced activity from Ni-Fe oxides containing a third metal. Energy & Environmental Science. 2014 ;7:2376-2382.
2015
Pokhrel R, Goetz MK, Shaner SE, Wu XX, Stahl SS. The "Best Catalyst" for Water Oxidation Depends on the Oxidation Method Employed: A Case Study of Manganese Oxides. Journal of the American Chemical Society. 2015 ;137:8384-8387.
Iosub AV, Stahl SS. Catalytic Aerobic Dehydrogenation of Nitrogen Heterocycles Using Heterogeneous Cobalt Oxide Supported on Nitrogen-Doped Carbon. Organic Letters. 2015 ;17:4404-4407.
McCann SD, Stahl SS. Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst. Accounts of Chemical Research. 2015 ;48:1756-1766.
Kim J, Stahl SS. Cu-Catalyzed Aerobic Oxidative Three-Component Coupling Route to N-Sulfonyl Amidines via an Ynamine Intermediate. Journal of Organic Chemistry. 2015 ;80:2448-2454.
Xie XM, Stahl SS. Efficient and Selective Cu/Nitroxyl-Catalyzed Methods for Aerobic Oxidative Lactonization of Diols. Journal of the American Chemical Society. 2015 ;137:3767-3770.
Rafiee M, Miles KC, Stahl SS. Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects. Journal of the American Chemical Society. 2015 ;137:14751-14757.
Osterberg PM, Niemeier JK, Welch CJ, Hawkins JM, Martinelli JR, Johnson TE, Root TW, Stahl SS. Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry. Org. Process Res. Dev. 2015 ;19:1537-1543.
Parajuli R, Gerken JB, Keyshar K, Sullivan I, Sivasankar N, Teamey K, Stahl SS, Cole EB. Integration of Anodic and Cathodic Catalysts of Earth-Abundant Materials for Efficient, Scalable CO2 Reduction. Topics in Catalysis. 2015 ;58:57-66.
Chen JYC, Dang LN, Liang HF, Bi WL, Gerken JB, Jin S, Alp EE, Stahl SS. Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe4+ by Mossbauer Spectroscopy. Journal of the American Chemical Society. 2015 ;137:15090-15093.

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