All Faculty and Research Staff Publications

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2012
Diao TN, White P, Guzei IA, Stahl SS. Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)(2)(TFA)(2). Inorganic Chemistry. 2012 ;51:11898-11909.
Wendlandt AE, Stahl SS. Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines. Organic Letters. 2012 ;14:2850-2853.
Rigsby ML, Mandal S, Nam W, Spencer LC, Llobet A, Stahl SS. Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O-2 evolution. Chemical Science. 2012 ;3:3058-3062.
Wendlandt AE, Stahl SS. Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Organic & Biomolecular Chemistry. 2012 ;10:3866-3870.
Hoover JM, Steves JE, Stahl SS. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nature Protocols. 2012 ;7:1161-1166.
Zhang J, Markiewicz MJ, Mowery BP, Weisblurn B, Stahl SS, Gellman SH. C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities. Biomacromolecules. 2012 ;13:323-331.
Gerken JB, Chen JYC, Masse RC, Powell AB, Stahl SS. Development of an O-2-Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation. Angewandte Chemie-International Edition. 2012 ;51:6676-6680.
Diao T, Wadzinski TJ, Stahl SS. Direct aerobic alpha,beta-dehydrogenation of aldehydes and ketones with a Pd (TFA)(2)/4,5-diazafluorenone catalyst. Chemical Science. 2012 ;3:887-891.
Zhang JH, Markiewicz MJ, Weisblum B, Stahl SS, Gellman SH. Functionally Diverse Nylon-3 Copolymers from Readily Accessible beta-Lactams. Acs Macro Letters. 2012 ;1:714-717.
Lu Z, Stahl SS. Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles. Organic Letters. 2012 ;14:1234-1237.
King AE, Ryland BL, Brunold TC, Stahl SS. Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics. 2012 ;31:7948-7957.
Campbell AN, Stahl SS. Overcoming the "Oxidant Problem": Strategies to Use O-2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu). Accounts of Chemical Research. 2012 ;45:851-863.
Weinstein AB, Stahl SS. Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations. Angew. Chem., Int. Ed. 2012 ;51:11505-11509.
Redford JE, McDonald RI, Rigsby ML, Wiensch JD, Stahl SS. Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles. Organic Letters. 2012 ;14:1242-1245.
2011
Decharin N, Stahl SS. Benzoquinone-Promoted Reaction of O-2 with a Pd-II-Hydride. Journal of the American Chemical Society. 2011 ;133:5732-5735.
Wendlandt AE, Suess AM, Stahl SS. Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights. Angewandte Chemie-International Edition. 2011 ;50:11062-11087.
Gerken JB, McAlpin GJ, Chen JYC, Rigsby ML, Casey WH, Britt DR, Stahl SS. Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity. Journal of the American Chemical Society. 2011 ;133:14431-14442.
McDonald RI, White PB, Weinstein AB, Tam CP, Stahl SS. Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands. Organic Letters. 2011 ;13:2830-2833.
Hoover JM, Stahl SS. Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols. Journal of the American Chemical Society. 2011 ;133:16901-16910.
Ruther RE, Rigsby ML, Gerken JB, Hogendoorn SR, Landis EC, Stahl SS, Hamers RJ. Highly Stable Redox-Active Molecular Layers by Covalent Grafting to Conductive Diamond. Journal of the American Chemical Society. 2011 ;133:5692-5694.
Huffman LM, Stahl SS. Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex. Dalton Transactions. 2011 ;40:8959-8963.
Ye X, Liu G, Popp BV, Stahl SS. Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)(2)/Pyridine. Journal of Organic Chemistry. 2011 ;76:1031-1044.
Benson MC, Ruther RE, Gerken JB, Rigsby ML, Bishop LM, Tan Y, Stahl SS, Hamers RJ. Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces. ACS Applied Materials & Interfaces. 2011 ;3:3110-3119.
Konnick MM, Decharin N, Popp BV, Stahl SS. O-2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways. Chemical Science. 2011 ;2:326-330.
Huffman LM, Casitas A, Font M, Canta M, Costas M, Ribas X, Stahl SS. Observation and Mechanistic Study of Facile C-O Bond Formation between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles. Chem. - Eur. J. 2011 ;17:10643-10650, S10643/1-S10643/48.
Izawa Y, Pun D, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols. Science. 2011 ;333:209-213.
McDonald RI, Liu G, Stahl SS. Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications. Chemical Reviews. 2011 ;111:2981-3019.
Decharin N, Popp BV, Stahl SS. Reaction of O(2) with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L](+) "Reductive Elimination" Pathway. Journal of the American Chemical Society. 2011 ;133:13268-13271.
Campbell AN, Meyer EB, Stahl SS. Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chemical Communications. 2011 ;47:10257-10259.
White PB, Stahl SS. Reversible Alkene Insertion into the Pd-N Bond of Pd(II)-Sulfonamidates and Implications for Catalytic Amidation Reactions. Journal of the American Chemical Society. 2011 ;133:18594-18597.
Diao T, Stahl SS. Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones. Journal of the American Chemical Society. 2011 ;133:14566-14569.
2010
Izawa Y, Stahl SS. Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization. Advanced Synthesis & Catalysis. 2010 ;352:3223-3229.
Campbell AN, White PB, Guzei IA, Stahl SS. Allylic C-H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover. Journal of the American Chemical Society. 2010 ;132:15116-15119.
Dohm MT, Mowery BP, Czyzewski AM, Stahl SS, Gellman SH, Barron AE. Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers. Journal of the American Chemical Society. 2010 ;132:7957-7967.
King AE, Huffman LM, Casitas A, Costas M, Ribas X, Stahl SS. Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C-H Bond: Evidence for an Aryl-Copper(III) Intermediate. Journal of the American Chemical Society. 2010 ;132:12068-12073.
Ye X, Johnson MD, Diao T, Yates MH, Stahl SS. Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions. Green Chemistry. 2010 ;12:1180-1186.
Casitas A, King AE, Parella T, Costas M, Stahl SS, Ribas X. Direct observation of Cu-I/Cu-III redox steps relevant to Ullmann-type coupling reactions. Chemical Science. 2010 ;1:326-330.
Popp BV, Morales CM, Landis CR, Stahl SS. Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0). Inorganic Chemistry. 2010 ;49:8200-8207.
McDonald RI, Wong GW, Neupane RP, Stahl SS, Landis CR. Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands. Journal of the American Chemical Society. 2010 ;132:14027-14029.
Gerken JB, Landis EC, Hamers RJ, Stahl SS. Fluoride-Modulated Cobalt Catalysts for Electrochemical Oxidation of Water under Non-Alkaline Conditions. Chemsuschem. 2010 ;3:1176-1179.
Zhang J, Gellman SH, Stahl SS. Kinetics of Anionic Ring-Opening Polymerization of Variously Substituted beta-Lactams: Homopolymerization and Copolymerization. Macromolecules. 2010 ;43:5618-5626.
McDonald RI, Stahl SS. Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides. Angewandte Chemie-International Edition. 2010 ;49:5529-5532.
Casitas A, Poater A, Sola M, Stahl SS, Costas M, Ribas X. Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu-III-halide species. Dalton Transactions. 2010 ;39:10458-10463.
Stahl SS. Organotransition Metal Chemistry: From Bonding to Catalysis by John Hartwig.; 2010 pp. 8524-8525.

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