All Faculty and Research Staff Publications

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2014
Rahimi A, Ulbrich A, Coon JJ, Stahl SS. Formic-acid-induced depolymerization of oxidized lignin to aromatics. Nature. 2014 ;515:249-52.
Chen JYC, Miller JT, Gerken JB, Stahl SS. Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion. Energy & Environmental Science. 2014 ;7:1382-1386.
Ryland BL, McCann SD, Brunold TC, Stahl SS. Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals. Journal of the American Chemical Society. 2014 ;136:12166-12173.
Wendlandt AE, Stahl SS. Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions. Journal of the American Chemical Society. 2014 ;136:11910-11913.
Diao TN, Stahl SS. O-2-promoted allylic acetoxylation of alkenes: Assessment of "push" versus "pull" mechanisms and comparison between O-2 and benzoquinone. Polyhedron. 2014 ;84:96-102.
Gladysz JA, Bedford RB, Fujita M, Gabbai FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, et al. Organometallics Roundtable 2013-2014. Organometallics. 2014 ;33:1505-1527.
Weinstein AB, Stahl SS. Palladium catalyzed aryl C-H amination with O-2 via in situ formation of peroxide-based oxidant(s) from dioxane. Catalysis Science & Technology. 2014 ;4:4301-4307.
Wang D, Izawa Y, Stahl SS. Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates. Journal of the American Chemical Society. 2014 ;136:9914-9917.
Ryland BL, Stahl SS. Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems. Angewandte Chemie-International Edition. 2014 ;53:8824-8838.
Tsybizova A, Ryland BL, Tsierkezos N, Stahl SS, Roithova J, Schroder D. Speciation Behavior of Copper( II) Acetate in Simple Organic Solvents - Revealing the Effect of Trace Water. European Journal of Inorganic Chemistry. 2014 ;2014:1407-1412.
Gerken JB, Shaner SE, Masse RC, Porubsky NJ, Stahl SS. A survey of diverse earth abundant oxygen evolution electrocatalysts showing enhanced activity from Ni-Fe oxides containing a third metal. Energy & Environmental Science. 2014 ;7:2376-2382.
2013
Hill NJ, Hoover JM, Stahl SS. Aerobic Alcohol Oxidation Using a Copper(I)/TEMPO Catalyst System: A Green, Catalytic Oxidation Reaction for the Undergraduate Organic Chemistry Laboratory. Journal of Chemical Education. 2013 ;90:102-105.
Diao TN, Pun D, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity. Journal of the American Chemical Society. 2013 ;135:8205-8212.
Pun D, Diao TN, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)(2)/2-Dimethylaminopyridine: Evidence for the Role of Pd Nanoparticles. Journal of the American Chemical Society. 2013 ;135:8213-8221.
Powell AB, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst. Organic Letters. 2013 ;15:5072-5075.
Izawa Y, Zheng CW, Stahl SS. Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols. Angewandte Chemie-International Edition. 2013 ;52:3672-3675.
Hoover JM, Stahl SS. Air oxidation of primary alcohols catalyzed by copper(I)/TEMPO. Preparation of 2-amino-5-bromobenzaldehyde. Organic Syntheses. 2013 ;90:240-250.
Rahimi A, Azarpira A, Kim H, Ralph J, Stahl SS. Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin. Journal of the American Chemical Society. 2013 ;135:6415-6418.
Greene JF, Hoover JM, Mannel DS, Root TW, Stahl SS. Continuous-Flow Aerobic Oxidation of Primary Alcohols with a Copper(I)/TEMPO Catalyst. Org. Process Res. Dev. 2013 ;17:1247-1251.
Steves JE, Stahl SS. Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems. Journal of the American Chemical Society. 2013 ;135:15742-15745.
Hoover JM, Ryland BL, Stahl SS, I JOf The Che. Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems. Acs Catalysis. 2013 ;3:2599-2605.
Kim J, Stahl SS. Cu/Nitroxyl-Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. Acs Catalysis. 2013 ;3:1652-1656.
Suess AM, Ertem MZ, Cramer CJ, Stahl SS. Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C-H Oxidation. Journal of the American Chemical Society. 2013 ;135:9797-9804.
Lauber MB, Stahl SS. Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System. Acs Catalysis. 2013 ;3:2612-2616.
Hoover JM, Ryland BL, Stahl SS. Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation. Journal of the American Chemical Society. 2013 ;135:2357-2367.
Ye X, White PB, Stahl SS. Mechanistic Studies of Wacker-Type Amidocyclization of Alkenes Catalyzed by (IMes)Pd(TFA)(2)(H2O): Kinetic and Stereochemical Implications of Proton Transfer. Journal of Organic Chemistry. 2013 ;78:2083-2090.
Gerken JB, Rigsby ML, Ruther RE, Perez-Rodriguez RJ, Guzei IA, Hamers RJ, Stahl SS. Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling. Inorganic Chemistry. 2013 ;52:2796-2798.
Martinez C, Wu YC, Weinstein AB, Stahl SS, Liu GS, Muniz K. Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of Phl(OAc)(2) on Aminopalladation Stereoselectivity. Journal of Organic Chemistry. 2013 ;78:6309-6315.
Hong WP, Iosub AV, Stahl SS. Pd-Catalyzed Semmler-Wolff Reactions for the Conversion of Substituted Cyclohexenone Oximes to Primary Anilines. Journal of the American Chemical Society. 2013 ;135:13664-13667.
Weinstein AB, Schuman DP, Tan ZX, Stahl SS. Synthesis of Vicinal Aminoalcohols by Stereoselective Aza-Wacker Cyclizations: Access to (-)-Acosamine by Redox Relay. Angewandte Chemie-International Edition. 2013 ;52:11867-11870.
2012
Zheng CW, Wang D, Stahl SS. Catalyst-Controlled Regioselectivity in the Synthesis of Branched Conjugated Dienes via Aerobic Oxidative Heck Reactions. Journal of the American Chemical Society. 2012 ;134:16496-16499.
Diao TN, White P, Guzei IA, Stahl SS. Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)(2)(TFA)(2). Inorganic Chemistry. 2012 ;51:11898-11909.
Wendlandt AE, Stahl SS. Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines. Organic Letters. 2012 ;14:2850-2853.
Rigsby ML, Mandal S, Nam W, Spencer LC, Llobet A, Stahl SS. Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O-2 evolution. Chemical Science. 2012 ;3:3058-3062.
Wendlandt AE, Stahl SS. Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Organic & Biomolecular Chemistry. 2012 ;10:3866-3870.
Hoover JM, Steves JE, Stahl SS. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nature Protocols. 2012 ;7:1161-1166.
Zhang J, Markiewicz MJ, Mowery BP, Weisblurn B, Stahl SS, Gellman SH. C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities. Biomacromolecules. 2012 ;13:323-331.
Gerken JB, Chen JYC, Masse RC, Powell AB, Stahl SS. Development of an O-2-Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation. Angewandte Chemie-International Edition. 2012 ;51:6676-6680.
Diao T, Wadzinski TJ, Stahl SS. Direct aerobic alpha,beta-dehydrogenation of aldehydes and ketones with a Pd (TFA)(2)/4,5-diazafluorenone catalyst. Chemical Science. 2012 ;3:887-891.
Zhang JH, Markiewicz MJ, Weisblum B, Stahl SS, Gellman SH. Functionally Diverse Nylon-3 Copolymers from Readily Accessible beta-Lactams. Acs Macro Letters. 2012 ;1:714-717.
Lu Z, Stahl SS. Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles. Organic Letters. 2012 ;14:1234-1237.
King AE, Ryland BL, Brunold TC, Stahl SS. Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics. 2012 ;31:7948-7957.
Campbell AN, Stahl SS. Overcoming the "Oxidant Problem": Strategies to Use O-2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu). Accounts of Chemical Research. 2012 ;45:851-863.
Weinstein AB, Stahl SS. Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations. Angew. Chem., Int. Ed. 2012 ;51:11505-11509.
Redford JE, McDonald RI, Rigsby ML, Wiensch JD, Stahl SS. Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles. Organic Letters. 2012 ;14:1242-1245.

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