All Faculty and Research Staff Publications

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2013
Hill NJ, Hoover JM, Stahl SS. Aerobic Alcohol Oxidation Using a Copper(I)/TEMPO Catalyst System: A Green, Catalytic Oxidation Reaction for the Undergraduate Organic Chemistry Laboratory. Journal of Chemical Education. 2013 ;90:102-105.
Diao TN, Pun D, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity. Journal of the American Chemical Society. 2013 ;135:8205-8212.
Pun D, Diao TN, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)(2)/2-Dimethylaminopyridine: Evidence for the Role of Pd Nanoparticles. Journal of the American Chemical Society. 2013 ;135:8213-8221.
Powell AB, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst. Organic Letters. 2013 ;15:5072-5075.
Izawa Y, Zheng CW, Stahl SS. Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols. Angewandte Chemie-International Edition. 2013 ;52:3672-3675.
Hoover JM, Stahl SS. Air oxidation of primary alcohols catalyzed by copper(I)/TEMPO. Preparation of 2-amino-5-bromobenzaldehyde. Organic Syntheses. 2013 ;90:240-250.
Rahimi A, Azarpira A, Kim H, Ralph J, Stahl SS. Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin. Journal of the American Chemical Society. 2013 ;135:6415-6418.
Greene JF, Hoover JM, Mannel DS, Root TW, Stahl SS. Continuous-Flow Aerobic Oxidation of Primary Alcohols with a Copper(I)/TEMPO Catalyst. Org. Process Res. Dev. 2013 ;17:1247-1251.
Steves JE, Stahl SS. Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems. Journal of the American Chemical Society. 2013 ;135:15742-15745.
Hoover JM, Ryland BL, Stahl SS, I JOf The Che. Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems. Acs Catalysis. 2013 ;3:2599-2605.
Kim J, Stahl SS. Cu/Nitroxyl-Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. Acs Catalysis. 2013 ;3:1652-1656.
Suess AM, Ertem MZ, Cramer CJ, Stahl SS. Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C-H Oxidation. Journal of the American Chemical Society. 2013 ;135:9797-9804.
Lauber MB, Stahl SS. Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System. Acs Catalysis. 2013 ;3:2612-2616.
Hoover JM, Ryland BL, Stahl SS. Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation. Journal of the American Chemical Society. 2013 ;135:2357-2367.
Ye X, White PB, Stahl SS. Mechanistic Studies of Wacker-Type Amidocyclization of Alkenes Catalyzed by (IMes)Pd(TFA)(2)(H2O): Kinetic and Stereochemical Implications of Proton Transfer. Journal of Organic Chemistry. 2013 ;78:2083-2090.
Gerken JB, Rigsby ML, Ruther RE, Perez-Rodriguez RJ, Guzei IA, Hamers RJ, Stahl SS. Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling. Inorganic Chemistry. 2013 ;52:2796-2798.
Martinez C, Wu YC, Weinstein AB, Stahl SS, Liu GS, Muniz K. Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of Phl(OAc)(2) on Aminopalladation Stereoselectivity. Journal of Organic Chemistry. 2013 ;78:6309-6315.
Hong WP, Iosub AV, Stahl SS. Pd-Catalyzed Semmler-Wolff Reactions for the Conversion of Substituted Cyclohexenone Oximes to Primary Anilines. Journal of the American Chemical Society. 2013 ;135:13664-13667.
Weinstein AB, Schuman DP, Tan ZX, Stahl SS. Synthesis of Vicinal Aminoalcohols by Stereoselective Aza-Wacker Cyclizations: Access to (-)-Acosamine by Redox Relay. Angewandte Chemie-International Edition. 2013 ;52:11867-11870.
2012
Zheng CW, Wang D, Stahl SS. Catalyst-Controlled Regioselectivity in the Synthesis of Branched Conjugated Dienes via Aerobic Oxidative Heck Reactions. Journal of the American Chemical Society. 2012 ;134:16496-16499.
Diao TN, White P, Guzei IA, Stahl SS. Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)(2)(TFA)(2). Inorganic Chemistry. 2012 ;51:11898-11909.
Wendlandt AE, Stahl SS. Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines. Organic Letters. 2012 ;14:2850-2853.
Rigsby ML, Mandal S, Nam W, Spencer LC, Llobet A, Stahl SS. Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O-2 evolution. Chemical Science. 2012 ;3:3058-3062.
Wendlandt AE, Stahl SS. Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Organic & Biomolecular Chemistry. 2012 ;10:3866-3870.
Hoover JM, Steves JE, Stahl SS. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nature Protocols. 2012 ;7:1161-1166.
Zhang J, Markiewicz MJ, Mowery BP, Weisblurn B, Stahl SS, Gellman SH. C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities. Biomacromolecules. 2012 ;13:323-331.
Gerken JB, Chen JYC, Masse RC, Powell AB, Stahl SS. Development of an O-2-Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation. Angewandte Chemie-International Edition. 2012 ;51:6676-6680.
Diao T, Wadzinski TJ, Stahl SS. Direct aerobic alpha,beta-dehydrogenation of aldehydes and ketones with a Pd (TFA)(2)/4,5-diazafluorenone catalyst. Chemical Science. 2012 ;3:887-891.
Zhang JH, Markiewicz MJ, Weisblum B, Stahl SS, Gellman SH. Functionally Diverse Nylon-3 Copolymers from Readily Accessible beta-Lactams. Acs Macro Letters. 2012 ;1:714-717.
Lu Z, Stahl SS. Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles. Organic Letters. 2012 ;14:1234-1237.
King AE, Ryland BL, Brunold TC, Stahl SS. Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics. 2012 ;31:7948-7957.
Campbell AN, Stahl SS. Overcoming the "Oxidant Problem": Strategies to Use O-2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu). Accounts of Chemical Research. 2012 ;45:851-863.
Weinstein AB, Stahl SS. Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations. Angew. Chem., Int. Ed. 2012 ;51:11505-11509.
Redford JE, McDonald RI, Rigsby ML, Wiensch JD, Stahl SS. Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles. Organic Letters. 2012 ;14:1242-1245.
2011
Decharin N, Stahl SS. Benzoquinone-Promoted Reaction of O-2 with a Pd-II-Hydride. Journal of the American Chemical Society. 2011 ;133:5732-5735.
Wendlandt AE, Suess AM, Stahl SS. Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights. Angewandte Chemie-International Edition. 2011 ;50:11062-11087.
Gerken JB, McAlpin GJ, Chen JYC, Rigsby ML, Casey WH, Britt DR, Stahl SS. Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity. Journal of the American Chemical Society. 2011 ;133:14431-14442.
McDonald RI, White PB, Weinstein AB, Tam CP, Stahl SS. Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands. Organic Letters. 2011 ;13:2830-2833.
Hoover JM, Stahl SS. Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols. Journal of the American Chemical Society. 2011 ;133:16901-16910.
Ruther RE, Rigsby ML, Gerken JB, Hogendoorn SR, Landis EC, Stahl SS, Hamers RJ. Highly Stable Redox-Active Molecular Layers by Covalent Grafting to Conductive Diamond. Journal of the American Chemical Society. 2011 ;133:5692-5694.
Huffman LM, Stahl SS. Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex. Dalton Transactions. 2011 ;40:8959-8963.
Ye X, Liu G, Popp BV, Stahl SS. Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)(2)/Pyridine. Journal of Organic Chemistry. 2011 ;76:1031-1044.
Benson MC, Ruther RE, Gerken JB, Rigsby ML, Bishop LM, Tan Y, Stahl SS, Hamers RJ. Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces. ACS Applied Materials & Interfaces. 2011 ;3:3110-3119.
Konnick MM, Decharin N, Popp BV, Stahl SS. O-2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways. Chemical Science. 2011 ;2:326-330.
Huffman LM, Casitas A, Font M, Canta M, Costas M, Ribas X, Stahl SS. Observation and Mechanistic Study of Facile C-O Bond Formation between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles. Chem. - Eur. J. 2011 ;17:10643-10650, S10643/1-S10643/48.
Izawa Y, Pun D, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols. Science. 2011 ;333:209-213.
McDonald RI, Liu G, Stahl SS. Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications. Chemical Reviews. 2011 ;111:2981-3019.
Decharin N, Popp BV, Stahl SS. Reaction of O(2) with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L](+) "Reductive Elimination" Pathway. Journal of the American Chemical Society. 2011 ;133:13268-13271.
Campbell AN, Meyer EB, Stahl SS. Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chemical Communications. 2011 ;47:10257-10259.

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