All Department Publications

Found 146 results
Author Title Type [ Year(Asc)]
Filters: Author is Reich, H. J.  [Clear All Filters]
2012
Reich HJ. What's Going on with These Lithium Reagents?. Journal of Organic Chemistry. 2012;77:5471-5491.
2011
Kolonko KJ, Wherritt DJ, Reich HJ. Mechanistic Studies of the Lithium Enolate of 4-Fluoroacetophenone: Rapid-Injection NMR Study of Enolate Formation, Dynamics, and Aldol Reactivity. Journal of the American Chemical Society. 2011;133:16774-16777.
2010
Kolonko KJ, Guzei IA, Reich HJ. Structure and Dynamics of alpha-Aryl Amide and Ketone Enolates: THF, PMDTA, TMTAN, HMPA, and Crypt-Solvated Lithium Enolates, and Comparison with Phosphazenium Analogues. Journal of Organic Chemistry. 2010;75:6163-6172.
2009
Reich HJ, Sikorski WH, Sanders AW, Jones AC, Plessel KN. Multinuclear NMR Study of the Solution Structure and Reactivity of Tris(trimethylsilyl)methyllithium and its Iodine Ate Complex. Journal of Organic Chemistry. 2009;74:719-729.
Kolonko KJ, Biddle MM, Guzei IA, Reich HJ. Solution Structures of Lithium Enolates of Cyclopentanone, Cyclohexanone, Acetophenones, and Benzyl Ketones. Triple Ions and Higher Lithiate Complexes. Journal of the American Chemical Society. 2009;131:11525-11534.
2008
Jones AC, Sanders AW, Sikorski WH, Jansen KL, Reich HJ. Reactivity of the triple ion and separated ion pair of tris(trimethylsilyl)methyllithium with aldehydes: A RINMR study. Journal of the American Chemical Society. 2008;130:6060-+.
Kolonko KJ, Reich HJ. Stabilization of ketone and aldehyde enols by formation of hydrogen bonds to phosphazene enolates and their aldol products. Journal of the American Chemical Society. 2008;130:9668-+.
2007
Jones AC, Sanders AW, Bevan MJ, Reich HJ. Reactivity of Individual Organolithium Aggregates:  A RINMR Study of n-Butyllithium and 2-Methoxy-6-(methoxymethyl)phenyllithium. Journal of the American Chemical Society. 2007;129:3492-3493.
Guzei IA, Kolonko KJ, Reich HJ. Unexpected crystallization of 1,3-bis(4fluorophenyl)propan-2-one in paratone oil. Acta Crystallographica Section E-Structure Reports Online. 2007;63:O4094-U3459.
2006
Reich HJ, Sikorski WH, Thompson JL, Sanders AW, Jones AC. Interconversion of contact and separated ion pairs in silyl- and arylthio-substituted alkyllithium reagents. Organic Letters. 2006;8:4003.
Jantzi KL, Guzei IA, Reich HJ. Solution and Solid-State Structures of Lithiated Phenyloxazolines. Organometallics. 2006;25:5390-5395.
Biddle MM, Reich HJ. Studies on the reactive species in fluoride-mediated carbon-carbon bond-forming reactions: Carbanion formation by desilylation with fluoride and enolates. Journal of Organic Chemistry. 2006;71:4031-4039.
2005
Reich HJ, Whipple WL. Mechanism of the lithium-iodine exchange in an iodothiophene. Canadian Journal of Chemistry. 2005;83:1577-1587.
Gung BW, Xue XW, Reich HJ. Off-center oxygen-arene interactions in solution: A quantitative study. Journal of Organic Chemistry. 2005;70:7232-7237.
Reich HJ, Biddle MM, Edmonston RJ. Reaction of metalated nitriles with enones. Journal of Organic Chemistry. 2005;70:3375-3382.
Jantzi KL, Puckett CL, Guzei IA, Reich HJ. Solution structure and chelation properties of 2-thienyllithium reagents. Journal of Organic Chemistry. 2005;70:7520-7529.
Gung BW, Xue XW, Reich HJ. The strength of parallel-displaced arene-arene interactions in chloroform. Journal of Organic Chemistry. 2005;70:3641-3644.
2004
Reich HJ, Goldenberg WS, Gudmundsson BO, Sanders AW, Kulicke KJ, Simon K, Guzei IA. Amine-chelated aryllithium reagents-structure and dynamics. Journal of the American Chemical Society. 2004:97-129.
2003
Reich HJ, Goldenberg WS, Sanders AW, Jantzi KL, Tzschucke CC. Amine- and ether-chelated aryllithium reagents-structure and dynamics. J Am Chem Soc. 2003;125(12):3509-21.
Reich HJ, Sanders AW, Bevan MJ, Sikorski WH, Dykstra RR. Identification and Mechanistic Consequences of Contact and Solvent-Separated Ion Pair Structures in Organolithium Chemistry. ChemInform. 2003;34:no–no.
2002
Reich HJ, Bevan MJ, Gudmundsson BÖ, Puckett CL. Are Ate Complexes True Intermediates in Lithium–Metalloid Exchange? Subtle Effects of Ion-Pair Structure in Lithium–Tellurium and Lithium–Selenium Exchange Reactions. Angewandte Chemie International Edition. 2002;41:3436–3439.
Reich HJ, Sanders AW, Fiedler AT, Bevan MJ. The effect of HMPA on the reactivity of epoxides, aziridines, and alkyl halides with organolithium reagents. J Am Chem Soc. 2002;124(45):13386-7.
Reich IL, Reich HJ, Kneer N, Lardy H. Ergosteroids V: preparation and biological activity of various D-ring derivatives in the 7-oxo-dehydroepiandrosterone series. Steroids. 2002;67(3-4):221-33.
Reich HJ, Gudmundsson B Ö, Green D P, Bevan M J, Reich IL. The Role of Ate Complexes in the Lithium-Sulfur, Lithium-Selenium and Lithium-Tellurium Exchange Reactions. Helvetica Chimica Acta. 2002;85:3748–3772.
2001
Reich HJ, Goldenberg WS, Gudmundsson BO, Sanders AW, Kulicke KJ, Simon K, Guzei IA. Amine-chelated aryllithium reagents--structure and dynamics. J Am Chem Soc. 2001;123(33):8067-79.
Reich HJ, Goldenberg WS, Sanders AW, Tzschucke CC. Chelated aryllithium reagents: ring size and chelating group effects. Org Lett. 2001;3(1):33-6.
Sikorski WH, Reich HJ. The regioselectivity of addition of organolithium reagents to enones and enals: the role of HMPA. J Am Chem Soc. 2001;123(27):6527-35.
2000
Reich HJ, Thompson JL. Solvent-dependent lithium bridging in allenyl-propargyllithium reagents. Organic Letters. 2000;2:783-786.
1999
Reich HJ, Sikorski WH. Regioselectivity of addition of organolithium reagents to enones: The role of HMPA. Journal of Organic Chemistry. 1999;64:14-15.
Reich HJ, Holladay JE, Walker TG, Thompson JL. Solution structure and stereochemistry of alkyl- and silyl-substituted allenyl-propargyllithium reagents. Journal of the American Chemical Society. 1999;121:9769-9780.
1998
Reich HJ, Green DP, Medina MA, Goldenberg WS, Gudmundsson BO, Dykstra RR, Phillips NH. Aggregation and reactivity of phenyllithium solutions. Journal of the American Chemical Society. 1998;120:7201-7210.
Reich IL, Lardy H, Wei Y, Marwah P, Kneer N, Powell DR, Reich HJ. Ergosteroids - III. Syntheses and biological activity of seco-steroids related to dehydroepiandrosterone. Steroids. 1998;63:542-553.
Reich HJ, Sikorski WH, Gudmundsson BO, Dykstra RR. Triple ion formation in localized organolithium reagents. Journal of the American Chemical Society. 1998;120:4035-4036.
Sikorski WH, Sanders AW, Reich HJ. Tris(trimethylsilyl)methane as an internal C-13 NMR chemical shift thermometer. Magnetic Resonance in Chemistry. 1998;36:S118-S124.
1996
Reich HJ, Kulicke KJ. Dynamics of solvent exchange in organolithium reagents. Lithium as a center of chirality. Journal of the American Chemical Society. 1996;118:273-274.
Reich HJ, Gudmundsson BO. Solution structure of 2- (dimethylamino)methyl phenyllithium. Journal of the American Chemical Society. 1996;118:6074-6075.
Reich HJ, Holladay JE. Structure of silyl-substituted allenyl/propargyl-lithium reagents in solution. Angewandte Chemie-International Edition in English. 1996;35:2365-2367.
Powell DR, Whipple WL, Reich HJ. Tetrakis(mu(3)-2-methyl-5-thienyl)tetrakis-(diethyl ether-O)-tetrahedro-tetralithium. Acta Crystallographica Section C-Crystal Structure Communications. 1996;52:1346-1348.
1995
Reich HJ, Kulicke KJ. Chelation Effects in Chiral Organolithium Reagents. Journal of the American Chemical Society. 1995;117:6621-6622.
Reich HJ, Holladay JE, Mason JD, Sikorski WH. THE ORIGIN OF REGIOSELECTIVITY IN AN ALLENYLLITHIUM REAGENT. Journal of the American Chemical Society. 1995;117:12137-12150.
Reich HJ, Holladay JE. Solution Structure of Allenyl-Propargyllithium Reagents. Journal of the American Chemical Society. 1995;117:8470-8471.
1994
Reich HJ, Borst JP, Dykstra RR. SOLUTION ION-PAIR STRUCTURE OF 2-LITHIO-1,3-DITHIANES IN THF AND THF-HMPA. Tetrahedron. 1994;50:5869-5880.
Reich HJ, Dykstra RR. SOLUTION STRUCTURE OF LITHIUM BENZENESELENOLATE AND LITHIUM DIPHENYLPHOSPHIDE - NMR IDENTIFICATION OF CYCLIC DIMERS AND MIXED DIMERS. Organometallics. 1994;13:4578-4585.
Reich HJ, Borst JP, Dykstra RR. (Trimethylstannyl)- and (tributylstannyl)lithium: solution structure in ether, THF, and HMPA. Organometallics. 1994;13:1-3.
1993
Reich HJ, Dykstra RR. EFFECTS OF ION-PAIR SEPARATION ON INVERSION AND ROTATION OF SULFUR-STABILIZED, SELENIUM-STABILIZED, AND SILICON-STABILIZED ORGANOLITHIUM REAGENTS. Angewandte Chemie-International Edition in English. 1993;32:1469-1470.
Reich HJ, Mason JD, Holladay JE. LITHIUM METALLOID EXCHANGE - REACTIVITY STUDIES OF AN ALLENYLLITHIUM REAGENT USING AN ISOMERIC PAIR OF ALLENYL AND PROP-2-YNYL STANNANES. Journal of the Chemical Society-Chemical Communications. 1993:1481-1483.
Reich HJ, Borst JP, Dykstra RR, Green DP. A NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC TECHNIQUE FOR THE CHARACTERIZATION OF LITHIUM ION-PAIR STRUCTURES IN THF AND THF/HMPA SOLUTION. Journal of the American Chemical Society. 1993;115:8728-8741.
Reich HJ, Dykstra RR. Structure effects of ion pair separation: planar and pyramidal sulfur and silicon substituted carbanions. Journal of the American Chemical Society. 1993;115:7041-7042.
Reich HJ, Reich IL, Yelm KE, Holladay JE, Gschneidner D. SYNTHESIS OF 2,3-DISUBSTITUTED 1,3-BUTADIENES FROM ORGANOTIN PRECURSORS AND BUTADIENYLLITHIUM REAGENTS - DIELS-ALDER REACTIVITY. Journal of the American Chemical Society. 1993;115:6625-6635.
1992
Reich HJ, Gudmundsson BO, Dykstra RR. The first organoselenium ate complex. Journal of the American Chemical Society. 1992;114:7937-7938.

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