All Department Publications

Found 174 results
Author Title Type [ Year(Asc)]
Filters: Author is Casey, C. P.  [Clear All Filters]
2012
Casey CP, Guan HR. Trimethylsilyl-Substituted Hydroxycyclopentadienyl Ruthenium Hydrides as Benchmarks To Probe Ligand and Metal Effects on the Reactivity of Shvo Type Complexes. Organometallics. 2012;31:2631-2638.
2011
Warner MC, Casey CP, Backvall J-E. Shvo's Catalyst in Hydrogen Transfer Reactions. Bifunctional Molecular Catalysis. 2011;37:85-125.
2010
Casey CP, Johnson JB, Jiao X, Beetner SE, Singer SW. Chain mechanism for exchange of D-2 with a ruthenium hydride. Chemical Communications. 2010;46:7915-7917.
Casey CP, Jiao X, Guzei IA. Formation of beta-Ruthenium-Substituted Enones from Propargyl Alcohols. Organometallics. 2010;29:4829-4836.
Molina DCA, Casey CP, Mueller I, Nozaki K, Jaekel C. New Low-Temperature NMR Studies Establish the Presence of a Second Equatorial-Apical Isomer of [(R,S)-Binaphos](CO)(2)RhH. Organometallics. 2010;29:3362-3367.
Casey CP. Tandem Rh/Ru Hydroformylation/Hydrogenation of Terminal Olefins to Linear Alcohols. Chemcatchem. 2010;2:1209-1211.
2009
Koren-Selfridge L, Londino HN, Vellucci JK, Simmons BJ, Casey CP, Clark TB. A Boron-Substituted Analogue of the Shvo Hydrogenation Catalyst: Catalytic Hydroboration of Aldehydes, Imines, and Ketones. Organometallics. 2009;28:2085-2090.
Casey CP, Guan HR. Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes. Journal of the American Chemical Society. 2009;131:2499-2507.
Casey CP, Boller TM, Samec JSM, Reinert-Nash JR. Quantitative Determination of the Regioselectivity of Nucleophilic Addition to eta(3)-Propargyl Rhenium Complexes and Direct Observation of an Equilibrium between eta(3)-Propargyl Rhenium Complexes and Rhenacyclobutenes. Organometallics. 2009;28:123-131.
2008
Casey CP, Beetner SE, Johnson JB. Spectroscopic determination of hydrogenation rates and intermediates during carbonyl hydrogenation catalyzed by Shvo's hydroxycyclopentadienyl diruthenium hydride agrees with kinetic modeling based on independently measured rates of elementary reactions. Journal of the American Chemical Society. 2008;130:2285-2295.
2007
Casey CP, Guan H. An efficient and chemoselective iron catalyst for the hydrogenation of ketones. Journal of the American Chemical Society. 2007;129:5816-+.
Casey CP, Francisco JS, Masciangioli TM. The future of US chemistry research: Benchmarks and challenges. Journal of Chemical Education. 2007;84:1089-1089.
Casey CP, Clark TB, Guzei IA. Intramolecular trapping of an intermediate in the reduction of Imines by a hydroxycyclopentadienyl ruthenium hydride: Support for a concerted outer sphere mechanism. Journal of the American Chemical Society. 2007;129:11821-11827.
Casey CP, Wong C-H. Partly cloudy with a chance of showers. ACS Chemical Biology. 2007;2:573-576.
2006
Casey CP, Carpenetti DW, Sakurai H. Models for intermediates in metallocene-catalyzed alkene polymerization: Alkene dissociation from Cp2Zr[eta(1) eta(2)-CH2Si(CH3)(2)CH2CH=CH2][B(C6F5)(4)]. Organometallics. 2006;25:1230-1235.
2005
Casey CP, Johnson JB, Singer SW, Cui Q. Hydrogen elimination from a hydroxycyclopentadienyl ruthenium(II) hydride: Study of hydrogen activation in a ligand-metal bifunctional hydrogenation catalyst. Journal of the American Chemical Society. 2005;127:3100-3109.
Casey CP, Bikzhanova GA, Cui Q, Guzei IA. Reduction of Imines by hydroxycyclopentadienyl ruthenium hydride: Intramolecular trapping evidence for hydride and proton transfer outside the coordination sphere of the metal. Journal of the American Chemical Society. 2005;127:14062-14071.
2000
Casey CP, Kraft S, Powell DR. Dimerization of rhenium alkynyl carbene complexes by a process involving two 1,1.5 rhenium shifts and coupling of the remote alkynyl carbons. Journal of the American Chemical Society. 2000;122:3771-3772.
Casey CP, Klein JF, Fagan MA. Kinetics and thermodynamics of alkene complexation in d(0) metal-alkyl-alkene complexes. Journal of the American Chemical Society. 2000;122:4320-4330.
Casey CP, Carpenetti DW. Measurement of barriers for alkene dissociation and for inversion at zirconium in a d(0) zirconium-alkyl-alkene complex. Organometallics. 2000;19:3970-3977.
1999
Casey CP, Paulsen EL, Beuttenmueller EW, Proft BR, Matter BA, Powell DR. Electronically dissymmetric DIPHOS derivatives give higher n : i regioselectivity in rhodium-catalyzed hydroformylation than either of their symmetric counterparts. Journal of the American Chemical Society. 1999;121:63-70.
Casey CP, Carpenetti DW, Sakurai H. Observation of zwitterionic d(0) zirconium-alkyl-alkene chelates: Models for intermediates in metallocene-catalyzed alkene polymerizations. Journal of the American Chemical Society. 1999;121:9483-9484.
1998
Casey CP, Brady JT. Acid-catalyzed isomerization of rhenium alkyne complexes to rhenium allene complexes via 1-metallacyclopropene intermediates. Organometallics. 1998;17:4620-4629.
Casey CP, Fagan MA, Hallenbeck SL. Alkene dissociation from a d(0) yttrocene-alkyl-alkene complex generates a pyramidal alkyl yttrium complex that inverts slowly. Organometallics. 1998;17:287-289.
Casey CP, Czerwinski CJ, Fraley ME. Chelated alkyl halide manganese complexes (eta(5):eta(1)-C5H4CH2CH2X)Mn(CO)(2) from photolysis of (eta(5)-C5H4CH2CH2X)Mn(CO)(3). Inorganica Chimica Acta. 1998;280:316-321.
Casey CP, Fisher JJ. Coordination of a disubstituted alkene in a chelated d(0)-metal-alkyl-alkene complex. Evidence for equilibrium between complexes with coordinated and free alkenes. Inorganica Chimica Acta. 1998;270:5-7.
Casey CP, Nash JR, Yu CS, Selmeczy AD, Chung S, Powell DR, Hayashi RK. Kinetic addition of nucleophiles to eta(3)-propargyl rhenium complexes occurs at the central carbon to produce rhenacyclobutenes. Journal of the American Chemical Society. 1998;120:722-733.
Casey CP, Brady JT, Boller TM, Weinhold F, Hayashi RK. Protonation of rhenium alkyne complexes produces eta(3)-allyl rhenium complexes via observable 1-metallacyclopropene intermediates. Journal of the American Chemical Society. 1998;120:12500-12511.
Casey CP, Carino RS, Brady JT, Hayashi RK. Reaction of Cp*(CO)(2)Re=Re(CO)(2)Cp* in THF with diethyl fumarate produces Cp*Re(CO)(3) and Cp*Re(CO)(eta(2)-(E)-EtO2CCH=CHCO2Et)(THF). Journal of Organometallic Chemistry. 1998;569:55-60.
1997
Casey CP, Czerwinski CJ, Powell DR, Hayashi RK. Cis addition of hydrogen chloride to an amphiphilic carbene complex. Journal of the American Chemical Society. 1997;119:5750-5751.
Casey CP, Paulsen EL, Beuttenmueller EW, Proft BR, Petrovich LM, Matter BA, Powell DR. Electron withdrawing substituents on equatorial and apical phosphines have opposite effects on the regioselectivity of rhodium catalyzed hydroformylation. Journal of the American Chemical Society. 1997;119:11817-11825.
Casey CP, Hallenbeck SL, Wright JM, Landis CR. Formation and spectroscopic characterization of chelated d(0) yttrium(III)-alkyl-alkene complexes. Journal of the American Chemical Society. 1997;119:9680-9690.
Casey CP, Chung S, Ha Y, Powell DR. Formation of platinum allyl and propargyl complexes from protonation of platinum enyne and diyne complexes. Inorganica Chimica Acta. 1997;265:127-138.
Casey CP, Carino RS, Sakaba H. Reaction of Cp*(CO)(2)Re=Re(CO)(2)Cp* with alkynes produces dimetallacyclopentenones Cp*(CO)(2)Re(mu-eta(1),eta(3)-CR=CR'CO)Re(CO)Cp* which react with acid to form cationic bridging vinyl complexes. Organometallics. 1997;16:419-426.
Casey CP, Underiner TL, Vosejpka PC, Slough GA, Gavney JA, Hayashi RK. Rearrangement of rhenium allyl vinyl ketone complexes. Organometallics. 1997;16:2189-2199.
Casey CP, Czerwinski CJ, Fusie KA, Hayashi RK. Ring strain perturbation of the equilibria between hydroxycarbene complexes and metal acyl hydride complexes. Journal of the American Chemical Society. 1997;119:3971-3978.
1996
Casey CP, Czerwinski CJ, Hayashi RK. Formation of a dirhenium carbene complex from reaction of (eta(5)-C5H4Li)Re(CO)(3) with (eta 5-C5H5)Re(CO)(3). Organometallics. 1996;15:4362-4365.
Casey CP, Carino RS, Sakaba H, Hayashi RK. Ligand additions to Cp*(CO)(2)Re=Re(CO)(2)Cp* and fragmentation and rearrangement reactions of CP*(CO)(2)Re(mu-CO)Re(CO)(L)Cp*. Organometallics. 1996;15:2640-2649.
Casey CP, Boese WT, Carino RS, Ford PC. Photochemical rearrangement of a rhenium dimetallacyclobutene studied by time-resolved infrared spectroscopy. Organometallics. 1996;15:2189-2191.
Casey CP, Carino RS, Hayashi RK, Schladetzky KD. Reaction of Cp*(CO)(2)Re=Re(CO)(2)Cp* with dimethyl acetylenedicarboxylate produces a 3,4-dimetallacyclobutene which undergoes photochemical isomerization to a 2,4-dimetallabicyclo 1.1.0 butane. Journal of the American Chemical Society. 1996;118:1617-1623.
Casey CP, Selmeczy AD, Nash JR, Yi CS, Powell DR, Hayashi RK. Synthesis of eta(3)-propargyl rhenium complexes. Journal of the American Chemical Society. 1996;118:6698-6706.
1995
Casey CP, Petrovich LM. (CHELATING DIPHOSPHINE)RHODIUM-CATALYZED DEUTERIOFORMYLATION OF 1-HEXENE - CONTROL OF REGIOCHEMISTRY BY THE KINETIC RATIO OF ALKYLRHODIUM SPECIES FORMED BY HYDRIDE ADDITION TO COMPLEXED ALKENE. Journal of the American Chemical Society. 1995;117:6007-6014.
Casey CP, Hallenbeck SL, Widenhoefer RA. KINETICS AND MECHANISM OF THE FORMATION OF THE BIS(ETHYLIDYNE) TRICOBALT CLUSTER CP-ASTERISK(3)CO(3)(MU(3)-CCH3)2 FROM REACTION OF ACETYLENE WITH CP-ASTERISK(3)CO(3)(MU(2)-H)(3)(MU(3)-H). Journal of the American Chemical Society. 1995;117:4607-4622.
Casey CP, Widenhoefer RA, Hayashi RK. REACTIONS OF CP(3)(ASTERISK)CO(3)(MU(2)-H)(3)(MU(3)-H) WITH CARBON-DIOXIDE, CARBON-DISULFIDE, AND PHENYL ISOCYANATE. Inorganic Chemistry. 1995;34:1138-1144.
1994
Barckholtz TA, Bursten BE, Niccolai GP, Casey CP. AN ANALYSIS OF THE METAL-METAL BONDING IN ORGANODIRHENIUM COMPLEXES CONTAINING RE-RE DOUBLE-BONDS. Journal of Organometallic Chemistry. 1994;478:153-160.
Casey CP, Widenhoefer RA, Hallenbeck SL, Hayashi RK. SYNTHESES AND X-RAY CRYSTAL-STRUCTURES OF THE TRICOBALT MONO(ETHYLIDYNE) CLUSTERS CP-ASTERISK-3CO3(MU-3-CCH3)(MU-3-CO)(MU-2-H), CP-ASTERISK-3CO3(MU-3-CCH3)(MU-3-CNCME3)(MU-2-H), AND CP-ASTERISK-3CO3(MU-3-CCH3)(MU-3-NO). Inorganic Chemistry. 1994;33:2639-2644.
Casey CP, Widenhoefer RA, Hallenbeck SL, Hayashi RK, Gavney JA. SYNTHESES, X-RAY CRYSTAL-STRUCTURES, AND FLUXIONAL BEHAVIOR OF THE CLUSTERS CP-ASTERISK-CO-3(3)(MU(2)-CO)(MU(3)-CO)(MU-H)(2), CP-ASTERISK-CO-3(3)(MU(2)-H)(MU(3)-ETA(2)-HC=NCME(3)), AND CP-ASTERISK-3CO3(MU(2)-H)(MU(3)-ETA(2)-HC=NCME(2)CH(2)ME). Organometallics. 1994;13:4720-4731.
Casey CP, Ha YY, Powell DR. SYNTHESIS AND REACTION OF RHENIUM ENYNE, AND VINYLALKENYLIDENE COMPLEXES. Journal of Organometallic Chemistry. 1994;472:185-193.
Casey CP, Ha YK, Powell DR. SYNTHESIS AND REACTIONS OF DIRHENIUM ALKENYLIDENE AND ALKYLIDYNE COMPLEXES. Journal of the American Chemical Society. 1994;116:3424-3428.
1993
Casey CP, Widenhoefer RA, Hallenbeck SL. CONVERSION OF ACETYLENE TO A TRIPLE BRIDGED ETHYLIDYNE LIGAND ON THE CLUSTER CP-ASTERISK-3CO3(MU(2)-H)3(MU(3)-H). Organometallics. 1993;12:3788-3789.

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