All Faculty and Research Staff Publications

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2017
Ahmed MS, Mannel DS, Root TW, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd-Bi-Te/C (PBT/C) Catalyst. Org. Process Res. Dev. 2017 ;21:1388-1393.
Goldsmith ZK, Harshan AK, Gerken JB, Voros M, Galli G, Stahl SS, Hammes-Schiffer S. Characterization of NiFe oxyhydroxide electrocatalysts by integrated electronic structure calculations and spectroelectrochemistry. Proceedings of the National Academy of Sciences of the United States of America. 2017 ;114:3050-3055.
Stahl SS, Rovis T. Cluster Preface: Catalytic Aerobic Oxidations. Synlett. 2017 ;28:1546-1547.
Hruszkewycz DP, Miles KC, Thiel OR, Stahl SS. Co/NHPI-mediated aerobic oxygenation of benzylic C-H bonds in pharmaceutically relevant molecules. Chemical Science. 2017 ;8:1282-1287.
Jaworski JN, McCann SD, Guzei IA, Stahl SS. Detection of Palladium(I) in Aerobic Oxidation Catalysis. Angewandte Chemie-International Edition. 2017 ;56:3605-3610.
Mannel DS, Ahmed MS, Root TW, Stahl SS. Discovery of Multicomponent Heterogeneous Catalysts via Admixture Screening: PdBiTe Catalysts for Aerobic Oxidative Esterification of Primary Alcohols. Journal of the American Chemical Society. 2017 ;139:1690-1698.
Walroth RC, Miles KC, Lukens JT, MacMillan SN, Stahl SS, Lancaster KM. Electronic Structural Analysis of Copper(II)-TEMPO/ABNO Complexes Provides Evidence for Copper(I)-Oxoammonium Character. Journal of the American Chemical Society. 2017 ;139:13507-13517.
Vasilopoulos A, Zultanski SL, Stahl SS. Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes. Journal of the American Chemical Society. 2017 ;139:7705-7708.
Das A, Stahl SS. Noncovalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene-TEMPO Conjugate. Angewandte Chemie-International Edition. 2017 ;56:8892-8897.
Wang DA, Stahl SS. Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)(2) and Discovery of Fe(OTf)(3) as a Highly Effective Cocatalyst. Journal of the American Chemical Society. 2017 ;139:5704-5707.
McCann SD, Lumb JP, Arndtsen BA, Stahl SS. Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diannine Precursor into a Highly Active Aerobic Oxidation Catalyst. Acs Central Science. 2017 ;3:314-321.
2016
Badalyan A, Stahl SS. Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators. Nature. 2016 ;535:406-410.
Anson CW, Ghosh S, Hammes-Schiffer S, Stahl SS. Co(salophen)-Catalyzed Aerobic Oxidation of p-Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis. Journal of the American Chemical Society. 2016 ;138:4186-4193.
White PB, Jaworski JN, Zhu GHarry, Stahl SS. Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions. Acs Catalysis. 2016 ;6:3340-3348.
Shaner SE, Hooker PD, Nickel AM, Leichtfuss AR, Adams CS, de la Cerda D, She YQ, Gerken JB, Pokhrel R, Ambrose NJ, et al. Discovering Inexpensive, Effective Catalysts for Solar Energy Conversion: An Authentic Research Laboratory Experience. Journal of Chemical Education. 2016 ;93:650-657.
Miles KC, Abrams ML, Landis CR, Stahl SS. KetoABNO/NOx Cocatalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to alpha-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation. Organic Letters. 2016 ;18:3590-3593.
McCann SD, Stahl SS. Mechanism of Copper/Azodicarboxylate-Catalyzed Aerobic Alcohol Oxidation: Evidence for Uncooperative Catalysis. Journal of the American Chemical Society. 2016 ;138:199-206.
Iosub AV, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products. Acs Catalysis. 2016 ;6:8201-8213.
Zultanski SL, Zhao JY, Stahl SS. Practical Synthesis of Amides via Copper/ABNO-Catalyzed Aerobic Oxidative Coupling of Alcohols and Amines. Journal of the American Chemical Society. 2016 ;138:6416-6419.
Huynh MT, Anson CW, Cavell AC, Stahl SS, Hammes-Schiffer S. Quinone 1 e(-) and 2 e(-)/2 H+ Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships. Journal of the American Chemical Society. 2016 ;138:15903-15910.
Clagg K, Hou HY, Weinstein AB, Russell D, Stahl SS, Koenig SG. Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C-H Bonds. Organic Letters. 2016 ;18:3586-3589.
2015
Pokhrel R, Goetz MK, Shaner SE, Wu XX, Stahl SS. The "Best Catalyst" for Water Oxidation Depends on the Oxidation Method Employed: A Case Study of Manganese Oxides. Journal of the American Chemical Society. 2015 ;137:8384-8387.
Iosub AV, Stahl SS. Catalytic Aerobic Dehydrogenation of Nitrogen Heterocycles Using Heterogeneous Cobalt Oxide Supported on Nitrogen-Doped Carbon. Organic Letters. 2015 ;17:4404-4407.
McCann SD, Stahl SS. Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst. Accounts of Chemical Research. 2015 ;48:1756-1766.
Kim J, Stahl SS. Cu-Catalyzed Aerobic Oxidative Three-Component Coupling Route to N-Sulfonyl Amidines via an Ynamine Intermediate. Journal of Organic Chemistry. 2015 ;80:2448-2454.
Xie XM, Stahl SS. Efficient and Selective Cu/Nitroxyl-Catalyzed Methods for Aerobic Oxidative Lactonization of Diols. Journal of the American Chemical Society. 2015 ;137:3767-3770.
Rafiee M, Miles KC, Stahl SS. Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects. Journal of the American Chemical Society. 2015 ;137:14751-14757.
Osterberg PM, Niemeier JK, Welch CJ, Hawkins JM, Martinelli JR, Johnson TE, Root TW, Stahl SS. Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry. Org. Process Res. Dev. 2015 ;19:1537-1543.
Parajuli R, Gerken JB, Keyshar K, Sullivan I, Sivasankar N, Teamey K, Stahl SS, Cole EB. Integration of Anodic and Cathodic Catalysts of Earth-Abundant Materials for Efficient, Scalable CO2 Reduction. Topics in Catalysis. 2015 ;58:57-66.
Chen JYC, Dang LN, Liang HF, Bi WL, Gerken JB, Jin S, Alp EE, Stahl SS. Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe4+ by Mossbauer Spectroscopy. Journal of the American Chemical Society. 2015 ;137:15090-15093.
Zultanski SL, Stahl SS. Palladium-catalyzed aerobic acetoxylation of benzene using NOx-based redox mediators. Journal of Organometallic Chemistry. 2015 ;793:263-268.
Iosub AV, Stahl SS. Palladium-Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexenes to Substituted Arene Derivatives. Journal of the American Chemical Society. 2015 ;137:3454-3457.
Steves JE, Preger Y, Martinelli JR, Welch CJ, Root TW, Hawkins JM, Stahl SS. Process Development of CuI/ABNO/NMI-Catalyzed Aerobic Alcohol Oxidation. Org. Process Res. Dev. 2015 ;19:1548-1553.
Greene JF, Preger Y, Stahl SS, Root TW. PTFE-Membrane Flow Reactor for Aerobic Oxidation Reactions and Its Application to Alcohol Oxidation. Org. Process Res. Dev. 2015 ;19:858-864.
Wendlandt AE, Stahl SS. Quinone-Catalyzed Selective Oxidation of Organic Molecules. Angewandte Chemie-International Edition. 2015 ;54:14638-14658.
Zheng CW, Stahl SS. Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to alpha-alkyl vinylarenes. Chemical Communications. 2015 ;51:12771-12774.
Steves JE, Stahl SS. Stable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl-Catalyzed Aerobic Alcohol Oxidation. Journal of Organic Chemistry. 2015 ;80:11184-11188.
2014
Stephenson NA, Gellman SH, Stahl SS. Ammonolysis of anilides promoted by ethylene glycol and phosphoric acid. Rsc Advances. 2014 ;4:46840-46843.
Wendlandt AE, Stahl SS. Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst. Journal of the American Chemical Society. 2014 ;136:506-512.
Rahimi A, Ulbrich A, Coon JJ, Stahl SS. Formic-acid-induced depolymerization of oxidized lignin to aromatics. Nature. 2014 ;515:249-52.
Chen JYC, Miller JT, Gerken JB, Stahl SS. Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion. Energy & Environmental Science. 2014 ;7:1382-1386.
Ryland BL, McCann SD, Brunold TC, Stahl SS. Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals. Journal of the American Chemical Society. 2014 ;136:12166-12173.
Wendlandt AE, Stahl SS. Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions. Journal of the American Chemical Society. 2014 ;136:11910-11913.
Diao TN, Stahl SS. O-2-promoted allylic acetoxylation of alkenes: Assessment of "push" versus "pull" mechanisms and comparison between O-2 and benzoquinone. Polyhedron. 2014 ;84:96-102.
Gladysz JA, Bedford RB, Fujita M, Gabbai FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, et al. Organometallics Roundtable 2013-2014. Organometallics. 2014 ;33:1505-1527.
Weinstein AB, Stahl SS. Palladium catalyzed aryl C-H amination with O2 via in situ formation of peroxide-based oxidant(s) from dioxane. Catal. Sci. Technol. 2014 ;4:4301-4307.
Weinstein AB, Stahl SS. Palladium catalyzed aryl C-H amination with O-2 via in situ formation of peroxide-based oxidant(s) from dioxane. Catalysis Science & Technology. 2014 ;4:4301-4307.
Wang D, Izawa Y, Stahl SS. Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates. Journal of the American Chemical Society. 2014 ;136:9914-9917.
Ryland BL, Stahl SS. Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems. Angewandte Chemie-International Edition. 2014 ;53:8824-8838.
Tsybizova A, Ryland BL, Tsierkezos N, Stahl SS, Roithova J, Schroder D. Speciation Behavior of Copper( II) Acetate in Simple Organic Solvents - Revealing the Effect of Trace Water. European Journal of Inorganic Chemistry. 2014 ;2014:1407-1412.

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