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Synthesis and characterization of three new thermally stable N-heterocyclic germylenes
Wed, 11/28/2012 - 1:39pm — root
| Title | Synthesis and characterization of three new thermally stable N-heterocyclic germylenes |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Tomasik, AC, Hill, NJ, West, R |
| Journal | Journal of Organometallic Chemistry |
| Volume | 694 |
| Pagination | 2122-2125 |
| Date Published | Jun |
| Accession Number | ISI:000266270400023 |
| Keywords | aluminum-hydride, amides, amines, carbene, chemistry, Chemistry, Inorganic & Nuclear, Chemistry, Organic, Complexes, General-synthesis, Germanium, germylene, Organogermanium, reactivity, secondary, silylene |
| Abstract | Three new stable germylenes, rac-1,3-di-tert-butyl-4,5-dimethyl-1,3-diaza-2-germacyclopentane2-ylide (1), 1,3-di-tert-butyl-4,4-dimethyl-1,3-diaza-2-germacyclopentane-2-ylide (2), and rac-1,3,4-tritert-butyl-1,3-diaza-2-germacyclopentane-2-ylide (3) have been synthesized by the reaction of their corresponding germyl dichlorides with elemental lithium. Full synthetic procedures and characterizations are described. (c) 2009 Elsevier B.V. All rights reserved. |
| Short Title | J. Organomet. Chem. |
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