Stahl Publications by Year
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2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001
| 2012 |
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103. "Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines"
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102. "Copper(II)-mediated oxidative cyclization of enamides to oxazoles" |
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101. "Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles" |
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100. "Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles" |
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99. "Overcoming the "Oxidant Problem": Strategies to Use O2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu)" |
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98. "C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities" |
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97. "Direct Aerobic α,β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)2/4,5-Diazafluorenone Catalyst" |
| 2011 |
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96. "Reversible Alkene Insertion into the Pd-N Bond of Pd(II)-Sulfonamidates and Implications for Catalytic Amidation Reactions" |
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95. "Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights" |
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94. "Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols" |
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93. "Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones" |
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92. "Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands" |
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91. "Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity" |
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90. "Observation and Mechanistic Study of Facile C-O Bond Formation Between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles" |
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89. "Reaction of O2 with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L]+ "Reductive Elimination" Pathway" |
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88. "Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces" |
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87. "Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols" |
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86. "Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex"
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85. "Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands"
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84. "Benzoquinone-Promoted Reaction of O2 with a PdII-Hydride"
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83. "Highly Stable Redox-Active Molecular Layers by Covalent Grafting to Conductive Diamond"
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82. "Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications" |
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81. "Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)2/Pyridine"
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80. "O2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways"
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| 2010 |
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79. "Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization"
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78. "Allylic C-H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy to Achieve Aerobic Catalytic Turnover"
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77. "Molecular mechansim of acid-triggered aryl-halide reductive elimination in well-defined aryl-CuIII-halide species"
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76. "Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands"
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75. "Fluoride-Modulated Cobalt Catalysts for Electrochemical Oxidation of Water under Non-Alkaline Conditions"
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74. "Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C-H Bond: Evidence for an Aryl-Copper(III) Intermediate"
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73. "Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0)"
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72. "Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides"
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| 71. "Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions" Ye, X.; Johnson, M. D.; Diao, T.; Yates, M. H.; Stahl, S. S. Green Chem., 2010, 12, 1180-1186. PDF. Supporting Info. Front Cover. ("Editor's Choice" in Science, Vol 329, July 2, 2010) (C&E News, June 24, 2010.)
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70. "Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions"
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69. "Kinetics of Anionic Ring-Opening Polymerization of Variously Substituted β-Lactams: Homopolymerization and Copolymerization"
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68. "Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers"
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| 2009 |
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67. "Nylon-3 Copolymers that Generate Cell-Adhesive Surfaces Identified by Library Screening"
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66. "Regioselective Copper-Catalyzed Chlorination and Bromination of Arenes with O2 as the Oxidant" |
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65. "Catalytic Transamidation Reactions Compatible with Tertiary Amide Metathesis under Ambient Conditions"
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64. "Structure-activity Relationships among Random Nylon-3 Copolymers that Mimic Antibacterial Host-Defense Peptides"
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63. "Synthesis of Pd(II) Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions"
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62. "Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction"
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61. "Steric Modulation of Chiral Biaryl Diamines via Pd-Catalyzed Directed C−H Arylation"
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60. "Synthesis and Isolation of a Stable, Axially-Chiral Seven-Membered N-Heterocyclic Carbene"
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59. "Mechanism of Pd(OAc)2/Pyridine Catalyst Reoxidation by O2: Influence of Labile Monodentate Ligands and Identification of a Biomimetic Mechanism for O2 Activation"
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58. "Access to Poly-β-Peptides with Functionalized Side Chains and End Groups via Controlled Ring-Opening Polymerization of β-Lactams"
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| 2008 |
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57. "Synthesis of β-Lactams Bearing Functionalized Side Chains from a Readily Available Precursor"
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56. "Dual Mechanism of Bacterial Lethality for a Cationic Sequence-Random Copolymer that Mimics Host-Defense Antimicrobial Peptides"
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55. "Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity"
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54. "Carbon-Nitrogen Bond Formation Involving Well-Defined Aryl-Copper(III) Complexes"
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53. "Reaction of Molecular Oxygen with a Pd(II)-Hydride To Produce a Pd(II)-Hydroperoxide: Experimental Evidence for an HX-Reductive-Elimination Pathway"
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52. "Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes: Efficient Synthesis of Ynamides"
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51. "Discovery and Mechanistic Study of Al(III)-Catalyzed Transamidation of Tertiary Amides"
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| 2007 |
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50. "Mimicry of Antimicrobial Host-Defense Peptides by Random Copolymers"
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49. "Palladium-Catalyzed Oxidative Amination of Alkenes: Improved Catalyst Reoxidation Enables the Use of Alkene as the Limiting Reagent"
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48. "The Two-Faced Reactivity of Alkenes: Cis - Versus Trans- Aminopalladation in Aerobic Pd- Catalyzed Intramolecular Aza-Wacker Reactions."
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47. "Insertion of Molecular Oxygen into a Pd-Hydride Bond: Computational Evidence for Two Nearly Isoenergetic Pathways."
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46. "Palladium-Catalyzed Aerobic Oxidative Amination of Alkenes: Development of Intra- and Intermolecular Aza-Wacker Reactions."
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45. "Reaction of Molecular Oxygen with an NHC-Coordinated Pd(0) Complex: Computational Insights and Experimental Implications."
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44. "Catalytic Metathesis of Simple Secondary Amides."
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43. "Ti(IV) - Mediated Reactions between Primary Amines and Secondary Carboxamides: Amidine Formation Versus Transamidation."
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42. "Palladium-Catalyzed Oxidation Reactions: Comparison of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants." |
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41. "N-Heterocyclic Carbenes as Ligands for High-Oxidation-State Metal Complexes and Oxidation Catalysis." |
| 2006 |
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40. "Synthesis of Pyrrolidines via Palladium(II)-Catalyzed Aerobic Oxidative Carboamination of Butyl Vinyl Ether and Styrenes with Allyl Tosylamides."
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39. "Highly Regioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and Evidence for cis -Aminopalladation and SN2 C-O Bond Formation."
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38. "Aerobic Intramolecular Oxidative Amination of Alkenes Catalyzed by NHC-Coordinated Palladium Complexes."
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37. "Reaction of Molecular Oxygen with a Pd(II)-Hydride to Produce a Pd(II)- Hydroperoxide: Acid Catalysis and Implications for Pd-Catalyzed Aerobic Oxidation Reactions."
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36. "Mechanism of Aluminum(III)-Catalyzed Transamidation of Unactivated Secondary Carboxamides."
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35. "Mechanism of Pd(OAc)2/DMSO-Catalyzed Aerobic Alcohol Oxidation: Mass-Transfer-Limitation Effects and Catalyst Decomposition Pathways."
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34. " 'Oxidatively-Induced' Reductive Elimination of Dioxygen from an η2-Peroxopalladium(II) Complex Promoted by Electron-Deficient Alkenes."
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33. "Unexpected Roles of Molecular Sieves in Palladium-Catalyzed Aerobic Oxidation Reactions."
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32. "Similarities Between the Reactions of Dioxygen and Alkenes with Palladium(0): Relevance to the Use of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants in Palladium-Catalyzed Oxidation Reactions."
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| 2005 |
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31. "Brønsted Base-Modulated Regioselectivity in the Aerobic Oxidative Amination of Styrene Catalyzed by Palladium."
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30. "Palladium-Catalyzed Oxidation of Organic Chemicals with O2." |
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29. "Titanium(IV)-Mediated Conversion of Carboxamides to Amidines and Implications for Catalytic Transamidation."
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28. "Development of 7-Membered N-Heterocyclic Carbene Ligands for Transition Metals."
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27. "Palladium(II) Complexes Possessing a Seven-Membered N-Heterocyclic Carbene Ligand."
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26. "Effects of Side Chain Configuration and Backbone Spacing on the Gene Delivery Properties of Lysine-Derived Cationic Polymers." |
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25. "Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium."
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| 2004 |
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24. "Insights into the Spin-Forbidden Reaction between L2Pd(0) and Molecular Oxygen."
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23 . "Inverse-Electron-Demand" Ligand Substitution: Experimental and Computational Insights into Olefin Exchange at Palladium(0)."
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22. "Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by Pd(OAc)2 / Pyridine Including Identification of the Catalyst Resting State and the Origin of Non-Linear [Catalyst] Dependence."
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21. "Characterization of Peroxo and Hydroperoxo Intermediates in the Aerobic Oxidation of N-Heterocyclic-Carbene-Coordinated Palladium(0)."
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20. "Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals via Direct Dioxygen-Coupled Catalytic Turnover."
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19. "Formation of Enamides via Palladium(II)-Catalyzed Vinyl Transfer from Vinyl Ethers to Nitrogen Nucleophiles."
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| 2003 |
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18. "Dioxygen-Coupled Oxidative Amination of Styrene."
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17. "Catalytic Transamidation under Moderate Conditions."
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16. "Inverse-Electron-Demand" Ligand Substitution in Palladium(0) Olefin Complexes."
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| 2002 |
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15. "The Wisconsin Schlenk Line: Incorporation of an Ergonomic Greaseless Three-Way Valve Design."
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14. "Ligand-Modulated Palladium Oxidation Catalysis: Mechanistic Insights into Aerobic Alcohol Oxidation with the Pd(OAc)2 / Pyridine Catalyst System."
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13. "Mechanistic Study of Alcohol Oxidation by the Pd(OAc)2/O2/DMSO Catalyst System and Implications for the Development of Improved Aerobic Oxidation Catalysts."
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12. "Efficient Intramolecular Oxidative Amination of Olefins through Direct Dioxygen-Coupled Palladium Catalysis."
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| 2001 |
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11. "Oxygenation of Nitrogen-Coordinated Palladium(0): Synthetic, Structural and Mechanistic Studies and Implications for Aerobic Oxidation Catalysis." |
| PUBLICATIONS (graduate and postdoctoral work) |
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10. "Oxygen Kinetic Isotope Effects in Methane Monooxygenase ." |
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9. "Dioxygen and Alkane Activation by Iron-Containing Enzymes." |
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8. "Mechanistic Studies of the Reaction of Reduced Methane Monooxygenase Hydroxylase with Dioxygen and Substrates" |
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7. "Homogeneous Oxidation of Alkanes by Electrophilic Late Transition Metals." |
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6. "Investigation of the Factors Affecting the Stability of Dihydrogen Adducts of Platinum(II)." |
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5. "Alkylplatinum(II) Intermediates in C-H Activation by Platinum Complexes in Aqueous Solution." |
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4. "Exploring the Mechanism of Aqueous C-H Activation by Pt(II) through Model Chemistry: Evidence for the Intermediacy of Alkylhydridoplatinum(IV) and Alkane σ-Adducts." |
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3. "Formation and Reductive Elimination of a Hydridoalkylplatinum(IV) Intermediate upon Protonolysis of an Alkylplatinum(II) Complex." |
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2. "C-H Activation by Aqueous Platinum Complexes: A Mechanistic Model." |
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1. "Oxidation of Zeise's Salt by [PtCl6]2- : A Mechanistic Model for Hydrocarbon Oxidation." |
| PATENTS |
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3. "Poly-β-Peptides From Functionalized β-Lactam Monomers and Antibacterial Compositions Containing Same." |
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2. "Seven-Membered Heterocyclic Carbenes and their Metal Complexes." |
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1. "Catalytic Transamidation and Amide Metathesis under Moderate Conditions." |
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3. J. Am. Chem. Soc. book review of Organotransition Metal Chemistry: From Bonding to Catalysis . By John Hartwig (University of Illinois, Urbana-Champaign). University Science Books: Sausalito, CA. 2010. Stahl, S. S. J. Am. Chem. Soc., Article ASAP DOI: 10.1021/ja103695e. PDF. |
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2. Book review for Angew. Chem. : |
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1. Stahl, S. S. Chemical and Engineering News, 2001 , 79(13), 282. |




















































































