Stahl Publications by Year

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2012 | 2011

2010 | 200920082007200620052004200320022001

 

2012

103.  "Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines"
 Wendlandt, A. E.; Stahl, S. S. Org. Lett. 2012, DOI: 10.1021/ol301095j.  PDF SI

 

 

102.  "Copper(II)-mediated oxidative cyclization of enamides to oxazoles"
 Wendlandt, A. E.; Stahl, S. S. Org. Biomol. Chem. 2012, 10, 3866-3870.  PDF SI

 

101.  "Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles"
 Lu, Z.; Stahl, S. S. Org. Lett. 201214, 1234–1237.  PDF SI

 

100.  "Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles"
 Redford, J. E.; McDonald, R. I.; Rigsby, M. L.; Wiensch, J. D.; Stahl, S. S. Org. Lett. 2012, 14, 1242–1245.  PDF SI

 

99.  "Overcoming the "Oxidant Problem": Strategies to Use O2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu)"
 Campbell, A. N.; Stahl, S. S. Acc. Chem. Res. 2012, DOI:  10.1021/ar2002045. PDF 

 

98.  "C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities"
 Zhang, Z.; Markiewicz, M. J.; Mowery, B. P.; Weisblum, B.; Stahl, S. S.; Gellman, S. H. Biomacromolecules 2012, 13, 323–331.  PDF SI1 SI2

 

97.  "Direct Aerobic α,β-Dehydrogenation of Aldehydes and Ketones with a Pd(TFA)2/4,5-Diazafluorenone Catalyst"
 Diao, T.; Wadzinski, T. J.; Stahl, S. S. Chem. Sci. 2012, 3, 887-891.  PDF SI

 
2011

96.  "Reversible Alkene Insertion into the Pd-N Bond of Pd(II)-Sulfonamidates and Implications for Catalytic Amidation Reactions"
 White, P. B.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 18594-18597.  PDF SI1 SI2

 

95.  "Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights"
 Wendlandt, A. E.; Suess, A. M.; Stahl, S. S. Angew. Chem. Int. Ed. 2011, 50, 11062-11087.  PDF 

 

94.  "Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols"
 Hoover, J. M.; Stahl, S. S. J. Am. Chem. Soc. 2011133, 16901-16910.  PDF Supporting Info 

 

93.  "Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones"
 Diao, T.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 14566-14569.   PDF. Supporting Info. 

 

92.  "Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands"
 Campbell, A. N.; Meyer, E. B.; Stahl, S. S. Chem. Commun. 2011, 47, 10257-10259.  PDF. Supporting Info. 

 

91.  "Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity"
 Gerken, J. B.; McAlpin, J. G.; Chen, J. Y. C.; Rigsby, M. L.; Casey, W. H.; Britt, R. D.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 14431-14442.  PDF. Supporting Info. 

 

90.  "Observation and Mechanistic Study of Facile C-O Bond Formation Between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles"
 Huffman, L. M.; Casitas, A.; Font, M.; Canta, M.; Costas, M.; Ribas, X.; Stahl, S. S. Chem. Eur. J. 2011, 17, 10643-10650.  PDF. Supporting Info. 

 

89.  "Reaction of O2 with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L]+ "Reductive Elimination" Pathway"
 Decharin, N.; Popp, B. V.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 13268–13271.  PDF. Supporting Info. 

 

88.  "Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces"
 Benson, M. C.; Ruther, R. E.; Gerken, J. B.; Rigsby, M. L.; Bishop, L. M.; Tan, Y.; Stahl, S. S.; Hamers, R. J. ACS Appl. Mater. Interfaces 2011, 3, 3110–3119.  PDF. Supporting Info. 

 

87.  "Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols"
 Izawa, Y.; Pun, D.; Stahl, S. S. Science 2011, 333, 209-213. PDF. Supporting Info.
 (C&E News 2011, 89, 8.)

 

86.  "Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex"
 Huffman, L. M.; Stahl, S. S. Dalton Trans. 2011, 40, 8959-8963B.  PDF. Supporting Info.

 

85.  "Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands"
 McDonald, R. I.; White, P. B.; Weinstein, A. B.; Tam, C. P.; Stahl, S. S. Org. Lett. 2011, 13, 2830-2833.  PDF. SI1. SI2.

 

84.  "Benzoquinone-Promoted Reaction of O2 with a PdII-Hydride"
 Decharin, N.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 5732-5735.  PDF. Supporting Info.

 

83.  "Highly Stable Redox-Active Molecular Layers by Covalent Grafting to Conductive Diamond"
 Ruther, R. E.; Rigsby, M. L.; Gerken, J. B.; Hogendoorn, S. R.; Landis, E. C.; Stahl, S. S.; Hamers, R. J.  J. Am. Chem. Soc. 2011, 133, 5692-5694.  PDFSupporting Info  

 

82.  "Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications"
 McDonald, R. I.; Liu, G.; Stahl, S. S. Chem. Rev. 2011, 111, 2981-3019.  PDF.

 

81.  "Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)2/Pyridine"
 Ye, X.; Liu, G.; Popp, B. V.; Stahl, S. S.  J. Org. Chem., 2011, 76, 1031-1044.  PDF. Supporting Info.

 

80.  "O2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways"
 Konnick, M. M.; Decharin, N.; Popp, B. V.; Stahl, S. S.  Chem. Sci., 2011, 2, 326-330.  PDF. Supporting Info. 

 
2010

79.  "Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization"
 Izawa, Y.; Stahl, S. S.  Adv. Synth. Catal., 2010, 352, 3223-3229. PDF. Supporting Info.

 

78.  "Allylic C-H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy to Achieve Aerobic Catalytic Turnover"
 Campbell, A. N.; White, P. B.; Guzei, I. A.; Stahl, S. S. J. Am. Chem. Soc., 2010, 132, 15116–15119.  PDF. Supporting Info. 

 

77.  "Molecular mechansim of acid-triggered aryl-halide reductive elimination in well-defined aryl-CuIII-halide species"
 Casitas, A.; Poater, A.; Sola, M.; Stahl, S. S.; Costas, M.; Ribas, X.  Dalton Trans., 2010, 39, 10458-10463.  PDF. Supporting Info. 

 

76.  "Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands"
 McDonald, R. I.; Wong, G. W.; Neupane, R. P.; Stahl, S. S.; Landis, C. R. J. Am. Chem. Soc., 2010, 132, 14027-14029.  PDF. Supporting Info. 

 

75.  "Fluoride-Modulated Cobalt Catalysts for Electrochemical Oxidation of Water under Non-Alkaline Conditions"
 Gerken, J. B.; Landis, E. C.; Hamers, R. J.; Stahl, S. S. ChemSusChem, 2010, 3, 1176-1179.  PDF. Supporting Info. 

 

74.  "Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C-H Bond: Evidence for an Aryl-Copper(III) Intermediate"
King, A. E.; Huffman, L. M.; Casitas, A.; Costas, M.; Ribas, X.; Stahl, S. S.  J. Am. Chem. Soc., 2010, 132, 12068-12073. PDF. Supporting Info.

 

73. "Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0)" 
Popp, B. V.; Morales, C. M.; Landis, C. R.; Stahl, S. S.  Inorg. Chem., 2010, 49, 8200-8207. PDF. Supporting Info. Front Cover.

 

72. "Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides"    
McDonald, R. I.; Stahl, S. S. Angew. Chem. Int. Ed., 2010, 49, 5529-5532. PDF. Supporting Info.

 
71. "Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions"   
Ye, X.; Johnson, M. D.; Diao, T.; Yates, M. H.; Stahl, S. S. Green Chem., 2010, 12, 1180-1186.  PDF. Supporting Info. Front Cover.
 ("Editor's Choice" in Science, Vol 329, July 2, 2010)
 (C&E News, June 24, 2010.)                                                                                     

 

 

70. "Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions" 
Casitas, A.; King, A. E.; Parella, T.; Costas, M.; Stahl, S. S.; Ribas, X.  Chem. Sci., 2010, 1, 326-330. PDF. Supporting Info.

 

69. "Kinetics of Anionic Ring-Opening Polymerization of Variously Substituted β-Lactams: Homopolymerization and Copolymerization"
Zhang, J.; Gellman, S. H.; Stahl, S. S. Macromolecules, 2010, 43 (13), 5618–5626.  PDF. Supporting Info.

 

 

68. "Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers"
Dohm, M. T.; Mowery, B. P.; Czyzewski, A. M.; Stahl, S. S.; Gellman, S. H.; Barron, A. E. J. Am. Chem. Soc., 2010, 132 (23), 7957-7967. PDF. Supporting Info.

 
2009

67. "Nylon-3 Copolymers that Generate Cell-Adhesive Surfaces Identified by Library Screening"
Lee, M.-R.; Stahl, S. S.; Gellman, S. H.; Masters, K. S. J. Am. Chem. Soc., 2009, 131 (46), 16779–16789. PDF . Supporting Info

 

66. "Regioselective Copper-Catalyzed Chlorination and Bromination of Arenes with O2 as the Oxidant"
Yang, L.; Lu, Z.; Stahl, S. S. Chem. Commun., 2009, 6460-6462. PDF . Supporting Info

 

65. "Catalytic Transamidation Reactions Compatible with Tertiary Amide Metathesis under Ambient Conditions"
Stephenson, N. S.; Zhu, J.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc., 2009, 131 (29), 10003–10008. PDF

 

64. "Structure-activity Relationships among Random Nylon-3 Copolymers that Mimic Antibacterial Host-Defense Peptides"
Mowery, B. P.; Lindner, A. H.; Weisblum, B.;Stahl, S. S.; Gellman, S. H. J. Am. Chem. Soc., 2009, 131 (28), 9735–9745. PDFSupporting Info

 

63. "Synthesis of Pd(II) Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions"
Scarborough, C. C.; Bergant, A.;Sazamaa, G.T.; Guzeia, I.A.; Spencera, L.C.; Stahl, S. S. Tetrahedron, 2009, 65 (26), 5084-5092. PDF

 

62. "Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction"
King, A. E.; Brunold, T. C.; Stahl, S. S. J. Am. Chem. Soc., 2009, 131, 5044–5045. PDF . Supporting Info

 

61. "Steric Modulation of Chiral Biaryl Diamines via Pd-Catalyzed Directed C−H Arylation"
Scarborough, C. C.; McDonald, R I.; Hartmann, C.; Sazama, G. T.; Bergant, A.; Stahl, S. S. J. Org. Chem., 2009, 74 (6), 2613-2615. PDF . Supporting Info

 

60. "Synthesis and Isolation of a Stable, Axially-Chiral Seven-Membered N-Heterocyclic Carbene"
Scarborough, C. C.; Guzei, I. A.; Stahl, S. S. Dalton Trans., 2009, 2284-2286. PDF . Supporting Info

 

59. "Mechanism of Pd(OAc)2/Pyridine Catalyst Reoxidation by O2: Influence of Labile Monodentate Ligands and Identification of a Biomimetic Mechanism for O2 Activation"
Popp, B. V. ; Stahl, S. S. Chem. Eur. J., 2009, 15, 2915-2933. PDF . Supporting Info

 

58. "Access to Poly-β-Peptides with Functionalized Side Chains and End Groups via Controlled Ring-Opening Polymerization of β-Lactams"
Zhang, J.;Kissounko, D. A.; Lee, S. E.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc., 2009, 131 (4), 1589-1597. PDF . Supporting Info

 
2008
 

57. "Synthesis of β-Lactams Bearing Functionalized Side Chains from a Readily Available Precursor"
Lee, M.; Stahl, S. S.; Gellman, S. H. Org. Lett., 2008, 10 (22), 5317-5319. PDF . Supporting Info

 

56. "Dual Mechanism of Bacterial Lethality for a Cationic Sequence-Random Copolymer that Mimics Host-Defense Antimicrobial Peptides"
Epand, R. F.; Mowery, B. P.; Lee, S. E.; Stahl, S. S.; Lehrer, R. I.; Gellman, S. H.; Epand,R. M. J. Mol. Biol., 2008, 379, 38–50. PDF

 

55. "Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity"
Hewgley, J. B.; Stahl, S. S.; Kozlowski, M. C. J. Am. Chem. Soc., 2008, 130 (37), 12232-12233. PDF . Supporting Info

 

54. "Carbon-Nitrogen Bond Formation Involving Well-Defined Aryl-Copper(III) Complexes"
Huffman, L. M.; Stahl, S. S. J. Am. Chem. Soc., 2008, 130 (29), 9196-9197. PDF . Supporting Info

 

53. "Reaction of Molecular Oxygen with a Pd(II)-Hydride To Produce a Pd(II)-Hydroperoxide: Experimental Evidence for an HX-Reductive-Elimination Pathway"
Konnick, M. M.; Stahl, S. S. J. Am. Chem. Soc., 2008, 130 (17); 5753-5762. PDF . Supporting Info

 

52. "Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes: Efficient Synthesis of Ynamides"
Hamada, T.; Ye, X.; Stahl, S. S. J. Am. Chem. Soc., 2008, 130, 833-835. PDF . Supporting Info (Experimental) .
Supporting Info (NMR spectra)

 

51. "Discovery and Mechanistic Study of Al(III)-Catalyzed Transamidation of Tertiary Amides"
Hoerter, J. M.; Otte, K. M.; Gellman, S. H.; Cui, Q.; Stahl, S. S. J. Am. Chem. Soc., 2008, 130, 647-654. PDF . Supporting Info

 
2007
 

50. "Mimicry of Antimicrobial Host-Defense Peptides by Random Copolymers"
Mowery, B. P.; Lee, S. E.; Kissounko, D. A.; Epand, R. F.; Epand, R. M.; Weisblum, B.; Stahl, S. S.; Gellman, S. H. J. Am. Chem. Soc., 2007, 129, 15474-15476. PDF . Supporting Info

 

49. "Palladium-Catalyzed Oxidative Amination of Alkenes: Improved Catalyst Reoxidation Enables the Use of Alkene as the Limiting Reagent"
Rogers, M. M.; Kotov, V.; Chatwichien, J.; Stahl, S. S. Org. Lett., 2007, 9, 4331-4334. PDF . Supporting Info

 

48. "The Two-Faced Reactivity of Alkenes: Cis - Versus Trans- Aminopalladation in Aerobic Pd- Catalyzed Intramolecular Aza-Wacker Reactions."
Liu, G.; Stahl, S. S. J. Am. Chem. Soc., 2007, 129, 6328-6335. PDF. Supporting Info.

 

47. "Insertion of Molecular Oxygen into a Pd-Hydride Bond: Computational Evidence for Two Nearly Isoenergetic Pathways."
Popp, B. V.; Stahl, S. S. J. Am. Chem. Soc., 2007, 129, 4410-4422. PDF . Supporting Info

 

46. "Palladium-Catalyzed Aerobic Oxidative Amination of Alkenes: Development of Intra- and Intermolecular Aza-Wacker Reactions."
Kotov, V.; Scarborough , C. C.; Stahl, S. S. Inorg. Chem., 2007, 46, 1910-1923. PDF
- Inorganic Chemistry "Forum" on Palladium Chemistry Relevant to Organic Synthetic Methodology)

 

45. "Reaction of Molecular Oxygen with an NHC-Coordinated Pd(0) Complex: Computational Insights and Experimental Implications."
Popp, B. V.; Wendlandt, J. E.; Landis, C. R.; Stahl, S. S. Angew. Chem. Int. Ed., 2007, 46, 601-604 . PDF
- Identified as a "Very Important Paper" (VIP) by Angew. Chem.

 

44. "Catalytic Metathesis of Simple Secondary Amides."
Bell, C. Kissounko, D. A.; Gellman, S. H.; Stahl, S. S. Angew. Chem. Int. Ed., 2007, 46, 761-763 . PDF

 

43. "Ti(IV) - Mediated Reactions between Primary Amines and Secondary Carboxamides: Amidine Formation Versus Transamidation."
Kissounko, D. A.; Hoerter, J. M.; Guzei, I. A.; Cui, Q.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc., 2007, 129, 1776-1783 . PDF . Supporting Info .

 

42. "Palladium-Catalyzed Oxidation Reactions: Comparison of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants."
Popp, B. V.; Stahl, S. S. In Organometallic Oxidation Catalysis, Meyer, F., Limberg, C. Eds.; Springer: New York , 2007; Vol. 22,
149-189. PDF

 

41. "N-Heterocyclic Carbenes as Ligands for High-Oxidation-State Metal Complexes and Oxidation Catalysis."
Rogers, M. M.; Stahl, S. S. In N-Heterocyclic Carbenes in Transition Metal Catalysis, Glorius, F., Ed.; Springer: New York , 2007;
Vol. 21, 21-46. PDF

 
2006
 

40. "Synthesis of Pyrrolidines via Palladium(II)-Catalyzed Aerobic Oxidative Carboamination of Butyl Vinyl Ether and Styrenes with Allyl Tosylamides."
Scarborough , C. C.; Stahl, S. S. Org. Lett., 2006, 8, 3251-3254. PDF . Supporting Info.

 

39. "Highly Regioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and Evidence for cis -Aminopalladation and SN2 C-O Bond Formation."
Liu, G.; Stahl, S. S. J. Am. Chem. Soc., 2006, 128, 7179-7181. PDF . Supporting Info (Experimental) . Supporting Info (NMR spectra)

 

38. "Aerobic Intramolecular Oxidative Amination of Alkenes Catalyzed by NHC-Coordinated Palladium Complexes."
Rogers, M. M.; Wendlandt, J. E.; Guzei, I. A.; Stahl, S. S. Org. Lett., 2006, 8, 2257-2260. PDF .Supporting Info (Experimental) . Supporting Info (NMR spectra)

 

37. "Reaction of Molecular Oxygen with a Pd(II)-Hydride to Produce a Pd(II)- Hydroperoxide: Acid Catalysis and Implications for Pd-Catalyzed Aerobic Oxidation Reactions."
Konnick, M. M.; Gandhi, B. A.; Guzei, I. A.; Stahl, S. S. Angew. Chem. Int. Ed., 2006, 45, 2904-2907. PDF .
- Identified by ACS Publications as a "2006 Most-Cited Article".

 

36. "Mechanism of Aluminum(III)-Catalyzed Transamidation of Unactivated Secondary Carboxamides."
Hoerter, J. M.; Otte, K. M.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc., 2006, 128, 5177-5183 . PDF . Supporting Info

 

35. "Mechanism of Pd(OAc)2/DMSO-Catalyzed Aerobic Alcohol Oxidation: Mass-Transfer-Limitation Effects and Catalyst Decomposition Pathways."
Steinhoff, B. A.; Stahl, S. S. J. Am. Chem. Soc., 2006, 128, 4348-4355 . PDF . Supporting Info

 

34. " 'Oxidatively-Induced' Reductive Elimination of Dioxygen from an η2-Peroxopalladium(II) Complex Promoted by Electron-Deficient Alkenes."
Popp, B. V.; Stahl, S. S. J. Am. Chem. Soc., 2006, 128, 2804-2805. PDF . Supporting Info

 

33. "Unexpected Roles of Molecular Sieves in Palladium-Catalyzed Aerobic Oxidation Reactions."
Steinhoff, B. A.; King, A. E.; Stahl, S. S. J. Org. Chem., 2006, 71, 1861-1868. PDF

 

32. "Similarities Between the Reactions of Dioxygen and Alkenes with Palladium(0): Relevance to the Use of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants in Palladium-Catalyzed Oxidation Reactions."
Popp, B. V.; Thorman, J. L.; Stahl, S. S. J. Mol. Catal. A: Chem., 2006, 251, 2-7. PDF
- Special journal issue devoted to research presented at the ADHOC 2005 conference in Cologne , Germany (ADHOC = Activation of Dioxygen and Homogeneous Oxidation Catalysis).

 
2005
 

31. "Brønsted Base-Modulated Regioselectivity in the Aerobic Oxidative Amination of Styrene Catalyzed by Palladium."
Timokhin, V. I. ; Stahl, S. S. J. Am. Chem. Soc., 2005, 127, 17888-17893. PDF . Supporting Info

 

30. "Palladium-Catalyzed Oxidation of Organic Chemicals with O2."
Stahl, S. S. Science, 2005, 309, 1824-1826. PDF

 

29. "Titanium(IV)-Mediated Conversion of Carboxamides to Amidines and Implications for Catalytic Transamidation."
Kissounko, D. A.; Guzei, I. A.; Gellman, S. H.; Stahl, S. S. Organometallics, 2005, 24, 5208-5210. PDF . Supporting Info

 

28. "Development of 7-Membered N-Heterocyclic Carbene Ligands for Transition Metals."
Scarborough, C. C.; Popp, B. V.; Guzei, I. A.; Stahl, S. S. J. Organomet. Chem., 2005, 690, 6143-6155. PDF
- Special journal issue devoted to recent developments in N -heterocyclic-carbene chemistry.

 

27. "Palladium(II) Complexes Possessing a Seven-Membered N-Heterocyclic Carbene Ligand."
Scarborough, C. C.; Grady, M. J. W.; Guzei, I. A.; Gandhi, B. A.; Bunel, E. E.; Stahl, S. S. Angew. Chem. Int. Ed., 2005, 44, 5269-5272 . PDF

 

26. "Effects of Side Chain Configuration and Backbone Spacing on the Gene Delivery Properties of Lysine-Derived Cationic Polymers."
Eldred, S. E.; Pancost, M. R.; Otte, K. M.; Rozema, D.; Stahl, S. S.; Gellman, S. H. Bioconjugate Chem., 2005, 16, 694-699. PDF

 

25. "Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium."
Brice, J. L.; Harang, J. E.; Timokhin, V. I.; Anastasi, N. R.; Stahl, S. S. J. Am. Chem. Soc., 2005, 127, 2868-2869 . PDF . Supporting Info .

 
2004
 

24. "Insights into the Spin-Forbidden Reaction between L2Pd(0) and Molecular Oxygen."
Landis, C. R.; Morales, C. M.; Stahl, S. S. J. Am. Chem. Soc., 2004, 126, 16302-16303 . PDF . Supporting Info

 

23 . "Inverse-Electron-Demand" Ligand Substitution: Experimental and Computational Insights into Olefin Exchange at Palladium(0)."
Popp, B. V.; Thorman, J. L.; Morales, C. M.; Landis, C. R.; Stahl, S. S. J. Am. Chem. Soc., 2004, 126, 14832-14842. PDF .
Supporting Info .

 

22. "Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by Pd(OAc)2 / Pyridine Including Identification of the Catalyst Resting State and the Origin of Non-Linear [Catalyst] Dependence."
Steinhoff, B. A.; Guzei, I. A.; Stahl S. S. J. Am. Chem. Soc., 2004, 126, 11268-11278. PDF . Supporting Info .

 

21. "Characterization of Peroxo and Hydroperoxo Intermediates in the Aerobic Oxidation of N-Heterocyclic-Carbene-Coordinated Palladium(0)."
Konnick, M. M.; Guzei, I. A.; and Stahl, S. S. J. Am. Chem. Soc., 2004, 126, 10212-10213. PDF . Supporting Info .

 

20. "Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals via Direct Dioxygen-Coupled Catalytic Turnover."
Stahl, S. S. Angew. Chem. Int. Ed., 2004, 43, 3400-3420. PDF . Cover Picture.

 

19. "Formation of Enamides via Palladium(II)-Catalyzed Vinyl Transfer from Vinyl Ethers to Nitrogen Nucleophiles."
Brice, J. l.; Meerdink, J. M.; Stahl, S. S. Org. Lett., 2004, 6, 1845-1848. PDF . Supporting Info

 
2003
 

18. "Dioxygen-Coupled Oxidative Amination of Styrene."
Timokhin, V. I.; Anastasi, N. R.; Stahl, S. S. J. Am. Chem. Soc., 2003, 125, 12996-12997. PDF . Supporting Info

 

17. "Catalytic Transamidation under Moderate Conditions."
Eldred, S. E.; Stone, D. A.; Gellman, S. H.; Stahl, S. S. J. Am. Chem. Soc., 2003, 125, 3422-3423. PDF
  ("Science Concentrate", C&E News, March 17, 2003.)
  ("Chemistry Highlight" for the year 2003, C&E News, December 22, 2003)

 

16. "Inverse-Electron-Demand" Ligand Substitution in Palladium(0) Olefin Complexes."
Stahl, S. S.; Thorman, J. L.; de Silva, N.; Guzei, I. A.; Clark, R. W. J. Am. Chem. Soc., 2003, 125, 12-13. PDF . Supporting Info

 
2002
 

15. "The Wisconsin Schlenk Line: Incorporation of an Ergonomic Greaseless Three-Way Valve Design."
Drier, T. O.; Stahl, S. S. Fusion, 2002 (3), 25-27 . PDF .
- Journal cover photograph.

 

14. "Ligand-Modulated Palladium Oxidation Catalysis: Mechanistic Insights into Aerobic Alcohol Oxidation with the Pd(OAc)2 / Pyridine Catalyst System."
Steinhoff, B. A.; Stahl, S. S. Org. Lett., 2002, 4, 4179-4181. PDF . Supporting Info .

 

13. "Mechanistic Study of Alcohol Oxidation by the Pd(OAc)2/O2/DMSO Catalyst System and Implications for the Development of Improved Aerobic Oxidation Catalysts."
Steinhoff, B. A.; Fix, S. R.; Stahl, S. S. J. Am. Chem. Soc., 2002, 124, 766-767. PDF . Supporting Info

 

12. "Efficient Intramolecular Oxidative Amination of Olefins through Direct Dioxygen-Coupled Palladium Catalysis."
Fix, S. R.; Brice, J. L.; Stahl, S. S. Angew. Chem. Int. Ed., 2002, 41, 164-166. PDF

 

 
2001
 

11. "Oxygenation of Nitrogen-Coordinated Palladium(0): Synthetic, Structural and Mechanistic Studies and Implications for Aerobic Oxidation Catalysis."
Stahl, S. S.; Thorman, J. L.; Nelson, R. C.; Kozee, M. A. J. Am. Chem. Soc., 2001, 123, 7188-7189. PDF . Supporting Info

 
PUBLICATIONS (graduate and postdoctoral work)
 

10. "Oxygen Kinetic Isotope Effects in Methane Monooxygenase ."
Stahl, S. S.; Francisco, W. A.; Merkx, M.; Klinman, J. P.; Lippard, S. J. J. Biol. Chem., 2001, 276, 4549-4553. PDF

 

9. "Dioxygen and Alkane Activation by Iron-Containing Enzymes."
Stahl, S. S.; Lippard, S. J. In Iron Metabolism: Inorganic Biochemistry and Regulatory Mechanism ; Ferreira, G. C., Moura, J. J. G., Franco, R., Eds.; Wiley-VCH: Weinheim, Germany, 1999, pp 303-321.

 

8. "Mechanistic Studies of the Reaction of Reduced Methane Monooxygenase Hydroxylase with Dioxygen and Substrates"
Valentine, A. M.; Stahl, S. S.; Lippard, S. J. J. Am. Chem. Soc., 1999, 121, 3876-3887. PDF

 

7. "Homogeneous Oxidation of Alkanes by Electrophilic Late Transition Metals."
Stahl, S. S.; Labinger, J. A..; Bercaw, J. E. Angew. Chem. Int. Ed., 1998, 37, 5000-5012. PDF

 

6. "Investigation of the Factors Affecting the Stability of Dihydrogen Adducts of Platinum(II)."
Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Inorg. Chem., 1998, 37, 2422-2431. PDF

 

5. "Alkylplatinum(II) Intermediates in C-H Activation by Platinum Complexes in Aqueous Solution."
Wang, L.; Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Mol. Catal., A, 1997, 116, 269-275. PDF

 

4. "Exploring the Mechanism of Aqueous C-H Activation by Pt(II) through Model Chemistry: Evidence for the Intermediacy of Alkylhydridoplatinum(IV) and Alkane σ-Adducts."
Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc., 1996, 118, 5961-5976. PDF

 

3. "Formation and Reductive Elimination of a Hydridoalkylplatinum(IV) Intermediate upon Protonolysis of an Alkylplatinum(II) Complex."
Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc., 1995, 117, 9371-9372. PDF

 

2. "C-H Activation by Aqueous Platinum Complexes: A Mechanistic Model."
Luinstra, G. A.; Wang, L.; Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Organomet. Chem., 1995, 504, 75-91. PDF

 

1. "Oxidation of Zeise's Salt by [PtCl6]2- : A Mechanistic Model for Hydrocarbon Oxidation."
Luinstra, G. A.; Wang, L.; Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Organometallics, 1994, 13, 755-756. PDF

 
PATENTS
 

3. "Poly-β-Peptides From Functionalized β-Lactam Monomers and Antibacterial Compositions Containing Same."
Stahl, S. S.; Gellman, S. H.; Lee, S. E.; Ilker, M. F.; Weisblum, B.; Kissounko, D. A. U. S. Patent 20070087404, April 19, 2007

 

2. "Seven-Membered Heterocyclic Carbenes and their Metal Complexes."
Stahl, S. S.; Scarborough , C. C. EP20060733854, January 23, 2008.

 

1. "Catalytic Transamidation and Amide Metathesis under Moderate Conditions."
Stahl, S. S.; Gellman, S. H.; Eldred, S. E. U.S. Patent 7,154,004, December 26, 2006.

 

INVITED PUBLICATIONS, BOOK REVIEWS

 

3.  J. Am. Chem. Soc. book review of Organotransition Metal Chemistry: From Bonding to Catalysis . By John Hartwig (University of Illinois, Urbana-Champaign). University Science Books: Sausalito, CA. 2010.

Stahl, S. S. J. Am. Chem. Soc., Article ASAP DOI: 10.1021/ja103695e. PDF.

 

2. Book review for Angew. Chem. :
Tsuji, J. Palladium Reagents and Catalysts: New Perspectives for the 21st Century Wiley: West Sussex, England , 2004, 656 pp.

 

1. Stahl, S. S. Chemical and Engineering News, 2001 , 79(13), 282.
(special issue celebrating the 125 th Anniversary of the American Chemical Society)
Big Challenges Ahead from Small Molecules: Catalysis Research Will Have Profound Imspact on Future National and Global Welfare. PDF