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Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands
Tue, 11/27/2012 - 11:52am — root
| Title | Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands |
| Publication Type | Journal Article |
| Year of Publication | 2011 |
| Authors | Campbell, AN, Meyer, EB, Stahl, SS |
| Journal | Chemical Communications |
| Volume | 47 |
| Pagination | 10257-10259 |
| Accession Number | WOS:000294500600015 |
| Keywords | activation, bond, C-h functionalization, chemistry, coordinated palladium(0), direct arylation, formation, metalation-deprotonation mechanism, molecular-oxygen, turnover |
| Abstract | Palladium-catalyzed aerobic oxidative cross-couplings of indoles and benzene have been achieved by using 4,5-diazafluorene derivatives as ancillary ligands. Proper choice of the neutral and anionic ligands enables control over the reaction regioselectivity. |
| Short Title | Chem. Commun |
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