| Title | Raman and extended X-ray absorption fine structure characterization of a sulfur-ligated Cu(I) ethylene complex: Modeling the proposed ethylene binding site of Arabidopsis thaliana ETR1 |
| Publication Type | Journal Article |
| Year of Publication | 2001 |
| Authors | Hirsch, J, George, SD, Solomon, EI, Hedman, B, Hodgson, KO, Burstyn, JN |
| Journal | Inorganic ChemistryInorganic Chemistry |
| Volume | 40 |
| Pagination | 2439-+ |
| Date Published | May |
| Type of Article | Article |
| ISBN Number | 0020-1669 |
| Accession Number | ISI:000168524100040 |
| Keywords | COPPER(I) COMPLEXES, olefins, UNSATURATED SMALL MOLECULES |
| Abstract | An ethylene complex of a thioether-ligated Cu(I) center was synthesized and characterized by Raman spectroscopy and EXAFS. Long Cu(I)-C bonds and low Cu-C vibrational frequencies reveal weak binding of the gaseous ligand. |
| Short Title | Raman and extended X-ray absorption fine structure characterization of a sulfur-ligated Cu(I) ethylene complex: Modeling the proposed ethylene binding site of Arabidopsis thaliana ETR1Inorg. Chem.Inorg. Chem. |
| Alternate Journal | Inorg. Chem. |