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Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu-III-halide species
Tue, 11/27/2012 - 11:52am — root
| Title | Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu-III-halide species |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Casitas, A, Poater, A, Sola, M, Stahl, SS, Costas, M, Ribas, X |
| Journal | Dalton Transactions |
| Volume | 39 |
| Pagination | 10458-10463 |
| Accession Number | ISI:000283601900014 |
| Keywords | activation, Bond formation, Chemistry, Inorganic & Nuclear, Complexes, copper, Coupling reactions, density, exchange, halogen, ligands, monocarbonyls |
| Abstract | Well-defined aryl-Cu-III-halide species undergo reductive elimination upon acid addition resulting in the formation of strong aryl-halide bonds. The computationally studied mechanism points towards ligand protonation as the rate-determining step, in agreement with previous experimental data. |
| Short Title | Dalton Trans |
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