Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex

TitleMechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex
Publication TypeJournal Article
Year of Publication2011
AuthorsHuffman, LM, Stahl, SS
JournalDalton Transactions
Volume40
Pagination8959-8963
Accession NumberWOS:000294475500030
Keywordsarylation, Bond formation, chemistry, copper(iii) intermediate, Coupling reactions, ligands, selectivities
Abstract

A net trans C-N reductive elimination reaction is observed from a macrocyclic aryl-Cu(III) complex, and a mechanistic study of this reaction indicates that coordinating ligands play a role in mediating this unusual transformation.

Short TitleDalton Trans