Return to Casey Group Research Topics.
- Slow Exponential Decrease in Aliphatic Inductive Effects with Distance in Addition of Trifluoroacetic Acid to Alkenes Having Remote Substituents, Peterson, P. E.; Casey, C. P. Tetrahedron Lett. 1963, 1569.
- Solvents of Low Nucleophilicity V. Platinum-Catalyzed Hydrogenation of Ketones, Tertiary Alcohols and Esters, and Tosylates in Acidic Solvents Including Trifluoroacetic Acid, Peterson, P. E.; Casey, C. P. J. Org. Chem. 1964, 29, 2325.
- Solvents of Low Nucleophilicity VI. The Effects of Remote Substituents in Addition of Trifluoroacetic Acid to Aliphatic, Cyclic and Bicyclic Alkenes, Peterson, P. E.; Casey, C. P.; Tao, E. V. P.; Agatrap, A. A.; Thompson, G. J. Am. Chem. Soc. 1965, 87, 5163.
- The Stereochemistry of the Thermal Decomposition of Vinylic Copper(I) and Silver(I) Organometallic Compounds, Whitesides, G. M.; Casey, C. P. J. Am. Chem. Soc. 1966, 88, 4541.
- Aliphatic Copper(I) and Silver(I) Organometallic Compounds, Whitesides, G. M.; Casey, C. P.; SanFilippo, Jr., J.; Panek, E. J. Trans. N.Y. Acad. Sci., Series II, 1967, 29, 572.
- Oxidative Coupling Using Copper(I) Ate Complexes, Whitesides, G. M.; SanFilippo, Jr., J.; Casey, C. P.; Panek, E. J. J. Am. Chem. Soc. 1967, 89, 5302.
- Reaction of Copper(I) Hydride with Organocopper(I) Compounds, Whitesides, G. M.; SanFilippo, Jr., J.; Stedronsky, E. R.; Casey, C. P. J. Am. Chem. Soc. 1969, 91, 6542.
- Mechanism of Thermal Decomposition of n-Butyl(tri-n-butylphosphine) Copper(I), Whitesides, G. M.; Stedronsky, E. R.; Casey, C. P.; SanFilippo, Jr., J. J. Am. Chem. Soc. 1970, 92, 1426.
- The Structure of King's Mn2(CO)10(CH2)3: A Cyclic Metal Carbene Complex, Casey, C. P. Chem. Commun. 1970, 1220.
- Hydroformylation of 3-methyl-1-hexene-3-d1. Evidence Against Direct Formylation of a Methyl Group in the 'Oxo' Reaction, Casey, C. P.; Cyr, C. R. J. Am. Chem. Soc. 1970, 93, 1280.
- The Thermal Decomposition of Vinylic Copper(I) and Silver(I) Organometallic Compounds, Whitesides, G. M.; Casey, C. P.; Krieger, J. K. J. Am. Chem. Soc. 1971, 93, 1379.
- Metal-Carbene Complexes from the Reaction of Methylpentacarbonylmanganese(I) with Sodium Pentacarbonylmanganate(-I), Casey, C. P.; Anderson, R. L. J. Am. Chem. Soc. 1971, 93, 3554. <
- Synthesis and Decarbonylation of Pyruvoylpentacarbonylmanganese, Casey, C. P.; Bunnell, C. A. J. Am. Chem. Soc. 1971, 93, 4077.
- Stereochemistry of the Addition of Lithium Dipropenylcuprate to 2-Cyclohexenone, Casey, C. P.; Boggs, R. A. Tetrahedron Lett. 1971, 2455.
- Nonstereospecific Formation of Olefins in the Norrish Type II Photochemical Cleavage of Ketones from the Singlet Excited State--Evidence for a Singlet Diradical Intermediate, Casey, C. P.; Boggs, R. A. J. Am. Chem. Soc. 1972, 94, 6457.
- Reactions of Metal-Carbene Complexes with Wittig Reagents--A New Vinyl Ether Synthesis, Casey, C. P.; Burkhardt, T. J. J. Am. Chem. Soc. 1972, 94, 6543.
- Generation and Reactions of Anions a to the Carbene Carbon Atom of Transition Metal-Carbene Complexes, Casey, C. P.; Boggs, R. A.; Anderson, R. L. J. Am. Chem. Soc. 1972, 94, 8947.
- Iron Carbonyl Catalyzed Isomerization of 3-Ethyl-1-Pentene--Multiple Olefin Isomerizations via a pi-Allyl Metal Hydride Intermediate, Casey, C. P.; Cyr, C. R. J. Am. Chem. Soc. 1973, 95, 2248.
- Olefin Isomerizations Accompanying the Hydroformylation of 3-Methyl-1-hexene-3-d1, Casey, C. P.; Cyr, C. R. J. Am. Chem. Soc. 1973, 95, 2240.
- Preparation and Molecular Structure of (3-Acetyl-4,5-dihydrofuran-2-yl) tetracarbonylmanganese(I), Casey, C. P.; Boggs, R. A.; Marten, D. F.; Calabrese, J. C. Chem. Commun. 1973, 243.
- Preparation of Transition Metal-Carbene Complexes Using Methyl Fluorosulfonate as an Alkylating Agent, Casey, C. P.; Cyr, C. R.; Boggs, R. A. Syn. Inorg. Metal-Org. Chem. 1973, 3, 249.
- Reaction of Lithium Dialkylcuprates with beta-Acetoxy alpha, beta-Unsaturated Carbonyl Compounds, A New Synthesis of alpha, beta-Unsaturated Carbonyl Compounds, Casey, C. P.; Marten, D. F. Tetrahedron Lett. 1973, 2071.
- Inversion of Configuration in the Bromination of Vinylmercurials, Casey, C. P.; Whitesides, G. M.; Kurth, J. J. Org. Chem. 1973, 38, 3406.
- Reaction of Metal-Carbene Complexes with Diazoalkanes. A Versatile New Vinyl Ether Synthesis, Casey, C. P.; Bertz, S. H.; Burkhardt, T. J. Tetrahedron Lett. 1973, 1421.
- Synthesis of Binuclear Metal-Carbene Complexes Containing Two Different Transition Metals: cis-(CO)5ReMn(CO)4C(OCH3)CH3 and cis-(CO)5ReMn(CO)4C(OCH3)C6H5, Casey, C. P.; Cyr, C. R. J. Organomet. Chem. 1973, 57, C69.
- (Diphenylcarbene)pentacarbonyltungsten(0), Casey, C. P.; Burkhardt, T. J. J. Am. Chem. Soc. 1973, 95, 5833.
- Thermal Decomposition of (Erythro-2,3-dimethylpentanoyl)pentacarbonylmanganese(I), Casey, C. P.; Cyr, C. R.; Grant, J. A. Inorg. Chem. 1974, 13, 910.
- A New General Synthesis of Isoprenoid Chains Employing the Reaction of Dialkylcuprates with beta-Acetoxy-alpha,beta-Unsaturated Esters, Casey, C. P.; Marten, D. F. Synth. Commun. 1973, 3, 321.
- Structure and Basicity of Anions Generated a to the Carbene Carbon Atom in Transition Metal Carbene Complexes, Casey, C. P.; Anderson, R. L. J. Am. Chem. Soc. 1974, 96, 1230.
- Stereoselective Synthesis of Both Z- and E-beta-acyloxy-alpha,beta-unsaturated Esters and Their Stereospecific Conversion to beta-Alkyl-alpha,beta-unsaturated Esters, Casey, C. P.; Marten, D. F. Tetrahedron Lett. 1974, 925.
- Reactions of Conjugate Bases of Metal Carbene Complexes with alpha-Bromo Esters, Casey, C. P.; Anderson, R. L. J. Organomet. Chem. 1974, 73, C28.
- Reaction of Metal-Carbene Complexes with Vinyllithium Reagents, Casey, C. P.; Brunsvold, W. R. J. Organomet. Chem. 1974, 77, 345.
- Synthesis and X-ray Structure of Tetramethylammonium cis-Acetylbenzoyltetracarbonylmanganate(I), Casey, C. P.; Bunnell, C. A. J. Chem. Soc., Chem. Commun. 1974, 733.
- Reactions of (Diphenylcarbene)pentacarbonyltungsten(0) with Alkenes. Role of Metal-Carbene Complexes in Cyclopropanation and Olefin Metathesis Reactions, Casey, C. P.; Burkhardt, T. J. J. Am. Chem. Soc. 1974, 96, 7808.
- Bisdecarbonylation of o-Carbomethoxybenzolypentacarbonylmanganese(I), Casey, C. P.; Bunnell, C. A. Inorg. Chem. 1975, 14, 796.
- Reactions of Metal Carbonyl Anions with Methyl Organometallics, Casey, C. P.; Cyr, C. R.; Anderson, R. L.; Marten, D. F. J. Am. Chem. Soc. 1975, 97, 3053.
- Book Review: The Chemistry of Organolithium Compounds by Wakefield, B. J.; Casey, C. P. J. Am. Chem. Soc. 1975, 97, 1990.
- Synthesis of alpha-Methylene-gamma-Butyrolactone via Transition Metal Carbene Complexes, Casey, C. P.; Brunsvold, W. R. J. Organomet. Chem. 1975, 102, 175.
- Thermolysis of (2-Oxyacyclopentylidene)pentacarbonylchromium(0): Evidence Against Free Carbenes in the Thermal Decomposition of Metal-Carbene Complexes, Casey, C. P.; Anderson, R. L. J. Chem. Soc., Chem. Commun. 1975, 895.
- Alkyl- and Arylpentacarbonyltungsten Anions, Casey, C. P.; Polichnowski, S. W.; Anderson, R. L. J. Am. Chem. Soc. 1975, 97, 7375.
- Site of Nucleophilic Attack on Acylpentacarbonylmanganese(I) Compounds, Casey, C. P.; Bunnell, C. A. J. Am. Chem. Soc. 1976, 98, 436.
- MO Calculations on Metal Carbene Complexes and Metal Acyl Complexes: The Importance of the LUMO in Determining the Site of Nucleophilic Attack, Block, T. J.; Fenske, R. F.; Casey, C. P. J. Am. Chem. Soc. 1976, 98, 441.
- Reactions of (CO)5WC(Tol)2 with Alkenes. A Model for Structural Selectivity in the Olefin Metathesis Reaction, Casey, C. P.; Tuinstra, H. E.; Saeman, M. C. J. Am. Chem. Soc. 1976, 98, 608.
- Synthesis, Crystal Structure and Stability of Pyruvoylpentacarbonylmanganese, Casey, C. P.; Bunnell, C. A.; Calabrese, J. C. J. Am. Chem. Soc. 1976, 98, 1166.
- An ESR Study of the Radical Anions Derived from Metal Carbene Complexes of Chromium, Molybdenum, and Tungsten, Krusic, P. J.; Klabunde, U.; Casey, C. P.; Block, T. F. J. Am. Chem. Soc. 1976, 98, 2015.
- Metal Carbene Complexes in Organic Synthesis, Casey, C. P. in Transition Metal Organometallics in Organic Synthesis, Vol. I, H. Alper, Editor, Academic Press, New York, NY, 1976, Chapter 3.
- Decarbonylation of beta-Carbomethoxypropionylpentacarbonylmanganese(I), Casey, C. P.; Brunsvold, W. R.; Koch, J. Inorg. Chem. 1976, 15, 1991.
- The Effects of Alkyl Substitution on the Thermodynamic Stability and the Kinetic Reactivity of alpha-Anions of Metal Carbene Complexes, Casey, C. P.; Brunsvold, W. R. J. Organomet. Chem. 1976, 118, 309.
- alpha-Anions of Metal Carbene Complexes in Organic Synthesis, Casey, C. P. J. Organomet. Chem. Library 1976, 1, 397.
- Synthesis of Transition Metal Formyl Compounds by Nucleophilic Attack of Hydride on Co-ordinated CO, Casey, C. P.; Neumann, S. M. J. Am. Chem. Soc. 1976, 98, 5395.
- Synthesis and Crystal Structure of Diphenylcarbene(pentacarbonyl) tungsten(0), Casey, C. P.; Burkhardt, T. J.; Bunnell, C. A.; Calabrese, J. C. J. Am. Chem. Soc. 1977, 99, 2127.
- Conjugate Addition of Enolate Anions to Vinyl Carbene Complexes, Casey, C. P.; Brunsvold, W. R. Inorg. Chem. 1977, 16, 391.
- Generation and Reactions of (Phenylmethylcarbene)pentacarbonyltungsten(0), Casey, C. P.; Albin, L. D.; Burkhardt, T. J. J. Am. Chem. Soc. 1977, 99, 2533.
- Reaction of Molecular Hydrogen with Metal-Carbene Complexes: Reductive Cleavage of the Carbene Ligand, Casey, C. P.; Neumann, S. M. J. Am. Chem. Soc. 1977, 99, 1651.
- (Diphenylcarbene)pentacarbonyltungsten(0), Casey, C. P.; Burkhardt, T. J.; Neumann, S. M.; Scheck, D. M. Inorganic Synthesis 1979, 19, 180.
- (2-Oxacyclopentylidene)pentacarbonylchromium(0), Casey, C. P.; Anderson, R. L.; Neumann, S. M.; Scheck, D. M. Inorganic Synthesis 1979, 19, 178.
- In Situ Generation and Reactions of (CO)5WC(C6H5)H with Alkenes - Role of Puckered Metallocyclobutanes in Determining the Stereochemistry of Cyclopropane Formation, Casey, C. P. Polichnowski, S. W. J. Am. Chem. Soc. 1977, 99, 6097.
- Conjugate Addition of Carbene Anions to alpha, beta-Unsaturated Carbonyl Compounds, Casey, C. P.; Brunsvold, W. R.; Scheck, D. M. Inorg. Chem. 1977, 16, 3059.
- Synthesis of Tetramethylammonium cis-Acetylphenyltetracarbonylrhenate(I) - A Stable Acyclic Alkyl-Acyl Metal Complex, Casey, C. P.; Scheck, D. M. J. Organomet. Chem. 1978, 142, C12.
- Stereochemistry of the Degenerate Matathesis of Terminal Alkenes - the Nature of the Chain-Carrying Metal-Carbene Complex, Casey, C. P.; Tuinstra, H. E. J. Am. Chem. Soc. 1978,100, 2270.
- Hydride Donation Reactions of Transition Metal Formyl Complexes, Casey, C. P.; Neumann, S. M. J. Am. Chem. Soc. 1978, 100, 2544.
- The Electrochemical Reduction of Arylmethoxycarbene Complexes of Chromium, Molybdenum and Tungsten, Casey, C. P.; Albin, L. D.; Saeman, M. C.; Evans, D. H. J. Organometal. Chem. 1978, 155, C37.
- Mechanistic Studies Related to the Metal Catalyzed Reduction of Carbon Monoxide to Hydrocarbons, Casey, C. P.; Neumann, S. M. in Inorganic Compounds with Unusual Properties -II. Advances in Chemistry Series, No. 173, American Chemical Society, Washington, D. C., 1979, Chapter 12.
- Transition Metal Carbene Complexes in Organic Synthesis, Casey, C. P. in Advances in Pesticide Science Part 2, H. Geissbuhler, Editor, Pergamon Press, Oxford, England, 1979, pp. 148-159.
- Synthesis, X-ray Crystal Structure, and Temperature Dependent NMR Spectrum of Tetraethylammonium alpha-Methoxybenzylpentacarbonyltungstate, Casey, C. P.; Polichnowski, S. W. Albin, L. D.; Tuinstra, H. E.; Calabrese, J. C. Inorg. Chem. 1978, 17, 3045.
- Preparation and Reactions of Alkyl- and Arylpentacarbonyltungsten Anions, Casey, C. P.; Polichnowski, S. W. J. Am. Chem. Soc. 1978, 100, 7565.
- Mechanistic Studies Related to the Olefin Metathesis Reaction, Casey, C. P.; Scheck, D. M.; Schusterman, A. J. in Fundamental Research in Homogeneous Catalysis, M. Tsutsui, Ed., Vol. 3, P. 141, 1979.
- Rhenium Formyl and Carboxy Complexes Derived from the (C5H5)Re(CO)2(NO)+ Cation: Models for the Fischer Tropsch and Water Gas Shift Reactions, Casey, C. P.; Andrews, M. A.; Rinz, J. E. J. Am. Chem. Soc. 1979, 101, 741.
- Metal Carbenes in Organic Chemistry, Casey, C. P. Chemtech 1979, 378.
- Disproportionation of a Neutral Metal-Formyl Complex and Synthesis of a Stable Hydroxymethyl Metal Compound, Casey, C. P.; Andrews, M. A.; McAlister, D. R. J. Am. Chem. Soc. 1979, 101, 3372.
- Stereochemistry and Mechanism of the Reaction of LiCu(CH3)2 with gamma-Cyclopropyl-alpha,beta-Unsaturated Ketones, Casey, C. P.; Cesa, M. C. J. Am. Chem. Soc. 1979, 101, 4236.
- Mechanism of Rearrangement of Platinacyclobutanes, Casey, C. P.; Scheck, D. M.; Shusterman, A. J. J. Am. Chem. Soc. 1979, 101, 4233.
- Reactions of (CO)5WCHC6H5 with Alkenes, Casey, C. P.; Polichnowski, S. W.; Shusterman, A. J. Jones, C. R. J. Am. Chem. Soc. 1979, 101, 7282.
- Tungsten-Carbene-Alkene Complexes, Casey, C. P.; Shusterman, A. J. J. Mol. Catal. 1980, 8, 1.
- Reduction of Coordinated Carbon Monoxide: Synthesis of Neutral Metal Formyl and Hydroxymethyl Derivatives of the (C5H5)Re(CO)2(NO)+ Cation, Casey, C. P.; Andrews, M. A.; McAlister, D. R.; Rinz, J. E. J. Am. Chem. Soc. 1980, 102, 1927.
- Model Studies of Metal Catalyzed CO Reduction, Casey, C. P.; Neumann, S. M.; Andrews, M. A. McAlister, D. R. Pure Applied Chemistry 1980, 52, 625.
- Preferred Kinetic Migration of Methyl and Preferred Thermodynamic Migration of Phenyl in Conversion of cis-Acetylbenzoyltetracarbonylrhenate(I) to cis-Benzoylmethyltetracarbonylrhenate(I) and cis-Acetylphenyltetracarbonylrhenate(I), Casey, C. P.; Scheck, D. M. J. Am. Chem. Soc. 1980, 102, 2723.
- The Mechanism of Reductive Elimination of Acetophenone from N(CH3)4+ [cis-(CO)4Mn(COCH3)(COC6H5)]-, Casey, C. P.; Scheck, D. M. J. Am. Chem. Soc. 1980, 102, 2728.
- Metal Carbene Complexes, Casey, C. P., Chapter in Reactive Intermediates. Vol. II, M. Jones, Jr. and R. A. Moss, Editors, Wiley-Interscience, New York, NY, 1981.
- Conversion of an eta5-Cyclopentadienyl Metal Complex to an eta1-Cyclopentadienyl Metal Complex upon Addition of Trimethylphosphine, Casey, C. P.; Jones, W. D. J. Am. Chem. Soc. 1980, 102, 6154-6156.
- Metal Formyl and Hydroxymethyl Metal Compounds, Casey, C. P.; Andrews, M. A.; McAlister, D. R.; Jones, W. D.; Harsy, S. G. J. Mol. Catal., 1981, 13, 43-59.
- Intermediates in Associative Phosphine Substitution Reactions of (eta5-C5H5)W(CO)2(NO), Casey, C. P.; Jones, W. D.; Harsy, S. G. J. Organomet. Chem. 1981, 206, C38-C42.
- Comment on Proposed Reaction Mechanisms for Formation of Isotactic Polypropylene, Casey, C. P. Macromolecules 1981, 14, 464-465.
- Interconversion of gamma-Silyl-alpha, beta-Unsaturated Carbonyl Compounds and Siloxy Butadienes by 1,5 Shifts of Silicon Between Carbon and Oxygen, Casey, C. P.; Jones, C. R.; Takuda, H. J. Org. Chem. 1981, 46, 2089-2092.
- Fluxional Behavior of (CO)4Fe(mu-AsMe2)Mo(CO)2(C5H5), Casey, C. P.; Bullock, R. M. J. Organomet. Chem. 1981, 218, C47-C50.
- Search for Heterobimetallic Dihydrides from the Reaction of H2 with Metal-Metal Bonds, Casey, C. P.; Bullock, R. M. J. Mol. Catal. 1982, 14, 283.
- 13CO Exchange Reactions of Metal Carbene Complexes, Casey, C. P.; Cesa, M. C. Organometallics, 1982, 1, 87.
- Synthesis and X-Ray Structure of cis-Tetracarbonyl[(Z)-eta2-allylamino (p-tolyl)carbene]tungsten(0): A Stable Metal-Carbene-Alkene Complex, Casey, C. P.; Shusterman, A. J.; Vollendorf, N. W.; Haller, K. J. J. Am. Chem. Soc. 1982, 104, 2417.
- The Synthesis and Interconversions of Dinuclear Iron Complexes with mu-CH3, -CH2 and -CH Ligands, Casey, C. P.; Fagan, P. J.; Miles, W. M. J. Am. Chem. Soc. 1982, 104, 1134.
- Tetraethylammonium trans-Tricarbonyl(Formyl)[tris-(3,5-Dimethylphenyl)Phosphite]Ferrate(0), Casey, C. P.; McAlister, D. R.; Calabrese, J. C.; Neumann, S. M.; Andrews, M. A.; Meszaros, M. W.; Haller, K. J. Crystal Structure Communications, 1982, 11, 1015.
- Stereochemistry and Detailed Mechanism of the Conversion of 13C Labeled cis-Acetylbenzoyltetracarbonylrhenate(I) to cis-Acetylphenyltetracarbonylrhenate(I), Casey, C. P.; Baltusis, L. M. J. Am. Chem. Soc. 1982, 104, 6347-6353.
- Acetal and Ketal Derivatives Related to Metal Formyl and Metal Acyl Complexes, Casey, C. P.; Tukada, H. Organometallics, 1982, 1, 1083-1084.
- Synthesis of Electrophilic Dimethylcarbene Iron Complexes, Casey, C. P.; Miles, W. H.; Tukada, H.; O'Connor, J. M. J. Am. Chem. Soc. 1982, 104, 3761-3762.
- Hydrocarbation: The Addition of the C-H Bond of a Cationic Bridging Iron Methylidyne Complex to Alkenes, Casey, C. P.; Fagan, P. J. J. Am. Chem. Soc. 1982, 104, 4950-4951.
- Heterobimetallic Compounds Linked By Heterodifunctional Ligands: Synthesis and X-Ray Crystal Structure of (CO)4Mn-Mo(CO)3[eta5-C5H4P(C6H5)2], Casey, C. P.; Bullock, R. M.; Fultz, W. C.; Rheingold, A. L. Organometallics 1982, 1, 1591-1596.
- The Structure of Intermediates Formed in the Reaction of Osmium Tetroxide with 1,1-Diphenylethylene, Casey, C. P. J. Chem. Soc., Chem. Commun. 1983, 126-127.
- Formation of the Bridging Acylium Complex (C5H5)2Fe2(CO)2(mu-CO)(mu-CHCO)+PF6- by Addition of CO to a Bridging Methylidyne-Iron Complex, Casey, C. P.; Fagan, P. J.; Day, V. W. J. Am. Chem. Soc. 1982, 104, 7360-7361.
- Intermediates in the Associative Phosphine Substitution Reaction of (eta5-C5H5)Re(CO)3, Casey, C. P.; O'Connor, J. M.; Jones, W. D.; Haller, K. J. Organometallics 1983, 2, 535-538.
- Metal-Metal Bonded Zirconium-Ruthenium and Zirconium-Iron Complexes, Casey, C. P.; Jordan, R. F.; Rheingold, A. L. J. Am. Chem. Soc. 1983, 105, 665-667.
- Conversion of an eta5-C5H5 Complex into a Cyclopentadienylidene Ketene Complex, Casey, C. P.; O'Connor, J. M. J. Am. Chem. Soc. 1983, 105, 2919-2920.
- Protonation of Metal-Metal Bonds in Heterobimetallic Compounds Linked by a Heterodifunctional Ligand, Casey, C. P.; Bullock, R. M. J. Organomet. Chem. 1983, 251, 245-248.
- Synthesis and Reactions of a Cationic Bridging Methylidyne-Iron Complex, Casey, C. P.; Fagan, P. J.; Miles, W. M.; Marder, S. R. in Organometallic Compounds-Synthesis, Structure, and Theory, B. L. Shapiro, Ed. pp. 87-114, Texas A and M University Press, College Station, Texas 1983.
- Reactions of Cationic Bridging Methylidyne-Iron Complex with Carbon Monoxide and with Alkenes, Casey, C. P.; Fagan, P. J.; Miles, W. H.; Marder, S. R. J. Mol. Catal. 1983, 21, 173-188.
- The Preparation of alpha-Methoxyalkyliron Complexes: Precursors of Secondary Carbeneiron Complexes, Casey, C. P.; Miles, W. H. J. Organomet. Chem. 1983, 254, 333-337.
- Novel Chain Mechanism for the Formylmetal to Hydridometal Conversion. Free Radical, Photochemical, and Electrochemical Methods of Initiation, Narayanan, B. A.; Amatore, C.; Casey, C. P.; Kochi, J. K. J. Am. Chem. Soc. 1983, 105, 6351-6352.
- Rearrangement of Bridging Alkylidyne Iron Complexes to Bridging Alkenyl Iron Complexes, Casey, C. P.; Marder, S. R.; Fagan, P. J. J. Am. Chem. Soc. 1983, 105, 7197-7198.
- Metal Carbene Complexes, Casey, C. P., Chapter in Reactive Intermediates. Vol III, M. Jones, Jr. and R. A. Moss, Editors, Wiley-Interscience, New York, NY, 1985.
- Synthesis of a Chelated Tungsten-Carbene-Alkene Complex and its Conversion to a Cyclopropane, Casey, C. P.; Vollendorf, N. W.; Haller, K. J. J. Am. Chem. Soc. 1984, 106, 3754-3764.
- Synthesis and X-Ray Crystal Structures of an Analogous Pair of Iron Formyl and Iron Acetyl Complexes, Casey, C. P.; Meszaros, M. W.; Neumann, S. M.; Gennick Cesa, I.; Haller, K. J. Organometallics 1985, 4, 143-149.
- (C5H5)2Zr[Ru(CO)2C5H5]2 A Metal-Metal Bonded Zirconium-Diruthenium Complex, Casey, C. P.; Jordan, R. F.; Rheingold, A. L. Organometallics, 1984, 3, 504-506.
- Synthesis of Molybdenum-Rhodium and Molybdenum-Iridium Compounds Linked by a Heterodifunctional Ligand and Formation of Molybdenum-Iridium Dihydrides by Reaction with Molecular Hydrogen, Casey, C. P.; Bullock, R. M.; Nief, F. J. Am. Chem. Soc. 1983, 105, 7574-7580.
- Photochemical Hydrogenolysis of the Phosphorus-Cyclopentadienyl Bond of (CO)4MnMo(CO)3[eta5-C5H4P(C6H4-p-CH3)2] and Formation of the Phosphido-Bridged Metal Hydride Complex (CO)4Mn[mu-P(C6H4-p-CH3)2](mu-H)Mo(CO)2(C5H5), Casey, C. P.; Bullock, R. M. Organometallics 1984, 3, 1100-1104.
- Synthesis and Characterization of (C5H5)(CO)2Fe=CH-CH=C(CH3)2+ and its Reaction with Alkenes to Give Vinyl Cyclopropanes, Casey, C. P.; Miles, W. H. Organometallics 1984, 3, 808-809.
- Mechanism of Carbon-Carbon Bond Formation in the Reaction of 1,2-Disubstituted Alkenes with a Cationic Bridging Methylidyne Iron Complex, Casey, C. P.; Meszaros, M. W.; Marder, S. R.; Fagan, P. J. J. Am. Chem. Soc. 1984, 106, 3680-3681.
- Reactions of a Cationic Bridging Methylidyne Iron Complex with Carbon Monoxide and with Alkenes, Casey, C. P.; Fagan, P. J.; Miles, W. H.; Marder, S. R.; Meszaros, M. W. PREPRINTS, Div. of Petrol. Chem., ACS 1984, 29, 577-588.
- eta5 to eta1 Conversions of Idenyltricarbonylrhenium, Casey, C. P.; O'Connor, J. M. Organometallics 1985, 4, 384-388.
- Early-Late Transition Metal Heterobimetallic Compounds Linked by a Heterodifunctional (Diphenylphosphino)Cyclopentadienyl Bridging Ligand, Casey, C. P.; Nief, F. Organometallics 1985, 4, 1218-1220.
- Photochemical Reaction of mu-Ethenylidene Complex [(C5H5)(CO)Fe]2(mu-CO)(mu-C=CH2) with Acetylenes, Casey, C. P.; Miles, W. H.; Fagan, P. J.; Haller, K. J. Organometallics 1985, 4, 559-563.
- Synthesis of [(C5H5)(CO)2Fe2(mu-CO)]2(mu-C3H3)]+ PF6- by Reaction of a Diiron Bridging Methylidyne Complex with a Diiron Bridging Ethenylidene Complex, Casey, C. P.; Marder, S. R.; Rheingold, A. L. Organometallics, 1985, 4, 762-766.
- Interconversions of eta5-C5H5, eta1-C5H5, and Ionic "eta0"-C5H5 Rhenium Compounds - Crystal Structure of [Re(NO)(CH3)(PMe3)4]+[C5H5]-, Casey, C. P.; O'Connor, J. M.; Haller, K. J. J. Am. Chem. Soc. 1985, 107, 1241-1246.
- Synthesis, Characterization and Reactions of (C5H5)(CO)2Fe=C(CH3)2+ and (C5H5)(CO)2Fe=CHCH=C(CH3)2+, Casey, C. P.; Miles, W. H.; Tukada, H. J. Am. Chem. Soc. 1985, 107, 2924-2931.
- The Synthesis and Reactions of a Cyclopentadienylidene Ketene Complex, Casey, C. P.; O'Connor, J. M.; Haller, K. J. J. Am. Chem. Soc. 1985, 107, 3172-3177.
- Synthesis and Reactions of Bridging Vinyl Carbyne Diiron Complexes, Casey, C. P.; Marder, S. R. Organometallics 1985, 4, 411-412.
- Generation and Spectroscopic Observation of a Tungsten-Carbene-Alkene Intermediate in Cyclopropane Formation, Casey, C. P.; Shusterman, A. J. Organometallics 1985, 4, 736-744.
- Ligand Induced Reactions of a Directly Bonded Early-Late Transition Metal Complex Involving Reversible Cleavage of a Zr-Ru Bond with Expulsion of a Ruthenium Hydride, Casey, C. P.; Palermo, R. E.; Jordan, R. F.; Rheingold, A. L. J. Am. Chem. Soc. 1985, 107, 4597-4599.
- Condensation of Aldehydes with mu-Alkylidyne Diiron Complexes - A New Synthesis of mu-Vinylcarbyne Complexes, Casey, C. P.; Konings, M. S.; Palermo, R. E.; Colborn, R. E. J. Am. Chem. Soc. 1985, 107, 5296-5297.
- Synthesis and Reactivity of Hydrocarbon Bridged Dinuclear Complexes, Casey, C. P.; Audett, J. D. Chem. Rev., 1986, 86, 339-352.
- Interconversion of mu-Alkylidyne and mu-Alkenyl Diiron Complexes, Casey, C. P.; Marder, S. R.; Adams, B. R. J. Am. Chem. Soc. 1985, 107, 7700-7705.
- Formation of a Bridging Methylidyne Complex and of a Bridging Vinyl Complex from the Reaction of [(C5H5)Fe(NO)]2(mu-CH2) with Trityl Cation, Casey, C. P.; Roddick, D. M. Organometallics 1986, 5, 436-438.
- Conversion of Diiron Bridging Alkenyl Complexes to Monoiron Alkenyl Compounds and to Alkenes, Casey, C. P.; Marder, S. R.; Colborn, R. E.; Goodson, P. A. Organometallics 1986, 5, 199-203.
- Reaction of a mu-Ethenylidene Diiron Complex with Ethyl Diazoacetate, Casey, C. P.; Austin, E. A. Organometallics, 1986, 5, 584-585.
- Reactions of a Cationic Bridging Methylidyne Complex with Activated Alkenes, Casey, C. P.; Ghodes, M. A.; Meszaros, M. W. Organometallics 1986, 5, 199-203.
- Regioselective Anion Generation and Alkylation at Carbon a to Nitrogen in (CO)5W=C[N(CH3)2]C6H4-p-CH3, Casey, C. P.; Hornung, N. L.; Vollendorf, N. W. J. Organomet. Chem. 1986, 303, 375-385.
- Zirconoxycarbene Complexes of Ruthenium -- Reduction of Coordinated CO in the Reaction of a Zr-Ru Compound with H2, Casey, C. P.; Palermo, R. E.; Rheingold, A. L. J. Am. Chem. Soc. 1986, 108, 549-550.
- Symposium on Industrial Applications of Organometallic Chemistry and Catalysis, Casey, C. P. J. Chem. Ed. 1986, 63, 188.
- Synthesis of a Vinylcarbynetetrairon Complex. Crystal and Molecular Structure of [(C5H5)2(CO)2Fe2(mu-CO)]2(mu-C5H3)+BF4-, Casey, C. P.; Konings, M. S.; Haller, K. J. J. Organomet. Chem. 1986, 301, C55-C58.
- Hydrocarbation - Formation of Diiron mu-Alkylidyne Complexes from the Addition of the Carbon-Hydrogen Bond of a mu-Methylidyne Complex Across Alkenes, Casey, C. P.; Meszaros, M. W.; Fagan, P. J.; Bly, R. K.; Marder, S. R.; Austin, E. A. J. Am. Chem. Soc. 1986, 108, 4043-4053.
- Formation of Diiron mu-Alkenyl Complexes from the Reaction of a mu-Methylidyne Complex with Selected Alkenes, Casey, C. P.; Meszaros, M. W.; Fagan, P. J.; Bly, R. K.; Colborn, R. E. J. Am. Chem. Soc. 1986, 108, 4053-4059.
- Reaction of a Diiron mu-Methylidyne Complex with 1,2-Disubstituted Alkenes, Casey, C. P.; Meszaros, M. W.; Marder, S. R.; Bly, R. K.; Fagan, P. J. Organometallics 1986, 5, 1873-1879.
- Steric and Electronic Factors Influencing the Amounts of mu-Alkylidyne and mu-Alkenyl ProductsObtained from Reaction of Diiron Methylidyne Complexes with Alkenes, Casey, C. P.; Meszaros, M. W.; Colborn, R. E.; Roddick, D. M.; Miles, W. H.; Gohdes, M. A. Organometallics 1986, 5, 1886-1890.
- Reactions of Acetylenes with the Cationic Bridging Methylidyne Complex [(C5H5)(CO)Fe]2(mu-CO)(mu-CH)+, Casey, C. P.; Woo, L. K.; Fagan, P. J.; Palermo, R. E.; Adams, B. R. Organometallics 1987, 6, 447-454.
- Conversion of mu-Alkylidyne Diiron Complexes to Nitriles, Casey, C. P.; Woo, L. K. J. Organomet. Chem. 1987, 328, 161-168.
- New Carbon-Carbon Bond-Forming Reactions of Diiron Complexes, Casey, C. P. Chemica Scripta 1987, 27, 501-503.
- Ring Slippage Chemistry of Transition Metal Cyclopentadienyl and Indenyl Complexes, Casey, C. P.; O'Connor, J. M. Chem. Rev. 1987, 87, 307-318.
- Heterobimetallic Compounds Linked by Heterodifunctional Ligands, Casey, C. P.; Bullock, R. M. Acc. Chem. Res. 1987, 20, 167-173.
- Intramolecular Cyclopropanation and Olefin Metathesis Reactions of (CO)5W=C(OCH2CH2CH=CHOCH3)C6H4-p-CH3, Casey, C. P.; Hornung, N. L.; Kosar, W. P. J. Am. Chem. Soc. 1987, 109, 4908-4916.
- Reaction of Diiron mu-Alkylidyne Complexes with Diazo Compounds, Casey, C. P.; Austin, E. A.; Rheingold, A. L. Organometallics 1987, 6, 2157-2164.
- Diiron mu-Vinylcarbyne Complexes Have Unusually Low Barriers to Vinyl Rotation Because Conjugation is Maintained Throughout Rotation, Casey, C. P.; Konings, M. S.; Marder, S. R.; Takezawa, Y. J. Organomet. Chem. 1988, 358, 347-361.
- Synthesis of a Heterobimetallic Dihydride by the Addition of a Rhenium Dihydride to a Platinum(0) Complex, Casey, C. P.; Rutter, Jr., E. W.; Haller, K. J. J. Am. Chem. Soc. 1987, 109, 6886-6887.
- Reactions of Heteroatom and Carbon Nucleophiles with the Cationic Bridging Methylidyne Complex {[(C5H5)(CO)Fe]2(mu-CO)(mu-CH)}+ PF6-, Casey, C. P.; Crocker, M.; Vosejpka, P. C.; Fagan, P. J.; Marder, S. R.; Gohdes, M. A. Organometallics, 1988, 7, 670-675.
- Synthesis of Cationic Diiron mu-Vinylcarbyne Complexes, Casey, C. P.; Konings, M. S.; Marder, S. R. Polyhedron 1988, 7, 881-901.
- Addition of Nucleophiles to Cationic Diiron mu-Vinylcarbyne Complexes - Synthesis of Functionalized Diiron mu-Alkenylidene Complexes, Casey, C. P.; Konings, M. S.; Marder, S. R. J. Organomet. Chem. 1988, 345, 125-134.
- Formation of Bridging Acylium and Nitrilium Complexes by Reaction of CO and CNC(CH3)3 with a Bridging Diiron Methylidyne Complex - Evidence for Strong Electron Donation from the Fe2C Core onto the mu-CHC�O and mu-CHC�NR Ligands, Casey, C. P.; Crocker, M.; Niccolai, G. P.; Fagan, P. J.; Konings, M. S. J. Am. Chem. Soc. 1988, 110, 6070-6076.
- Reactions of Organocopper Reagents with the Cationic Bridging Acylium Complex [C5H5(CO)Fe]2(mu-CO)(mu-CHCO)+, Casey, C. P.; Crocker, M.; Vosejpka, P. C.; Rheingold, A. L. Organometallics 1989, 8, 278-282.
- Addition of Carbon Nucleophiles to (mu-Alkenyl)diiron Complexes, Casey, C. P.; Vosejpka, P. C., Organometallics 1988, 7, 934-936.
- Synthesis of an Unstable Vinyl Substituted Diiron-mu-Alkenyl Complex. Iron-Iron Bond Cleavage and Rearrangement to an Iron-Substituted Butadiene-Iron Complex, Casey, C. P.; Konings, M. S.; Gohdes, M. A.; Meszaros, M. W. Organometallics 1988, 7, 2103-2107.
- Photochemical Reactions of Diiron mu-Alkenylidene Complexes with Hydrogen, Trialkylsilanes, and Diazo Compounds: Cleavage to Alkenes, Vinylsilanes and Allenes, Casey, C. P.; Austin, E. A. J. Am. Chem. Soc. 1988, 110, 7106-7113.
- Cyclopropane Formation from the Reaction of (gamma-Haloalkyl)iron Compounds with Silver(1+), Casey, C. P.; Smith, L. J. Organometallics 1988, 7, 2419-2421.
- A New Synthesis of Rhenium-Carbene Complexes from the Reaction of Cp(CO)2ReH- with Cp2Zr(eta2-COR)Cl, Casey, C. P.; Nagashima, H. J. Am. Chem. Soc. 1989, 111, 2352-2353.
- Inversion of Stereochemistry at the Carbon Bound to Iron in Cyclopropane Formation from threo-C5H5(CO)2FeCHDCHDCH2S(CH3)C6H5+, Casey, C. P.; Smith, L. J. Organometallics, 1989, 8, 2288-2290.
- Synthesis of Rhodium Containing Heterobimetallic Hydride Complexes, Casey, C. P.; Whiteker, G. T. Inorg. Chem. 1990, 29, 876-879.
- Acid Catalyzed trans to cis Isomerization of [C5H5(CO)Fe]2(mu-CO)(mu-CH2), Casey, C. P.; Gable, K. P.; Roddick, D. M. Organometallics 1990, 9, 221-226.
- Hydrogen Transfer from CpRe(CO)2H2 to trans-Ir(CO)(Cl)(PPh3)2 via a Heterobimetallic Re-Ir Intermediate, Casey, C. P.; Rutter, Jr., E. W. Inorg. Chem. 1990, 29, 2333-2335.
- Reactions of Nucleophiles with Cationic Bridging Alkylidyne Complexes, Casey, C. P.; Vosejpka, P. C.; Crocker, M. J. Organomet. Chem., 1990, 394, 339-347.
- Synthesis of endo, endo-2,5-Bis(diphenylphosphinomethyl)bicyclo[2.2.1]heptane, a Chelating Diphosphine with a Natural Bite Angle of 120�, Casey, C. P.; Whiteker, G. T. J. Org. Chem. 1990, 55, 1394-1396.
- Synthesis of Rhenium-Alkene Complexes from the Reaction of the Heterobimetallic Dihydride C5H5(CO)2HRe-PtH(PPh3)2 with Alkynes, Casey, C. P.; Rutter, Jr., E. W. J. Am. Chem. Soc. 1989, 111, 8917-8919.
- The Natural Bite Angle of Chelating Diphosphines, Casey, C. P.; Whiteker, G. T. Israel J. Chem., 1990, 30, 299-304.
- Pentacoordinate Fe(CO)3 Complexes of Diphosphine Ligands with Bite Angles Greater than 120�, Casey, C. P.; Whiteker, G. T.; Campana, C. F.; Powell, D. R. Inorg. Chem., 1990, 29, 3376-3381.
- A New Route to Early-Late Heterobimetallic mu-Alkylidene Complexes, Casey, C. P.; Askham, F. R.; Petrovich, L. M. J. Organomet. Chem. 1990, 387, C31-C35.
- Amphiphilic Carbene Complexes - Both Electrophiles and Nucleophiles Attack the Carbene Carbon of C5H5(CO)2Re=CHR, Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc., 1990, 112, 3713-3715.
- Rearrangement of an Allyl Vinyl Rhenium Complex to a Rhenium Allyl Vinyl Ketone Complex Via Two Consecutive Concerted Organometallic Rearrangements, Casey, C. P.; Vosejpka, P. C.; Gavney, Jr. J. A. J. Am. Chem. Soc. 1990, 112, 4083-4085.
- Synthesis of Cationic pi-Allyl Rhenium Complexes and Their Reactions with Carbon Nucleophiles, Casey, C. P.; Yi, C. S. Organometallics, 1990, 9, 2413-2414.
- Stereochemistry and Mechanism of Cyclopropane Formation From Ionization of C5H5(CO)2Fe(CH2)3X, Casey, C. P.; Smith, L. J. Organometallics 1992, 11, 738-744.
- New Reactions of Organorhenium Compounds, Casey, C. P.; Rutter, E. W., Jr.; Hazin, P. N.; Wang, Y.; Yi, C. S.; Nagashima, H.; Petrovich, L. M.; Askham, F. R.; Vosejpka, P. C.; Sakaba, H.; Underiner, T. L. in "Organic Synthesis Via Organometallics" Ed. Hoffmann, R. W.; Dštz, K. H., Vieweg & Verlag, 1991, 186-205.
- Synthesis and Reactions of Directly Bonded Zirconium-Ruthenium Heterobimetallic Complexes, Casey, C. P. J. Organometal. Chem. 1990, 400, 205-221.
- Acid Catalyzed Isomerization and Deuterium Exchange of Rhenium Alkene Complexes via In-Place Rotation of an Agostic Alkyl Rhenium Cation, Casey, C. P.; Yi, C. S. Organometallics 1991, 10, 33-35.
- Diphosphines with Natural Bite Angles Near 120� Increase Selectivity for n-Aldehyde Formation in Rhodium-Catalyzed Hydroformylation, Casey, C. P.; Whiteker, G. T.; Melville, M. G.; Petrovich, L. M.; Gavney, J. A., Jr. ; Powell, D. R. J. Am. Chem. Soc. 1992, 114, 5535-5543.
- Book Review: Organometallics: A Concise Introduction by Elschenbroich, C; Salzer, A. VCH Publishers, New York. 1989, xi + 479 pp.; Casey, C. P. J. Am. Chem. Soc. 1991, 113, 6709.
- Reduction and Chain Extension of the Carbene Ligand of Rhenium Carbene Complexes. Casey, C. P.; Sakaba, H.; Underiner, T. L. J. Am. Chem. Soc. 1991, 113, 6673-6674.
- Synthesis and Reactions of Cp*(CO)2Re=Re(CO)2Cp*. Casey, C. P.; Sakaba, H.; Hazin, P. N.; Powell, D. R. J. Am. Chem. Soc. 1991, 113, 8165-8166.
- Phosphine Induced Cyclopentadienyl Ring Slippage Catalyzes CO Insertion into a Methyl Compound to Produce an Acetyl Rhenium Compound, Casey, C. P.; Widenhoefer, R. A.; O'Connor, J. M. J. Organomet. Chem. 1992, 428, 99-105.
- Attempted Generation of Cp(CO)2Re(mu-H)Pt(PPh3)2[C(CH3)=CHCH3] From Reaction of Cp(CO)2ReH- with (PPh3)3Pt[(E)-C(CH3)=CHCH3]+ Produces Cp(CO)2Re(cis-CH3CH=CHCH3), Casey, C. P.; Wang, Y. Organometallics 1992, 11, 13-14.
- The Electronic Structure of [(eta5-C5H5)2Co2]: A Comment on the Existence of a Complex with an Unsupported Co-Co Double Bond, Abrahamson, H. B.; Niccolai, G. P.; Heinekey, D. M.; Casey, C. P.; Bursten, B. E. Angew. Chem. Int. Ed. Engl. 1992, 31, 471-472.
- Metal Insertion into a CH Bond as a Route to the Heterobimetallic mu-Methylidene Complex C5H5(CO)2Re(mu-CH2)Pt(PPh3)2, Casey, C. P.; Wang, Y.; Petrovich, L. M.; Underiner, T. L.; Hazin, P. N.; Desper, J. M. Inorg. Chim. Acta 1992, 198-200, 557-564.
- Nucleophilic Attack at the Central Carbon of a Cationic (eta3-Propargyl)rhenium Complex, Casey, C. P.; Yi, C. S. J. Am. Chem. Soc. 1992, 114, 6597-6598.
- Reaction of C5Me5(CO)2Re(HC�CCH3) with Ph3C+PF6- Produces the eta3-Allyl Complex C5Me5(CO)2Re[eta3-Ph2CC(Ph)CHCH3]+PF6-, Casey, C. P.; Yi, C. S.; Gavney, J. A., Jr. J. Organomet. Chem. 1993, 443, 111-114.
- "[Cp*Co=CoCp*]" is a Hydride, Kersten, J. L.; Rheingold, A. L.; Theopold, K. H.; Casey, C. P.; Widenhoefer, R. A.; Hop, C. E. C. A. Angew. Chem. Intl. Ed. Engl. 1992, 31, 1341-1343.
- Rearrangement of a Propargyl Vinyl Rhenium Complex to a Rhenium Allenyl Vinyl Ketone Complex, Casey, C. P.; Underiner, T. L.; Vosejpka, P. C.; Gavney, J. A., Jr.; Kiprof, P. J. Am. Chem. Soc. 1992, 114, 10826-10834.
- Kinetic Generation of cis-C5H5(CO)2ReH2 from Reaction of C5H5(CO)2Re(mu-H)Pt(H)(PPh3)2 with Diphenylacetylene, Casey, C. P.; Tanke, R. S.; Hazin, P. N.; Kemnitz, C. R.; McMahon, R. J. Inorg. Chem. 1992, 31, 5474-5479.
- Mechanism of Rearrangement of An Allyl Vinyl Rhenium Complex to a Allyl Vinyl Ketone Rhenium Complex: The Role of Concerted Organometallic Reactions in Avoiding High Energy Coordinatively Unsaturated Intermediates, Casey, C. P.; Vosejpka, P. C.; Underiner, T. L.; Slough, G. A.; Gavney, J. A., Jr. J. Am. Chem. Soc. 1993, 115, 6680-6688.
- Organorhenium Chemistry, Casey, C. P. Science 1993, 259, 1552-1558.
- Reaction of NO with Cp*3Co3(mu-H)4 Preserves the Tricobalt Cluster and Produces Cp*3Co3(mu3-NO)2, Casey, C. P.; Widenhoefer, R. A.; Hayashi, R. K. Inorg. Chim. Acta. 1993, 212, 81-85.
- Mechanism of Alkyne Reduction by the Heterobimetallic Dihydride Cp(CO)2Re(mu-H)Pt(H)(PPh3)2, Casey, C. P.; Wang, Y.; Tanke, R. S.; Hazin, P. N.; Rutter, E. W. New J. Chem. 1994, 18, 43-50.
- Reaction of CO and tert-Butyl Isocyanide with the Cluster Cp*3Co3(mu2-H)3(mu3-H); Facile Hydrogen Transfer to Isocyanide forms Cp*3Co3(mu2-H)(mu3-eta2-HC=NCMe3), Casey, C. P.; Widenhoefer, R. A.; Hallenbeck, S. L.; Gavney, J. A., Jr. J. Chem. Soc., Chem. Commun. 1993, 1692-1694.
- Conversion of Acetylene to a Triple Bridged Ethylidyne Ligand on the Cluster Cp*3Co3(mu2-H)3(mu3-H), Casey, C. P.; Widenhoefer, R. A.; Hallenbeck, S. L. Organometallics 1993, 12, 3788-3789.
- Synthesis and Reactions of Rhenium Enyne, and Vinylvinylidene Complexes, Casey, C. P.; Ha, Y.; Powell, D. R. J. Organomet. Chem. 1994, 472, 185-193.
- An Analysis of the Metal-Metal Bonding in Organodirhenium Complexes with Re-Re Double Bonds, Casey, C. P.; Niccolai, G. P.; Barckholtz, T. A.; Bursten, B. E. J. Organomet. Chem. 1994, 478, 153-160.
- X-ray Crystal Structures of Two Ethylidyne Tricobalt Clusters: Thermolysis of Cp*Co(H2C=CH2)2 Produces Cp*3Co3(mu3-CCH3)(mu3-H) not Cp*3Co3(mu3-CCH3)2, Casey, C. P.; Widenhoefer, R. A.; Hallenbeck, S. L.; Hayashi, R. K.; Powell, D. R.; Smith, G. W. Organometallics, 1994, 13, 1521-1524.
- Synthesis and Reactions of Dirhenium Alkenylidene and Alkylidyne Complexes, Casey, C. P.; Ha, Y.; Powell, D. R. J. Am. Chem. Soc., 1994, 116, 3424-3428.
- Synthesis and X-Ray Crystal Structures of the Tricobalt Mono(ethylidyne) Clusters Cp*3Co3(mu3-CCH3)(mu3-CO)(mu2-H), Cp*3Co3(mu3-CCH3)(mu3-CNCMe3)(mu2-H), and Cp*3Co3(mu3-CCH3)(mu3-NO), Casey, C. P.; Widenhoefer, R. A.; Hallenbeck, S. L.; Hayashi, R. K. Inorg. Chem., 1994, 33, 2639-2644.
- The Photochemical Dehydrogenation of [C5H5(CO)Fe]2(mu-CO)(mu-CHCH2CH2CH2CH3) to [C5H5(CO)Fe](mu-CO)(mu-eta1,eta3-CHCH=CHCH2CH3)[FeC5H5], Casey, C. P. and Niccolai, G. P. Organometallics, 1994, 13, 2527-2531.
- Syntheses, X-ray Crystal Structures, and Fluxional Behavior of the Clusters Cp*3Co3(mu2-CO)(mu3-CO)(mu-H)2, Cp*3Co3(mu-H)(mu3-eta2-HC=NCMe3), and Cp*3Co3(mu-H)(mu3-eta2-HC=NCMe2CH2Me), Casey, C. P.; Widenhoefer, R. A.; Hallenbeck, S. L.; Hayashi, R. K. ; Gavney, J. A., Jr. Organometallics, 1994, 13, 4720-4731.
- The Reaction of Cp*3Co3(mu3-H)(mu2-H)3 with Carbon Dioxide, Carbon Disulfide, and Phenyl Isocyanate, Casey, C. P.; Widenhoefer, R. A.; Hayashi, R. K. Inorg. Chem., 1995, 34, 1138-1144.
- Chelating Diphosphine Rhodium Catalyzed Deuterioformylation of 1-Hexene : Control of Regiochemistry by the Kinetic Ratio of Alkyl Rhodium Species Formed by Hydride Addition to Complexed Alkene, Casey, C. P.; Petrovich, L. M. J. Am. Chem. Soc., 1995, 117, 6007-6014.
- On the Structure of M(allyl)4 (M = Mo, W, Zr), Landis, C.; Cleveland, T.; Casey, C. P. Inorg. Chem., 1995, 34, 1285-1287.
- The Reaction of Cp*3Co3(mu3-CCH3)(mu3-H) with (Trimethylsilyl)diazomethane and Ethyl Diazoacetate: Facile Hydrogen Transfer Forms the Diazenide Clusters Cp*3Co3(mu3-CCH3)(mu3-eta1-NNCH2SiMe3) and Cp*3Co3(mu3-CCH3)(mu3-eta1-NNCH2CO2CH2CH3) Casey, C. P.; Widenhoefer, R. A.; Hayashi, R. K. Inorg. Chem., 1995, 34, 2258-2262.
- Kinetics and Mechanism of the Formation of the Bis(ethylidyne) Tricobalt Cluster Cp*3Co3(mu3-CCH3)2 from Reaction of Acetylene with Cp*3Co3(mu2-H)3(mu3-H) Casey, C. P.; Hallenbeck, S. L.; Widenhoefer, R. A. J. Am. Chem. Soc., 1995, 117, 4607-4622.
- Equilibrium Between a Hydroxycarbene Complex and a Metal Acyl Hydride Complex Casey, C. P.; Czerwinski, C. J.; Hayashi, R. K. J. Am. Chem. Soc., 1995, 117, 4189-4190.
- The Reaction of Cp*(CO)2Re=Re(CO)2Cp* with Dimethyl Acetylenedicarboxylate Produces a 3,4-Dimetallacyclobutene Which Undergoes Photochemical Isomerization to a 2,4-Dimetalla(1.1.0)bicyclobutane Casey, C. P; Carino, R. S.; Hayashi, R. K.; Schladetzky, K. D. J. Am. Chem. Soc., 1996, 118, 1617-1623.
- Synthesis and Spectroscopic Characterization of the d0 Transition Metal-Alkyl-Alkene Complex Cp*2YCH2CH2C(CH3)2CH=CH2 Casey, C. P.*; Hallenbeck, S. L.*; Pollock, D. W.; Landis, C. R. J. Am. Chem. Soc., 1995, 117, 9770-9771.
- Comprehensive Organometallic Chemistry II: a Review of the Literature 1982-1994; Volume 6 Manganese Group Casey, C. P., Volume Editor; Abel, E. W.; Stone, G. G. A.; Wilkinson, G. Editors-in-Chief; Pergamon, 1995.
- Ligand Additions to Cp*(CO)2Re=Re(CO)2Cp* and Fragmentation and Rearrangement Reactions of Cp*(CO)2Re(mu-CO)Re(CO)(L)Cp* Casey, C.P.; Carino, R. S.; Sakaba, H.; Hayashi, R. K. Organometallics, 1996, 15, 2640-2649.
- Photochemical Rearrangement of a Rhenium Dimetallacyclobutene Studied by Time Resolved Infrared Spectroscopy Casey, C.P.; Boese, W. T.; Carino, R. S.; Ford, P. C. Organometallics, 1996, 15, 2189-2191.
- Synthesis of Eta3-Propargyl Rhenium Complexes, Casey, C. P.; Selmeczy, A. D.; Nash, J. R.; Yi, C. S.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc., 1996, 118, 6698-6706.
- Formation of a Dirhenium Carbene Complex from Reaction of (Eta5-C5H4Li)Re(CO)3 with Eta5-C5H5Re(CO)3, Casey, C. P.; Czerwinski, C. J.; Hayashi, R. K. Organometallics, 1996, 15, 4362
- Reaction of Cp*(CO)2Re:Re(CO)2Cp* with Alkynes Producing Dimetallacyclopentenones Cp*(CO)2Re(m-h1,h3-CR:CR'CO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes. Casey, C. P.; Carino, R. S.; Sakaba, H. Organometallics, 1997, 16, 419
- Ring Strain Perturbation of the Equilibria between Hydroxycarbene Complexes and Metal Acyl Hydride Complexes. Casey, C. P.; Czerwinski, C. J.; Fusie, K. A.; Hayashi, R. K. J. Am. Chem. Soc., 1997, 119, 3971
- Cis Addition of Hydrogen Chloride to an Amphiphilic Carbene Complex. Casey, C. P.; Czerwinski, C. J.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc., 1997, 119, 5750
- Rearrangement of Rhenium Allyl Vinyl Ketone Complexes. Casey, C. P.; Underiner, T. L.; Vosejpka, P. C.; Slough, G. A.; Gavney, J. A., Jr.; Hayashi, R. K. Organometallics, 1997, 16, 2189
- Formation and Spectroscopic Characterization of Chelated d0 Yttrium(III)-Alkyl-Alkene Complexes. Casey, C. P.; Hallenbeck, S. L.; Wright, J. M.; Landis, C. R. J. Am. Chem. Soc., 1997, 119, 9680
- Formation of platinum allyl and propargyl complexes from protonation of platinum enyne and diyne complexes. Casey, C. P.; Chung, S.; Ha, Y.; Powell, D. R. Inorg. Chim. Acta, 1997, 265, 127
- Electron Withdrawing Substituents on Equatorial and Apical Phosphines Have Opposite Effects on the Regioselectivity of Rhodium Catalyzed Hydroformylation. Casey, C. P.; Paulsen, E. L.; Beuttenmueller, E. W.; Proft, B. R.; Petrovich, L. M.; Matter, B. A.; Powell, D. R. J. Am. Chem. Soc., 1997, 119, 11817
- Alkene Dissociation from a d0 Yttrocene-Alkyl-Alkene Complex Generates a Pyramidal Alkyl Yttrium Complex That Inverts Slowly. Casey, C. P.; Fagan, M. A.; Hallenbeck, S. L. Organometallics, 1998, 17, 287
- Kinetic Addition of Nucleophiles to h3-Propargyl Rhenium Complexes Occurs at the Central Carbon to Produce Rhenacyclobutenes. Casey, C. P.; Nash, J. R.; Yi, C. S.; Selmeczy, A. D.; Chung, S.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc., 1998, 120, 722
- Database of Palladium Chemistry: Reactions, Catalytic Cycles and Chemical Parameters on CD-ROM Version 1.0.Academic Press: Kent. 1997. Casey, C. P.; Brady, J. T. J. Am. Chem. Soc., 1998, 120, 1347
- Coordination of a disubstituted alkene in a chelated d0-metal-alkyl-alkene complex. Evidence for equilibrium between complexes with coordinated and free alkenes. Casey, C. P.; Fisher, J. J. Inorg. Chim. Acta, 1998, 270, 5
- Reaction of Cp*(CO)2Re:Re(CO)2Cp* in THF with diethyl fumarate produces Cp*Re(CO)3 and Cp*Re(CO)(h2-(E)-EtO2CCH:CHCO2Et)(THF). Casey, C. P.; Carino, R. S.; Brady, J. T.; Hayashi, R. K. J. Organometallic Chem., 1998, 569, 55
- Acid-Catalyzed Isomerization of Rhenium Alkyne Complexes to Rhenium Allene Complexes via 1-Metallacyclopropene Intermediates. Casey, C. P.; Brady, J. T. Organometallics, 1998, 17, 4620
- Chelated alkyl halide manganese complexes (h5:h1-C5H4CH2CH2X)Mn(CO)2 from photolysis of (h5-C5H4CH2CH2X)Mn(CO)3. Casey, C. P.; Czerwinski, C. J.; Fraley, M. E. Inorg. Chim. Acta, 1998, 280, 316
- Protonation of Rhenium Alkyne Complexes Produces h3-Allyl Rhenium Complexes via Observable 1-Metallacyclopropene Intermediates. Casey, C. P.; Brady, J. T.; Boller, T. M.; Weinhold, F.; Hayashi, R. K. J. Am. Chem. Soc., 1998, 120, 12500
- Electronically Dissymmetric DIPHOS Derivatives Give Higher n:i Regioselectivity in Rhodium-Catalyzed Hydroformylation Than Either of Their Symmetric Counterparts. Casey, C. P.; Paulsen, E. L.; Beuttenmueller, E. W.; Proft, B. R.; Matter, B. A.; Powell, D. R. J. Am. Chem. Soc., 1999, 121, 63
- Observation of Zwitterionic d0 Zirconium-Alkyl-Alkene Chelates: Models for Intermediates in Metallocene-Catalyzed Alkene Polymerizations. Casey, C. P.; Carpenetti, D. W., II; Sakurai, H. J. Am. Chem. Soc., 1999, 121, 9483
- Dimerization of Rhenium Alkynyl Carbene Complexes by a Process Involving Two [1,1.5] Rhenium Shifts and Coupling of the Remote Alkynyl Carbons. Casey, C. P.; Kraft, S.; Powell, D. R. J. Am. Chem. Soc., 2000, 122, 3771
- Kinetics and Thermodynamics of Alkene Complexation in d0 Metal-Alkyl-Alkene Complexes. Casey, C. P.; Klein, J. F.; Fagan, M. A. J. Am. Chem. Soc., 2000, 122, 4320
- Measurement of Barriers for Alkene Dissociation and for Inversion at Zirconium in a d0 Zirconium-Alkyl-Alkene Complex. Casey, C. P.; Carpenetti, D. W., II. Organometallics, 2000, 19, 3970
- Reaction of rhenium alkynyl carbene complexes with tertiary phosphines produces dihydrophospholium rhenium complexes by a formal CH insertion process. Casey, C. P.; Kraft, S.; Powell, D. R.; Kavana, M. J. Organometallic Chem. 2001, 617
- Phosphines as ligands. Bite angle effects for diphosphines. van Leeuwen, P. W. N. M.; Casey, C. P.; Whiteker, G. T. Catalysis by Metal Complexes, 2000, 22 (Rhodium Catalyzed Hydroformylation), 63-105
- Hydrogen Transfer to Carbonyls and Imines from a Hydroxycyclopentadienyl Ruthenium Hydride: Evidence for Concerted Hydride and Proton Transfer Casey, C. P. Singer, S. W. Powell, D. R., Hayashi, R. K., Kavana, M. J. Am. Chem. Soc., 2001, 123, 1090.
- [1,3]-Metal Shifts in Rhenium Alkynyl Carbene Complexes. Casey, C. P.; Kraft, S.; Powell, D. R. Organometallics, 2001, 20, 2651
- Intramolecular CH Insertion Reactions of (Pentamethylcyclopentadienyl)Rhenium Alkynylcarbene Complexes. Casey, C. P.; Kraft, S.; Kavana, M. Organometallics, 2001, 20, 3795
- Book Review: Catalytic Polymerization of Cycloolefins: Ionic, Ziegler-Natta and Ring-Opening Metathesis Polymerization. Studies in Surface Science and Catalysis. Volume 131. By Dragutan, V., and Streck, R.; Casey, C. P. J. Am. Chem. Soc., 2001, 123, 10427
- The role of a hydroxycyclopentadienyl ruthenium dicarbonyl formate in formic acid reductions of carbonyl compounds catalyzed by Shvo's diruthenium catalyst. Casey, C. P.; Singer, S. W.; Powell, D. R. Can. J. Chem, 2001, 79, 1002
- Models for Intermediates in Metallocene-Catalyzed Alkene Polymerization: Alkene Dissociation from Cp2Zr[h1,h2-CH2Si(CH3)2CH2CH:CH2][B(C6F5)4]. Casey, C. P.; Carpenetti, D. W., II; Sakurai, H. Organometallics, 2001, 20, 4262
- Direct Observation of a Nonchelated Metal-Alkyl-Alkene Complex and Measurement of the Rate of Alkyl Migration to a Coordinated Alkene. Casey, C. P.; Lee, T.-Y.; Tunge, J. A.; Carpenetti, D. W., II. J. Am. Chem. Soc., 2001, 123, 10762
- Kinetics and Mechanism of Formation of Yttrium Alkyl Complexes from (Cp2YH)2 and Alkenes. Casey, C. P.; Tunge, J. A.; Lee, T.-Y.; Carpenetti, D. W., II. Organometallics, 2002, 21, 389
- Observation of non-chelated bis(pentamethylcyclopentadienyl)zirconium-alkyl-alkene complexes is thwarted by competitive arene or amine coordination or by b-hydride elimination. Casey, C. P.; Carpenetti, D. W. J. Organometallic Chem., 2002, 642, 120
- Formation of cis-Enediyne Complexes from Rhenium Alkynylcarbene Complexes. Casey, C. P.; Kraft, S.; Powell, D. R. J. Am. Chem. Soc., 2002, 124, 2584
- Unexpected Formation of the Isopropylamine Complex [2,3,4,5-Ph4(h4-C4CO)](CO)2Ru(H2NCHMe2) in the Attempted Synthesis of an Isopropyl Alcohol Complex. Casey, C. P.; Bikzhanova, G. A.; Baeckvall, J.-E.; Johansson, L.; Park, J.; Kim, Y. Organometallics, 2002, 21, 1955
- Protonation of rhenium 1,3-enyne and 1,3-diyne complexes: formation of exo-alkylidene h3-allyl and h3-propargyl complexes. Casey, C. P.; Chung, S. Inorg. Chim. Acta, 2002, 334, 283
- Statement on education - A core commitment of chemists and the ACS. Casey, C. P. J. Chem. Educ., 2002, 79, 1036.
- Structural Isomers of Aryl-Substituted h3-Propargyl Complexes: h2-1-Metalla(methylene)cyclopropene and h3-Benzyl Complexes. Casey, C. P.; Boller, T. M.; Kraft, S.; Guzei, I. A. J. Am. Chem. Soc. 2002, 124, 13215
- Protonated Aminocyclopentadienyl Ruthenium Hydride Reduction of Benzaldehyde and the Conversion of the Resulting Ruthenium Triflate to a Ruthenium Hydride with H2 and Base. Casey, C. P.; Vos, T. E.; Singer, S. W.; Guzei, I. A. Organometallics 2002, 21, 5038
- Why propene is not polymerized by (Cp2*YH)2: reactions of yttrium alkyl complexes with alkenes produce allyl and vinyl yttrium complexes. Casey, C. P.; Tunge, J. A.; Fagan, M. A. Journal of Organometallic Chemistry 2002, 663, 91
- Synthesis and Reactivity of Hydroxycyclopentadienyl and Aminocyclopentadienyl Ruthenium Alcohol Complexes. Casey, C. P.; Vos, T. E.; Bikzhanova, G. A. Organometallics 2003, 22, 901
- Kinetic Isotope Effect Evidence for a Concerted Hydrogen Transfer Mechanism in Transfer Hydrogenations Catalyzed by [p-(Me2CH)C6H4Me]Ru(NHCHPhCHPhNSO2C6H4-p-CH3). Casey, C. P.; Johnson, J. B. Journal of Organic Chemistry 2003, 68, 1998.
- Structural Dependence of Thermodynamics of Alkene Binding to Yttrium Alkyl Complexes and of Kinetics of Alkyl Migration to Coordinated Alkenes. Casey, C. P.; Tunge, J. A.; Lee, T.-Y.; Fagan, M. A. Journal of the American Chemical Society 2003, 125, 2641
- Indenyl Rhenium Alkyne Complexes: CO Substitution via Alkyne-Assisted Ring Slippage and CO-Catalyzed Phosphine Substitution. Casey, C. P.; Vos, T. E.; Brady, J. T.; Hayashi, R. K. Organometallics 2003, 22, 1183
- Formation of manganese enediyne complexes from manganese alkynylcarbene complexes. Casey, C. P.; Dzwiniel, T. L.; Kraft, S.; Kozee, M. A.; Powell, D. R. Inorganica Chimica Acta 2003, 345 320
- Synthesis of Cyclic cis-Enediynes from Manganese Carbyne Complexes and a,w-Diynes. Casey, C. P.; Dzwiniel, T. L.; Kraft, S.; Guzei, I. A. Organometallics 2003, 22, 3915
- Manganese Trifluoroacetoxycarbene Complexes Are Convenient Intermediates in the Synthesis of Cyclic Enediynes. Casey, C. P.; Dzwiniel, T. L. Organometallics 2003, 22, 5285
- Stereochemistry of Cyclopropane Formation Involving Group IV Organometallic Complexes. Casey, C. P.; Strotman, N. A. J. Am. Chem. Soc. 2004, 23, 4121.
- Reversal of Enantioselectivity in the Hydroformylation of Styrene with [2S,4S-BDPP]Pt(SnCl3)Cl at High Temperature Arises from a Change in the Enantioselective-Determining Step. Casey, C. P.; Martins, S. C.; Fagan, M. A. J. Am. Chem. Soc. 2004, 126, 5585.
- Equilibrium between h2-(o-Ethynylbenzoyl)rhenium Complexes and Rhenium Isobenzofuryl Carbene Complexes and Subsequent Reactions of Isobenzofuryl Carbene Complexes. Casey, C. P.; Strotman, N. A.; Guzei, I. A. Organometallics 2004, 23, 4121.
- The ACS academic employment initiative. A new avenue for faculty job searching and recruiting. Casey, Charles; Bell, Jerry A. J. Chem. Ed. 2004, 81, 1697.
- A critical juncture for graduate education. Casey, C. P. J. Chem. Ed. 2004, 81, 1698.
- Isomerization and Deuterium Scrambling Evidence for a Change in the Rate-Limiting Step during Imine Hydrogenation by Shvo's Hydroxycyclopentadienyl Ruthenium Hydride. Casey, Charles P.; Johnson, Jeffrey B. J. Am. Chem. Soc. 2005, 127, 1883.
- Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium (II) Hydride: Study of Hydrogen Activation in a Ligand-Metal Bifunctional Hydrogenation Catalyst. Casey, C. P.; Johnson, J. B.; Singer, S. W.; Cui, Q. J. Am. Chem. Soc. 2005, 127, 3100.
- Furan Forming Reactions of cis-2-Alken-4-yn-1-ones. Casey, C. P.; Strotman, N. A. J. Org. Chem. 2005, 70, 2576.
- Reduction of Imines by Hydroxycyclopentadienyl Ruthenium Hydride: Intramolecular Trapping Evidence for Hydride and Proton Transfer Outside the Coordination Sphere of the Metal. Casey, C. P.; Bikzhanova, G. A.; Cui, Q.; Guzei, I. A. J. Am. Chem. Soc. 2005, 127, 14062.
- Kinetic isotope effect evidence for the concerted transfer of hydride and proton from hydroxycyclopentadienyl ruthenium hydride in solvents of different polarities and hydrogen bonding ability. Casey, C. P.; Johnson, J. J. Can. J. Chem. 2005 , 83, 1339.
- Trapping Evidence for the Thermal Cyclization of Di-(o-Acetylphenyl)Acetylene to 3,3'-Dimethyl-1,1'-Biisobenzofuran. Casey, C. P.; Strotman, N. A.; Guzei, I. A. Beilstein J. Org. Chem., 2005, 1, 18.
- An easier route to employment. Casey, C.P.; Bell, J. Nature 2005, 437, 1394.
- 2005 Nobel Prize in chemistry - Development of the olefin metathesis method in organic synthesis. Casey, C. P. J. Chem. E., 2006, 83, 192.
- Stereochemistry of Imine Reduction by a Hydroxycyclopentadienyl Ruthenium Hydride. Casey, C. P.; Bikzhanova, G. A.; Guzei, I. A. J. Am. Chem. Soc. 2006, 128, 2286.
- The PPh3-Substituted Hydroxycyclopentadienyl Ruthenium Hydride [2,5-Ph2-3,4-Tol2(h5-C4COH)]Ru(CO)(PPh3)H Is a More Efficient Catalyst for Hydrogenation of Aldehydes. Casey, C. P.; Strotman, N. A.; Beetner, S. E.; Johnson, J. B.; Priebe, D. C.; Vos, T. E.; Khodavandi, B.; Guzei, I. A. Organometallics 2006, 25, 1230.
- PPh3-Substituted [2,5-Ph2-3,4-Tol2(h5-C4COH)]Ru(CO)(PPh3)H Exhibits Slower Stoichiometric Reduction, Faster Catalytic Hydrogenation, and Higher Chemoselectivity for Hydrogenation of Aldehydes over Ketones Than the Dicarbonyl Shvo Catalyst. Casey, C. P.; Strotman, N. A.; Beetner, S. E.; Johnson, J. B.; Priebe, D. C.; Guzei, I. A. Organometallics 2006, 25, 1236.
- Mechanism of cyclopropanol to cyclopropanol isomerization mediated by Ti(IV) and a Lewis acid. Casey, C. P.; Strotman, N. A. Can. J. Chem. 2006, 84, 1208.
- An Efficient and Chemoselective Iron Catalyst for the Hydrogenation of Ketones. Casey, C. P.; Guan, H. J. Am. Chem. Soc., 2007, 129, 5816.