| Reference: | Vedejs, E.; Reid, J. G.; Rodgers, J. D.; Wittenberger, S. J. J. Am. Chem. Soc. 1990, 112, 4351-4357. DOI. Vedejs, E.; Wittenberger, S. J. J. Am. Chem. Soc. 1990, 112, 4357-4364. DOI |
| Keywords: | Photochemistry • O-SiMe2tBu -> O-H • Sulfide -> Sulfonium • N-C(O)R -> N-H • N-H -> N-SiMe2tBu • N-SiR3 -> N-H • O-H -> O-C(O)R • Sulfide -> Sulfonium • Selenoxide 2,3-Sigmatropic • Si-Allyl -> Se-Allyl • Sulfoxide-Ei -> Ene • Ketone-α-S(O)nR -> Ketone • Ketone enolate+Me-I • Claisen acylation, acyl-X • CarboxAmide enolate+CarboxCl • CarboxCl+Enolate • Selenoxide-Ei -> EneLactam • Diels-Alder, Enone • Allyl-OH -> Allyl-Cl • Mitsunobu -> Cl • Ketone enolate+Me-I • Ylide-S 2,3-Sigmatropic • Ketone epimerization • N-C(O)R -> N-H • Ketone -> Alkyl-OH • N-H -> N-C(O)R • Diels-Alder, Thioaldehyde • Sulfide-6 • |
| Reagents: | Mesityl-Li • Chloroacetyl-Cl • NaH • SePh-Cl • Perbenzoic acid, 3-chloro • HS-CH2Bz • Photochemistry • HF·NEt3 • PBu3, CCl4 • LiNiPr2 • MeI • Carbonate, potassium • DMAP • LiN(SiMe3)2 • MeI • HF·NEt3 • DMAP • Me3O+ X- • Zn° • SePh-SeR2+ • Periodate, sodium • Perbenzoic acid, 3-chloro • Diselenide, phenyl • Me3O+ X- • Butadiene, 2-OR • AlHiBu2 • DMAP • |