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Total synthesis of Isotadeonal:
Reference: Kende, A. S.; Blacklock, T. J. Tetrahedron Lett. 1980, 21, 3119. DOI
Keywords: Enal → Acetal • Acetal → Enal • EnolEther → Aldehyde • Peterson → Enol ether • Claisen acylation, formate • Ketone enolate+Formate • KetoAldehyde → Enone • Aldehyde → Enal • Li-Silane+Ketone • Enone+Li-R • Li-Ether+Ketone • Aldehyde → Aldehyde-α-OH • Epoxidation, peracid • CompNu-Acetal/EnolEther+H+
Reagents: Formate, ethyl • DDQ • Glycol • TsOH • LiCH2-OR • KH • HCl, H2O • HCl, H2O • Perbenzoic acid, 3-chloro •

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