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Total synthesis of Vineomycinone B2, Methyl Ester:
Reference: Tius, M. A.; Gu, X. Q.; Gomez-Galeno, J. J. Am. Chem. Soc. 1990, 112, 8188–8189. DOI
Keywords: O-SiMe2tBu -> O-H • O-MOM -> O-H • Pd/Zn-Vinyl+Aryl-X • Negishi coupling • Li/Sn -> Li-Vinyl • Li-Vinyl -> Zn-Vinyl • Hydrogenation Vinyl-OR • Li/H -> Li-Aryl • Li-Aryl -> Sn-Aryl • Pd/Sn-Aryl+Allyl-X • Stille coupling • Cu-Me+EnoateEster • Anthracene -> Anthraquinone •
Reagents: BuLi(tert) • ZnCl2 • PPh3 • BH3CN-Na+ • HCl • BuLi(n) • SnBu3-Cl • Pd2(dba)3 • LiCuMe2 • HCl, MeOH •

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