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Total synthesis of Vincorine:
Reference: Horning, B. D.; MacMillan, D. W. C. J. Am. Chem. Soc. 2013, 135, 6442-6445. DOI
Keywords: N-H → N-Me • Li/H → Li-Indole • Iminium catalysis • Diels-Alder, Enal(asym) • Pinnick oxidation • Aldehyde → CarboxAcid • Iminium+N-R • Enamine → Aminal • Radical cyclization(Alkyl) • Allene synthesis • Allene Hydrogenation • CarboxAcid → CarboxEster(telluro) • Reductive amination, B-H • Pd/Zn-Aryl+Vinyl-X • Amine-5 • Amine-6 •
Reagents: Ditelluride, phenyl • NaH • MeI • BuLi(n) • ZnCl2 • HBF4 • Chlorite, sodium • NMO • BH4-Na+ • BH(OAc)3-Na+ • Acetic acid, trifluoro • H2, Pd • O=C(OR)Cl •

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