| Reference: | Paquette, L. A.; Yan, T. H. Tetrahedron Lett. 1982, 23, 3227. DOI |
| Keywords: | Alkyl-OH -> Aldehyde O-H -> O-Me Vinyl-H -> Vinyl-Br Li/Br -> Li-Vinyl Li-Vinyl+Aldehyde McMurry coupling -> Ene 1,3-Sigmatropic Simmons-Smith Dehydroalkoxylation -> Diene O-H -> O-Me Si-Allyl+Ketone Ketone+Si-R Sakurai allylation |
| Reagents: | CH2I2, ZnEt2 MnO2 BuLi(n) TsOH Bromine MeMgI BuLi(n) Formaldehyde HMPA (solvent) TiCl3 Fluoride, Bu4N+ Acetone (react) |