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Total synthesis of Verrucarol (partial):
Reference: Roush, W. R.; D'Ambra, T. E. J. Org. Chem. 1981, 46, 5045. DOI
Keywords: Ozonolysis • Selenoxide-Ei → Ene • Diels-Alder, EnoateEster • Mechanism • Mitsunobu → SeR • CompRed-CarboxEster/Epoxide+Al-H • CompNu-Alcohol/Alcohol+SeCN • Baeyer-Villiger • Lactone-6 • Epoxidation, peracid • Wagner-Meerwein • Mechanism •
Reagents: Selenocyanate, o-nitrophenyl • PBu3 • Perbenzoic acid, 3-chloro • BF3·OEt2 • AlH(OMe)3-Li+ • Li°/H2NCH2CH2NH2 • O3 • Me2S • Perbenzoic acid, 3-chloro • Perbenzoic acid, 3,5-dinitro •

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