| Reference: | Taschner, M. J.; Shahripour, A. J. Am. Chem. Soc. 1985, 107, 5570. DOI |
| Keywords: | CarboxEster -> CarboxAcid • CarboxEster -> Alkyl-OH • Alkyl-OH -> Aldehyde • Wittig-methoxymethyl • Reductive formylation • Alkene cleavage • Haloform • Ketone -> Alkyl-OH • Lactone-5 • Lemieux-Johnson oxidation • Alkene cleavage • Bredt's Rule • ConjReduct-Alkylation • Ketone enolate+Alkyl-X • Bromoacetate+Enolate • Enone ConjReduct • Lactone enolate+Alkyl-X • Lactone-5 • Lactone enolate+Alkyl-X • Mg-Alkyl+Ketone • Alkyl-OH -> Ketone • Aldol-H+ -> Aldol • Dehydration -> Ene • Lemieux-Johnson oxidation • CompE+-Aldehyde/Ketone+Wittig • CompRed-Ketone/CarboxEster+B-H • Lactone-5 • |
| Reagents: | Li°/NH3 • Bromoacetate • Hydroxide, potassium • Li°/NH3 • LiNiPr2 • AlH4-Li+ • DMSO, (COCl)2 • NEt3 • PPh3=CH-OMe • HCl, H2O • MeMgBr • OsO4, NaIO4 • SOCl2 • BH3CN-Na+ • Acetic acid • LiNiPr2, HMPA • Allyl-Br • OsO4, NaIO4 • Hypochlorite, potassium • DMSO, (COCl)2 • MeI • |