| Reference: | Buchi, G.; Gould, S. J.; Naf, F. J. Am. Chem. Soc. 1971, 93, 2492. DOI |
| Keywords: | Li-Alkynyl+Ketone • Mechanism • Aldehyde -> Imine • Mechanism • N-CHO -> N-Me • Mannich • Amine-6 • Gabriel synthesis • N-H -> N-C(O)H • Alkyne -> Ketone • Ester Pyrolysis • Enone -> Ketone • Hydrogenation Enone • Pictet-Spengler • N-CHO -> N-Me • Ketone-α-OR -> Ketone • Pictet-Spengler • |
| Reagents: | Phthalimide • HCl • Formic acetic anhydride • Hg(OAc)2 • Flash vacuum pyrolysis • H2, Pd • BF3·OEt2 • AlH4-Li+ • Li°/NH3 • BF3·OEt2 • AlH4-Li+ • Hydroxide, sodium • |