| Reference: | Dauben, W. G.; Ashcraft, A. C J. Am. Chem. Soc. 1963, 85, 3673. DOI |
| Keywords: | Simmons-Smith Enone enolate+Alkyl-X Deconjugative alkylation Wolff-Kishner Ketone -> CH2 Allylic oxidation -> Enone Enone -> Allyl-OH Alkyl-OH -> Ketone Mg-Alkyl+Ketone Ketone+Mg-R Dehydration-> Ene |
| Reagents: | MeI KOtBu Hydrazine Hydroxide, potassium CrO4Na2 Acetic anhydride AlH4-Li+ CH2I2, Zn/Cu MeMgBr Chloride, ammonium |