| Reference: | Hassfeld, J.; Eggert, U.; Kalesse, M. Synthesis 2005, 1183. DOI |
| Keywords: | O-H -> O-PMB • EnoateEster -> Allyl-OH • Allyl-OH -> Enal • CarboxAmide(Evans) -> CarboxAmide(Weinreb) • O-H -> O-SiMe2tBu • O-H -> O-SiEt3 • O-H -> O-Me • O-PMB -> O-H • Alkyl-OH -> Ketone • O-H -> O-SiMe2tBu • Ketone -> Alkyl-OH • Alkyl-OH -> Aldehyde-α-OR • Pinnick oxidation • Aldehyde -> CarboxAcid • O-PMB -> O-H • Mitsunobu -> Lactone-15+ • Alkyl-OH -> Alkyl-OC(O)R • Macrolactonization • Lactone-15+ • B-Allyl-Ipc+Aldehyde • Aldol-B-Ipc • Wittig-carboxymethyl -> EnoateEster • Aldol-B-Evans • CarboxAmide(Weinreb) -> Aldehyde • CarboxEster enolate+Aldehyde • Ketone enolate+Aldehyde • Aldol-Li -> Aldol • Felkin-Anh • Ozonolysis • Mukaiyama Aldol • Aldol-Si • Ketene acetal+Aldehyde • Aldehyde+Enolsilane • Chiral auxiliary • |
| Reagents: | Crotyl-B(Ipc)2 • BF3·OEt2 • NaH • O3 • PPh3=C(Me)-CO2R • AlHiBu2 • MnO2 • BOTfBu2 • NMe(OMe)-AlMe2 • SiMe2tBu-OTf • AlHiBu2 • SiEt3-OTf • SiMe2tBu-Cl • Me3O+ X- • DDQ • RuO4-Pr4N+, NMO • NaN(SiMe3)2 • SiMe2tBu-OTf • AlHiBu2 • RuO4-Pr4N+, NMO • Chlorite, sodium • DDQ • PPh3, DEAD • AD-Mix • DMSO (solvent) • |