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Total synthesis of Sulcatol:
Reference: Davies, S. G.; Smyth, G. D. Tetrahedron: Asymmetry. 1996, 7, 1005. DOI
Keywords: Fischer esterification • CarboxAcid → CarboxEster • Amine → AmineOxide • Li-Amide+EnoateEster • ConjAdd(asym) Li-Amide • Dehydration → Ene • Hydrogenolysis N-O • 2,3-Sigmatropic Amine oxide • Meisenheimer rearrangement •
Reagents: LiN(Phenethyl)R • HCl, MeOH • MeMgBr • Perbenzoic acid, 3-chloro • Al2O3 • POCl3 • Na°/NH3 • Chiral auxiliary-Misc •

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