| Reference: | Knight, S. D.; Overman, L. E.; Pairaudeau, G. J. Am. Chem. Soc. 1993, 115, 9293-9294; DOI; Knight, S. D.; Overman, L. E.; Pairaudeau, G. J. Am. Chem. Soc. 1995, 117, 5776- 5788. DOI |
| Keywords: | O-H -> O-C(O)OR • Ketone -> Alkyl-OH • EnoateEster -> Allyl-OH • O-H -> O-SiiPr3 • Jones oxidation • Allyl-OH -> Enone • Vinyl-OTf -> Sn-Vinyl • Protecting group - Amine • O-SiiPr3 -> O-H • Finkelstein reaction • Allyl-OH -> Allyl-Cl • O-tBu -> O-H • CarboxEster -> Aldehyde • Ether-7 • Lactam-6 • Mechanism • Knoevenagel condensation • ConjAdd M-OR • Ether-7 • Ketone -> Imine • EnoateEster -> CarboxEster • N-H -> N-Allyl • N-H -> N-Alkyl • Epoxide+Na-Amide • Amine-6 • Pd/Sn-Vinyl+Aryl-X+CO • Stille carbonylative coupling • Carbonylation • Pd-Enolate allylation • Tsuji-Trost allylation • CompE+-Allyl-X/Allyl-X+Pd-Enolate • Enone -> Vinyl-OTf • ConjReduct-Triflation • Enone ConjReduct • Pd-Stannylation • Wittig-methyl • Epoxidation, nucleophilic Enone • Dehydration -> Enoate • Claisen acylation, Mander • Ketone enolate+Mander • Mechanism • Mannich • Aza-Claisen • Amine-5 • |
| Reagents: | O=C(OR)Cl • NaH • Pd2(dba)3 • BH3CN-Na+ • TiCl4 • Carbodiimide • CuCl • AlHiBu2 • SiiPr3-Cl • CrO3, H2SO4 (Jones) • BHEt3-Li+ • Tf2NPh • SnMe3-SnMe3 • Pd(PPh3)4 • Pd2(dba)3 • AsPh3 • CO • Hydroperoxide, tbutyl • Triton B • PPh3=CH2 • Fluoride, Bu4N+ • MeSO2Cl • NEtiPr2 • Chloride, lithium • Acetamide, trifluoro • NaH • Epoxide • NaH • Hydroxide, potassium • LiNiPr2 • O=C(OR)CN • HCl • Zn° • H2SO4 • NaOMe • AlHiBu2 • Malonic acid • Acetic anhydride • DMF (solvent) • Formaldehyde • Sulfide, sodium • |