| Reference: | Ley, S. V.; et al Org. Lett. 2003, 5, 4815, 4819. DOI |
| Keywords: | Si-Alkynyl -> H-Alkynyl • Diol -> Ketal • O-SiiPr3 -> O-H • Alkyl-OH -> Aldehyde • Propargyl-OH -> Ynone • CarboxEster -> Alkyl-OH • O-H -> O-SiiPr3 • Li-Dithiane+Epoxide • Li-Alkynyl+Epoxide • Epoxide+Li-R • Li/H -> Li-Alkynyl • Cu-Vinyl+Epoxide • Epoxide+Cu-R • Mg-Alkynyl+Aldehyde • Ketone -> Alkyl-OH • Ynone -> Dithiane • |
| Reagents: | Epoxide • Alkynyl-Li • BF3·THF • Epoxide • Vinyl-MgX • CuI • Fluoride, Bu4N+ • SiEt3-Cl • Alkynyl-MgX • BuLi(n) • Epoxide • I2, NaHCO3 • B(OMe)Et2 • Me2C(OMe)2 • Fluoride, Bu4N+ • DMSO, (COCl)2 • Alkyl-MgX • Dess-Martin • HS-(CH2)3-SH • HS-(CH2)3-SH • AlH4-Li+ • SiiPr3-Cl • Propiolate • BH4-Na+ • Imidazole • Imidazole • |