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Total synthesis of Sparteine:
Reference: Smith, B. T.; Wendt, J. A.; Aube, J. Org. Lett. 2002, 4, 2577. DOI
Keywords: Alkyl-OH -> Ketone • Ketone -> Ketal • CarboxAmide -> Thioamide • N-Boc -> N-H • Photochemistry • Aldol-Li -> Enone • Ketone enolate+Alkyl-X, Intram • Hydrogenation Alkene • Enone -> Ketone • Mitsunobu -> Azide • Alkyl-OH -> Alkyl-N3 • Nitrone -> Oxaziridine • Pd-Hydrosilylation • CarboxAmide -> Amine • CarboxAmide -> Amine • CompE+-CarboxAmide/Ketone+Lawesson • Amine-6 • C-Si -> C-OH, Alkyl • N-H -> N-Alkyl • Alkyl-X -> Alkyl-I • Finkelstein reaction • Schmidt Reaction • Amine-6 •
Reagents: H2O2 • DMSO, (COCl)2 • Glycol • LiNiPr2 • MeSO2Cl • H2, Pd • Azide, zinc • PPh3, DEAD • Lawesson • RaNi • LiNiPr2 • Iodide, sodium • NHBoc2 • Carbonate, potassium • Acetic acid • Bicarbonate, sodium • Photochemistry • AlH4-Li+ • PdCl(Allyl) • DBU • DMF (solvent) • TiCl4

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