| Reference: | Mander, L. N.; Thomson, R. J. Org. Lett. 2003, 5, 1321. DOI |
| Keywords: | Ketone -> Alkyl-OH • O-MOM -> O-H • O-H -> O-SiMe2tBu • Epoxidation, peracid • O-H -> O-MOM • ConjAdd M-CN • Ketone -> Ketal • Retro-Diels-Alder, cyclopentadiene • Barton-McCombie reduction • Alkyl-OH -> Alkyl-H • Claisen acylation, Mander • Enone enolate+Mander • O-MOM -> O-H • Allyl-OH -> Enal • CarboxEster -> CarboxAcid • Li-Nitrile+Alkyl-X • Cu-Vinyl+Enone • Nitrile -> Aldehyde • Alkyl-OH -> Alkyl-I • Aldehyde -> Alkyl-OH • O-H -> O-MOM • O-SiMe2tBu -> O-H • Epoxide -> Allyl-OH • Cu-Alkyl+Vinyl-X • Diels-Alder, Intram • Enolsilane -> Ketone enolate • Retro-Diels-Alder, cyclopentadiene • Cu-Alkyl+Enone • Enone+Cu-R • ConjAdd-Alkylation • |
| Reagents: | Propenyl-MgX • BH4-Na+ • S=C(OPh)Cl • TsOH·Py • SiMe2tBu-Cl • Perbenzoic acid, 3-chloro • LiNiPrCy • Cl-CH2-OR • PPh3, I2 • Cyanide, potassium • Dowex • LiNiPr2, HMPA • AlHiBu2 • LiNiPr2 • NaH • Alkyl-MgX • MgBr2 • MnO2 • Thiolate, propyl • BH4-Na+ • Cl-CH2-OR • O=C(OR)CN • Tf2NPh • HSnBu3 • AIBN • Fluoride, Bu4N+ • Epoxide • CuI • HS-Bu • CuI • MeLi • SiMe3-Cl • |