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Total synthesis of Solenopsin:
Reference: Reding, M. T.; Buchwald, S. L. J. Org. Chem. 1998, 63, 6344. DOI
Keywords: Alkyl-X → Alkyl-N3 • Staudinger • Azide → Amine • N-H → N-Boc • Li/H → Li-Amine • Nitrile+Mg-R → Ketone • Mg-Alkyl+Nitrile • Imine → Amine(asym) • Amine-6 • Li-Amine+Alkyl-X • Alkyl-X+Li-R •
Reagents: Alkyl-MgX • Azide, sodium • PPh3 • HSiPhH2 • Boc2O • BuLi(sec) • Sulfate, dimethyl • Chiral catalyst • Acetic acid, trifluoro •

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