| Reference: | Wilson, R. M.; Jen, W. S.; MacMillan, D. W. C. J. Am. Chem. Soc. 2005, 127, 11616. DOI |
| Keywords: | Alkyl-OH -> Ketone-1,3-di • Lactone-6 • Li/H -> Li-Pyrone • Diels-Alder, Intram(asym) • Mukaiyama Aldol • Aldol-Si • Ketene acetal+Aldehyde • Aldehyde+Enolsilane • Li-Vinyl+CarboxEster • Vinyl-OH -> Vinyl-OMe • Pyrone synthesis • |
| Reagents: | Imidazolone • TiCl4 • Dess-Martin • DBU • MeOTs • Carbonate, potassium • LiNiPr2 • Formate, methyl • DMF (solvent) • Chiral catalyst • |