| Reference: | Trost, B. M.; Shi, Z. J. Am. Chem. Soc. 1994, 116, 7459-7460. DOI |
| Keywords: | Payne rearrangement • O-H -> O-SiMe3 • Alkyne Carbometalation • Lactone-5 • Hydrogenation Alkene • Li-Alkynyl+Alkyl-X • Li/H -> Li-Alkynyl • Hydrogenation Lindlar • Sharpless epoxidation • Payne rearrangement • Alkyl-OH -> Alkyl-I • Ether-5 • O-SiMe3 -> O-H • Ramberg-Baecklund • |
| Reagents: | Alkynyl-Li • HMPA (solvent) • H2, Pd • Hydroperoxide, tbutyl • DEET • Ti(OiPr)4 • HS-tBu • Hg(OAc)2 • Acetic acid, trifluoro • PPh3, I2 • Carbonate, cesium • DMF (solvent) • Perbenzoic acid, 3-chloro • SiMe3-Cl • Ru(COD)Cl • Rh(PPh3)3Cl • H2, Rh • KOtBu • TsOH • |