| Reference: | Beaudry, S. M.; Trauner, D. Org. Lett. 2005, 7, 4475-4477. DOI |
| Keywords: | O-H -> O-SiMe2tBu O-H -> O-C(O)R Ether-5 Electrocyclic-8π Electrocyclic-6π Pd/Sn-Vinyl+Vinyl-X Stille coupling Ketoester dianion+AcylImidazole Li-Vinyl+Aldehyde Enal+Li-R Claisen-Ireland Pd-Stannylation Vinyl-I -> Sn-Vinyl CarboxEster -> CarboxEster-α-OH CompE+-Aldehyde/Vinyl-X+Li-R |
| Reagents: | SnMe3-SnMe3 PdCl2(MeCN)2 Vinyl-SnR3 Fluoride, cesium Vinyl-Li SiMe2tBu-Cl Acetic anhydride LiNiPr2 SiMe3-Cl Carbonate, potassium LiNiPr2 NBS DMF (solvent) BuLi(n) DBU MeOSO2F SiMe3-Cl |