| Reference: | Matteson, D. S.; Singh, R. P. J. Org. Chem. 1998, 63, 4466. DOI |
| Keywords: | B-Alkyl -> Alkyl-OH • Alkene cleavage • Li-Dichloromethyl+Borane • Mg-Alkyl+Borane • Metalate rearrangement (B) • Lemieux-Johnson oxidation • B-Vinyl -> Vinyl-H • Alkyne Haloboration • Li-Dichloromethyl+Borane • Li-Chloromethyl+Borane • Mg-Vinyl+Borane • Metalate rearrangement (B) • Chiral auxiliary • |
| Reagents: | LiCHCl2 • MeMgCl • LiCHCl2 • EtMgX • H2O2, NaOH • BBr3 • Acetic acid • Mg° • OsO4, NaIO4 • LiCHCl2 • ZnCl2 • LiCH2-Cl • Vinyl-MgX • |