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Total synthesis of Semperviridine:
Reference: Gribble, G. W.; Barden, T. C.; Johnson, D. A. Tetrahedron Lett. 1988, 44, 3195. DOI
Keywords: Allyl-OH → Enone • Aryl-S(O)nR → Aryl-H • N-H → N-SO2R • Li/H → Li-Indole • Li/H → Li-Indole • Li-Aryl+Aldehyde • Li-Aryl+Aldehyde • Ketone → Ketone-1,2-di • Triazene • Dehydration → Enamine • Diels-Alder-inverse, Enamine • Pyridine synthesis •
Reagents: LiNiPr2 • Acetaldehyde • MnO2 • SeO2 • Thiouronium • Perbenzoic acid, 3-chloro • Na(Hg) • Sulfonyl chloride, benzene • BuLi(n) • Bromoacetaldehyde • Hydroxide, sodium • Pyrrolyl-Li •

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