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Total synthesis of Semperviridine:
Reference: Gribble, G. W.; Barden, T. C.; Johnson, D. A. Tetrahedron Lett. 1988, 44, 3195. DOI
Keywords: Allyl-OH -> Enone • Aryl-SO2R -> Aryl-H • N-H -> N-SO2R • Li/H -> Li-Indole • Li/H -> Li-Indole • Li-Aryl+Aldehyde • Ketone -> Ketone-1,2-di • Triazene • Dehydration -> Enamine • Diels-Alder-inverse, Enamine • Pyridine synthesis •
Reagents: LiNiPr2 • Acetaldehyde • MnO2 • SeO2 • Thiouronium • Perbenzoic acid, 3-chloro • Na(Hg) • PhSO2Cl • BuLi(n) • Bromoacetaldehyde • Hydroxide, sodium • Pyrrolyl-Li •

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