| Reference: | Davis, F. A.; Prasad, K. R.; Nolt, M. B.; Wu. Y. Org. Lett. 2003, 5, 925. DOI |
| Keywords: | Ketone -> Alkyl-OH • Ketone -> Alkyl-OH • N-S(O)R -> N-H • CarboxAmide(Weinreb)+Mg-R • Mg-Alkyl+CarboxAmide(Weinreb) • Aldehyde -> Imine • N-SO2R -> N-H • N-H -> N-Alkyl • Amine-6 • N-H -> N-Alkyl • Amine-6 • Sulfinamide, chiral • CarboxAmide enolate(Weinreb)+Imine • Imine+Enolate • Chiral auxiliary • |
| Reagents: | Ti(OEt)4 • MeMgBr • BHEt3-Li+ • NaH • Perbenzoic acid, 3-chloro • Na°/NH3 • AlH(OtBu)3-Li+ • Perbenzoic acid, 3-chloro • Na°/NH3 • 18-cr-6 • NaH • 18-cr-6 • Weinreb acetamide • |