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Total synthesis of Reserpine:
Reference: Stork, G. Pure Appl. Chem. 1989, 61 439
Keywords: Si-Aryl → H-Aryl • O-Bn → O-H • O-H → O-SO2R • Baeyer-Villiger • O-H → O-Me • Lactone → Lactol • CompRed-Lactone/CarboxEster+Al-H • Pictet-Spengler • N-H → N-Alkyl • Aldehyde → Cyanoamine • Si-Alkyl → HO-Alkyl • ConjAdd Enolate •
Reagents: Fluoride, R4N+ • H2, Pd • TsCl • Perbenzoic acid, 3-chloro • MeI • Ag2O • AlHiBu2 • Cyanide, potassium • HCl, THF •

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