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Total synthesis of Reiswigin A Model:
Reference: Jones, D. N.; Maybury, M. W. J.; Swallow, S.; Tomkinson, N. C.O.Tetrahedron Lett. 1993, 34, 8553. DOI
Keywords: Ketone → Alkyl-OH • Dehydration → Ene • Epoxidation, peracid • Li-Allyl+Ketone • Enone+Li-R • ConjAdd-Alkylation • KetoSulfone enolate+Alkyl-X • Alkyl-X+Enolate • Reductive elimination - S/OR • Allyl-OH → Enone • ConjReduct-Acylation • EneSulfone ConjReduct •
Reagents: Allyl-Li • Iodoacetate • NaH • MeI • AlH4-Li+ • SOCl2 • Perbenzoic acid, 3-chloro • Na(Hg) • Permanganate, barium •

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