| Reference: | Stork, G.; Niu, D.; Fujimoto. A.; Koft, E. R.; Balkovec, J. M.; Tata, J. R.; Dake, G. R. J. Am. Chem. Soc. 2001, 123, 3239. DOI |
| Keywords: | O-H -> O-SiMe2tBu • O-SiMe2tBu -> O-H • Lactone-5 • Lactone -> Lactol • Imine -> Amine • O-SiPh2tBu -> O-H • O-H -> O-SO2R • Benzyl-H -> Benzyl-OH • Allylic oxidation -> Allyl-OH • Li-Benzyl+O2 • Wittig-methoxymethyl • Reductive formylation • Mitsunobu -> Azide • Alkyl-OH -> Alkyl-N3 • CarboxAmide enolate+Alkyl-X • Li-Benzyl+Aldehyde • Aldehyde+Li-R • CompE+-Aldehyde/Azide+Li-R • Amine+Alkyl-X • Amine-6 • Alkyl-OH -> Ketone • Staudinger • Azide -> Amine • Ketone -> Imine • Amine-6 • |
| Reagents: | AlMe3 • SiMe2tBu-Cl • LiNiPr2 • Iodoethanol • TsOH·Py • AlHiBu2 • PPh3=CH-OMe • PPh3, DEAD • HCl, H2O • Benzyl-Li • BH4-Na+ • HF • MeSO2Cl • NaH • Azide, diphenylphosphoryl • AlMe2-NR2 • Imidazole • DMSO (solvent) • DMSO, (COCl)2 • PPh3 • |